公开(公告)号：EP1611631A1

公开(公告)日：2006-01-04

申请号：EP04758614.4

申请日：2004-03-30

申请人： TEXACO DEVELOPMENT CORPORATION

发明人： WHEAT, Williams, S. ,  MIRKOVIC, Vesna, R. ,  TO, Hugh, N. ,  BENEDETTO, Dennis, J.

IPC分类号： H01M8/04 ,  C01B3/24

CPC分类号： H01M8/04231 ,  C01B3/382 ,  C01B3/48 ,  C01B2203/00 ,  C01B2203/0244 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/045 ,  C01B2203/047 ,  C01B2203/0485 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0844 ,  C01B2203/0877 ,  C01B2203/0883 ,  C01B2203/0894 ,  C01B2203/1205 ,  C01B2203/1241 ,  C01B2203/1276 ,  C01B2203/142 ,  C01B2203/146 ,  C01B2203/1604 ,  C01B2203/1609 ,  C01B2203/1614 ,  C01B2203/1633 ,  C01B2203/169 ,  C01B2203/1695 ,  C01B2203/82 ,  H01M8/0618

摘要： An operational cycle for a fuel processor capable of reforming a fuel, the operational cycle is disclosed. The operational cycle includes: an off state; a manager check state entered into from the off state, and in which the operational readiness of the fuel processor is checked; a preheat state entered into from the manager check state, and in which the fuel processor preheats gases, including the fuel, for mixing into a process feed stream; a startup state entered into from the preheat state, and in which the fuel processor begins operating under start-up conditions; a run state entered into from the startup state, and in which the fuel processor reforms the process feed stream into a reformate under steady-state conditions; and a shutdown state entered into any one of the manager check state, preheat state, startup state, and run state. The operational cycle may be employed in a fuel processor for a fuel cell or a fuel cell power plant.

公开(公告)号：EP1578689A2

公开(公告)日：2005-09-28

申请号：EP03814106.5

申请日：2003-12-18

申请人： HONDA GIKEN KOGYO KABUSHIKI KAISHA ,  Symyx Technologies, Inc.

发明人： HAGEMEYER, Alfred ,  CARHART, Raymond, F. ,  YACCATO, Karin ,  LESIK, Andreas ,  BROOKS, Christopher, James ,  PHILLIPS, Cory, Bernard

IPC分类号： C01B3/16 ,  B01J23/89 ,  B01J23/58

CPC分类号： B01J23/652 ,  B01J23/58 ,  B01J23/63 ,  B01J23/648 ,  B01J23/6562 ,  B01J23/8946 ,  C01B3/16 ,  C01B2203/00 ,  C01B2203/0283 ,  C01B2203/1011 ,  C01B2203/1023 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1088 ,  C01B2203/1094 ,  C01B2203/1614 ,  Y02P20/52

摘要： A method and catalysts and fuel processing apparatus for producing a hydrogen-rich gas, such as a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas, such as a syngas, contacts a water gas shift catalyst in the presence of water, preferably at a temperature of less than about 450°C, to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst comprising: a) Pt, its oxides or mixtures thereof; b) at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, their oxides and mixtures thereof; and c) at least one of Sc, Y, Ti, Zr, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Co, Ir, Ni, Pd, La, Ce, Pr, Nd, Sm, Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.

摘要翻译： 公开了用于生产富氢气体如富氢合成气的方法和催化剂以及燃料处理装置。 根据该方法，含CO的气体（例如合成气）在水存在下接触水煤气变换催化剂，优选在低于约450℃的温度下，产生富氢气体，例如 富氢合成气。 还公开了水煤气变换催化剂，其包含：a）Pt，其氧化物或其混合物; b）Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba中的至少一种，它们的氧化物及其混合物; 和c）Sc，Y，Ti，Zr，V，Nb，Ta，Cr，Mo，W，Mn，Fe，Co，Ir，Ni，Pd，La，Ce，Pr，Nd，Sm，Eu ，它们的氧化物及其混合物。 WGS催化剂可以负载在载体上，例如氧化铝，氧化锆，二氧化钛，二氧化铈，氧化镁，镧系元素，氧化铌，氧化钇和氧化铁中的任何一种或其组合。 还公开了包含这种水煤气变换催化剂的燃料处理器。

公开(公告)号：EP1467168A3

公开(公告)日：2005-09-14

申请号：EP04008379.2

申请日：2004-04-06

申请人： HONDA MOTOR CO., Ltd.

发明人： Yoshida, Nobuyoshi ,  Hanai, Satoshi ,  Yamagami, Takeshi

IPC分类号： F28D7/00 ,  F28D7/12

CPC分类号： F28D9/0025 ,  B01B1/005 ,  B01J19/2485 ,  B01J19/249 ,  B01J2219/2453 ,  B01J2219/2459 ,  B01J2219/246 ,  B01J2219/2465 ,  B01J2219/247 ,  B01J2219/2482 ,  C01B3/48 ,  C01B2203/00 ,  C01B2203/0244 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0833 ,  C01B2203/0838 ,  C01B2203/0844 ,  C01B2203/0866 ,  C01B2203/1288 ,  C01B2203/142 ,  C01B2203/82 ,  F28D7/12 ,  H01M8/04022 ,  H01M8/04074 ,  H01M8/0618 ,  H01M8/0668 ,  H01M2008/1095

摘要： A heat exchanger includes: a casing (21); an external cylinder (32) which is arranged inside the casing (21) with a clearance formed between the external cylinder (32) and an inner surface of the casing (21) and is supported in a cantilevered manner, has a closed end portion (32b), and forms a first fluid passage (81) between the external cylinder (32) and the casing (21); and an internal cylinder (40) which is arranged inside the external cylinder (32) with a clearance formed between the internal cylinder (40) and an inner surface of the external cylinder (32) and is supported in a cantilevered manner, is open at both ends, and forms a second fluid passage (71), which is turned around at the closed end portion (32b) of the external cylinder (32), between the internal cylinder (40) and the external cylinder (32).

公开(公告)号：EP1565398A1

公开(公告)日：2005-08-24

申请号：EP03786057.4

申请日：2003-11-14

申请人： L'air Liquide Société Anonyme pour l'étude et l'exploitation des procédés Georges Claude

发明人： SUN, Lian-Ming ,  GAUTHIER, Pierre-Robert ,  MARTY, Pascal ,  DENIS, Catherine ,  IMBAULT, Raphaëlle

IPC分类号： C01B3/38 ,  C01B13/02

CPC分类号： C01B3/382 ,  C01B3/501 ,  C01B2203/00 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0405 ,  C01B2203/041 ,  C01B2203/0475 ,  C01B2203/0495 ,  C01B2203/0883 ,  C01B2203/0894 ,  C01B2203/1052 ,  C01B2203/1241 ,  C01B2203/127 ,  C01B2203/1288 ,  C01B2203/142 ,  C01B2203/147

摘要： The invention relates to a method of producing synthesis gas containing hydrogen and carbon monoxide. The inventive method comprises the following: a step (a) in which a hydrocarbon mixture undergoes pre-reforming; a step (b) in which the pre-reformed mixture resulting from step (a) is reformed in a catalytic ceramic membrane reactor (RCMC) by an oxidising mixture containing oxygen in order to obtain the raw synthesis gas containing hydrogen, carbon monoxide, carbon dioxide and water, and an oxygen-depleted mixture; and steps involving the pre-heating of the different fluids used. The invention is characterised in that prior to step (b), the oxidising mixture is brought to a temperature of between 871 °C and 1300 °C and, preferably, a temperature of the order of 1000 °C.

公开(公告)号：EP1532355A1

公开(公告)日：2005-05-25

申请号：EP03756174.3

申请日：2003-05-12

申请人： Massachusetts Institute of Technology

发明人： RABINOVICH, Alexander ,  ALEXEEV, Nikolai ,  BROMBERG, Leslie ,  COHN, Daniel, R. ,  SAMOKHIN, Andrei

IPC分类号： F02B43/10 ,  F02M25/12 ,  B01J19/08 ,  H05H1/34

CPC分类号： C01B3/342 ,  B01J19/088 ,  B01J2219/0809 ,  B01J2219/083 ,  B01J2219/0832 ,  B01J2219/0869 ,  B01J2219/0877 ,  B01J2219/0884 ,  B01J2219/0892 ,  B01J2219/0894 ,  C01B2203/00 ,  C01B2203/0261 ,  C01B2203/06 ,  C01B2203/0844 ,  C01B2203/0861 ,  C01B2203/0866 ,  C01B2203/1023 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1247 ,  C01B2203/1288 ,  C01B2203/148 ,  C01B2203/1604 ,  F02B43/10 ,  F02M25/12 ,  F02M27/042 ,  H05H1/48 ,  H05H2001/3431 ,  Y02T10/121 ,  Y02T10/32

摘要： A novel apparatus and method is disclosed for a plasmatron fuel converter ('plasmatron') that efficiently uses electrical energy to produce hydrogen rich gas. The volume and shape of the plasma discharge is controlled by a fluid flow established in a plasma discharge volume. A plasmatron according to this invention produces a substantially large effective plasma discharge volume allowing for substantially greater volumetric efficiency in the initiation of chemical reactions within a volume of bulk fluid reactant flowing through the plasmatron.

公开(公告)号：EP0790292B1

公开(公告)日：2005-03-16

申请号：EP97300893.1

申请日：1997-02-12

申请人： Mitsubishi Heavy Industries, Ltd.

发明人： Iijima, Masaki ,  Uchida, Satoshi ,  Shinada, Osamu

IPC分类号： C10L3/00 ,  C10J3/46 ,  C10K1/00

CPC分类号： C10K1/32 ,  C01B3/32 ,  C01B3/36 ,  C01B2203/00 ,  C01B2203/025 ,  C01B2203/0415 ,  C01B2203/045 ,  C01B2203/0475 ,  C01B2203/0485 ,  C01B2203/0495 ,  C01B2203/06 ,  C01B2203/0844 ,  C01B2203/0883 ,  C01B2203/1258 ,  C01B2203/146 ,  C10L3/00 ,  Y02P20/124 ,  Y02P20/129

公开(公告)号：EP1505036A2

公开(公告)日：2005-02-09

申请号：EP04008538.3

申请日：2004-04-08

申请人： MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.

发明人： Suzuki, Motohiro ,  Asou, Tomonori ,  Mukai, Yuri ,  Ukai, Kunihiro ,  Maenishi, Akira ,  Tamura, Yoshio

IPC分类号： C01B3/38 ,  C01B3/48 ,  H01M8/06 ,  B01J8/04 ,  B01J19/24 ,  B01J19/00

CPC分类号： B01J19/2485 ,  B01B1/005 ,  B01J8/0411 ,  B01J8/0453 ,  B01J8/0465 ,  B01J8/0492 ,  B01J8/0496 ,  B01J2208/00309 ,  B01J2208/00495 ,  B01J2208/00504 ,  B01J2208/0053 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/00 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0816 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0866 ,  C01B2203/0883 ,  C01B2203/0894 ,  C01B2203/1011 ,  C01B2203/1023 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1223 ,  C01B2203/1241 ,  C01B2203/1288 ,  C01B2203/1294 ,  C01B2203/1619 ,  C01B2203/169 ,  C01B2203/82 ,  H01M8/04022 ,  H01M8/0612 ,  H01M8/0662 ,  Y02P20/128

摘要： A hydrogen generator comprises therein a reformer, a Shifter, a material flow passage with first evaporator through which a material is supplied to the reformer, a reformed gas flow passage for leading the reformed gas derived from the reformer to the Shifter, a shifted gas flow passage through which a shifted gas derived from the Shifter is taken out, and second steam flow passage formed adjacent to the reformed gas flow passage to be located at upstream side of the Shifter. The second evaporator is provided within the second steam flow passage. Apart of heat of the reformed gas is recovered as latent heat by the second evaporator. Thereby, temperature of the Shifter is controlled.

摘要翻译： 一种氢发生器，其中包括重整器（16），移位器（15），具有第一蒸发器的材料流动通道，材料通过该原料供应到重整器，重整气流通道，用于将从重整器导出的重整气体引导到 移位器，取出来自移动器的移动气体的移动气体流路，以及与重整气体流路相邻形成的第二蒸汽流路，位于移动器的上游侧。 第二蒸发器设置在第二蒸汽流动通道内。 重新蒸发的气体除了热量作为潜热被第二蒸发器回收。 由此，可以控制移动器的温度。

公开(公告)号：EP1495802A1

公开(公告)日：2005-01-12

申请号：EP03715625.4

申请日：2003-03-28

申请人： Kyushu Electric Power Co., Inc.

发明人： UCHIDA, Yoshitaka, KYUSHU ELEC. POWER CO., INC. ,  TSUJIMOTO, Keigo, KYUSHU ELEC. POWER CO., INC.

IPC分类号： B01J23/76 ,  B01J23/80 ,  C01B3/40

CPC分类号： C01B3/40 ,  B01J23/002 ,  B01J23/462 ,  B01J23/755 ,  B01J23/83 ,  B01J23/894 ,  B01J37/0205 ,  B01J37/031 ,  B01J2523/00 ,  C01B2203/00 ,  C01B2203/0233 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  Y02P20/52 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/821 ,  B01J2523/847 ,  B01J2523/41 ,  B01J2523/48

摘要： Disclosed is a reforming-catalyst composition, which comprises nickel oxide and lanthanum oxide as a catalytic material for inducing a reaction between stream and either one of methane, natural gas and town gas to produce a hydrogen-containing gas. The nickel oxide and lanthanum oxide are formed as a perovskite-structured compound partly or in their entirety. The reforming-catalyst composition may include an oxide consisting of either one of alumina, silica and zirconia, on which the perovskite-structured compound is formed to serve as a catalyst carrier. Further, the reforming-catalyst composition may include nickel or ruthenium supported by aforesaid catalyst carrier consisting of the perovskite-structured compound. The reforming-catalyst composition of the present invention allows highly concentrated hydrogen to be produced at a low S/C ratio in steam reforming of methane, natural gas or town gas, while maintaining catalytic activity over a long time-period.

摘要翻译： 公开了一种重整催化剂组合物，其包含氧化镍和氧化镧作为用于在流与甲烷，天然气和城镇煤气中的任一种之间的反应的催化材料中产生含氢气体。 氧化镍和氧化镧部分或全部形成为钙钛矿结构化合物。 重整催化剂组合物可以包括氧化铝，二氧化硅和氧化锆中的任一种，其上形成钙钛矿结构化合物作为催化剂载体的氧化物。 此外，重整催化剂组合物可以包括由上述由钙钛矿结构化合物组成的催化剂载体负载的镍或钌。 本发明的重整催化剂组合物允许在甲烷，天然气或城镇煤气的蒸汽重整中以低S / C比率生产高度浓缩的氢气，同时保持长时间的催化活性。

公开(公告)号：EP1471033A2

公开(公告)日：2004-10-27

申请号：EP04009714.9

申请日：2004-04-23

申请人： MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.

发明人： Fujihara, Seiji ,  Ukai, Kunihiro ,  Taguchi, Kiyoshi ,  Wakita, Hidenobu

IPC分类号： C01B3/48 ,  C01B3/38 ,  C01B3/58 ,  H01M8/06 ,  B01J19/00 ,  B01J8/04

CPC分类号： C01B3/48 ,  B01J8/048 ,  B01J8/0488 ,  B01J19/0013 ,  B01J2219/00063 ,  B01J2219/002 ,  B01J2219/00209 ,  B01J2219/00213 ,  B01J2219/00227 ,  C01B3/38 ,  C01B3/583 ,  C01B2203/00 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/1023 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1217 ,  C01B2203/1235 ,  C01B2203/1619 ,  C01B2203/1623 ,  C01B2203/1685 ,  C01B2203/169 ,  C01B2203/1695 ,  C01B2203/82 ,  H01M8/04007 ,  H01M8/0612 ,  H01M8/0662

摘要： A hydrogen generator of the present invention is provided with: a reformer for generating a reformed gas containing hydrogen from a feed material containing an organic compound at least containing carbon and hydrogen and water; a heater for heating the reformer to a temperature required for generating the reformed gas: a carbon monoxide reducing unit having a carbon monoxide reducing catalyst for reducing carbon monoxide contained in the reformed gas generated in the reformer; and a temperature detector for detecting at least one of a temperature of the reformed gas in the carbon monoxide reducing unit and a temperature of the carbon monoxide reducing catalyst, wherein an amount of the feed material to be supplied to the reformer is controlled based on a comparison between a detected temperature detected by the temperature detector and a reference temperature set in accordance with the amount of the feed material.

摘要翻译： 本发明的氢发生器设有：重整器（1），用于从含有至少含有碳和氢和水的有机化合物的进料中产生含氢气的重整气体; 用于将重整器加热到生成重整气体所需的温度的加热器：一氧化碳还原单元（7），其具有用于还原在重整器中产生的重整气体中所含的一氧化碳的一氧化碳还原催化剂; 以及温度检测器，用于检测一氧化碳减少单元中的重整气体（6）的温度和一氧化碳还原催化剂的温度中的至少一个，其中控制供给到重整器的进料的量被控制 基于由温度检测器检测到的检测温度与根据进料的量设定的参考温度之间的比较。

公开(公告)号：EP1464616A2

公开(公告)日：2004-10-06

申请号：EP04013377.9

申请日：2000-09-06

申请人： DaimlerChrysler AG

发明人： Autenrieth, Rainer ,  Docter, Andreas Dr. ,  Wiesheu, Norbert

IPC分类号： C01B3/38 ,  C01B3/32 ,  B01J8/02 ,  B01J12/00

CPC分类号： B01J8/0278 ,  B01J8/008 ,  B01J8/0285 ,  B01J12/007 ,  B01J2208/00407 ,  B01J2208/00415 ,  B01J2208/00716 ,  C01B3/323 ,  C01B3/38 ,  C01B3/382 ,  C01B2203/00 ,  C01B2203/0244 ,  C01B2203/066 ,  C01B2203/0844 ,  C01B2203/085 ,  C01B2203/1223 ,  C01B2203/142 ,  C01B2203/1604 ,  C01B2203/1619 ,  C01B2203/82

摘要： Ein Reaktorsystem dient zur Umsetzung eines Kohlenwasserstoff- oder Kohlenwasserstoffderivat-Einsatzstoffs. Es umfasst einem katalysatorbelegten Reaktionsraum, dem wenigstens ein Reaktionseduktstrom über einen Reaktionsraumeintritt zuführbar ist, und elektrische Heizmitteln, die eine vor dem Reaktionsraumeintritt befindliche elektrische Heizvorrichtung zum Aufheizen wenigstens eines Reaktionseduktes in einer Startbetriebsphase beinhalten.
Dabei weisen die elektrischen Heizmittel Mittel zum punktuellen Einbringen des wenigstens einen in der Heizvorrichtung (41) aufgeheizten Reaktionseduktes in den Reaktionsraum (45) an einer oder mehreren Stellen des Eintrittsquerschnitts (47) für Reaktionsedukte auf.

摘要翻译： 反应器系统改变烃燃料或烃衍生物。 反应器具有催化反应室（45），其具有用于反应液流的流动供应的入口（46）和在起动阶段中操作的电加热元件（41）。 加热器加热在入口全横截面积（47）上的一个或多个选定点（43）处释放的空气。 在启动阶段期间，反应液流（44）在有限的横截面积（43）上被供应到腔室（45）。 在正常操作期间，通过整个横截面积（47）提供喷射。