Abstract:
The invention relates to a process for the preparation of a hollow filament (F) based on one or several molten or dissolved hyperbranched polymers (P) and potentially one or several further polymers (FP), characterized in that the molten or dissolved hyperbranched polymer (P) or the mixture of the hyperbranched polymer (P) with the further polymer (FP) is passed through one or several spinnerets (S), wherein the ratio between the spinneret die-length (L) and the die-channel (Delta-D) is between 0.1 and 9.5. The process can be applied for the preparation of hyperbranched polyethersulfone (HPES) hollow filaments.
Abstract:
A thermoplastic molding material comprising: A) from 40 to 97.9% by weight of at least one polyether sulfone, B) from 2 to 59.9% by weight of at least one polysulfone, C) from 0.1 to 2% by weight of stearic acid, and optionally further additives and assistants, has an improved flowability, surface quality and notched impact resistance, and can be used to construct floodlights.
Abstract:
The present invention relates to thermoplastic molding compounds containing a mixture of the following: A) at least one methyl methacrylate polymer; B) at least one copolymer, obtainable by the polymerization of a mixture consisting of (B1) at least one vinyl aromatic monomer and (B2) at least one vinyl cyanide as monomers; C) at least one graft copolymer, obtainable from a core and a first graft shell and a second graft shell; D) at least one poly(butyl acrylate) with a molecular weight of 1700 to 4000 g/mol (determined as the MW by gel permeation chromatography); and E) optionally, conventional additives as component (E); a method for the production of these thermoplastic molding compounds, the use of these thermoplastic molding compounds for the production of molded objects, and the use of styrene-methyl methacrylate copolymers with a molecular weight of 1700 to 4000 g/mol (determined as the MW by gel permeation chromatography) for improving the flowability and reducing the dependence of the impact strength and the haze value of thermoplastic molding compounds on injection conditions.
Abstract:
Thermoplastic moulding compositions comprising: A) from 40 to 96% by weight of a partly aromatic polyamide, B) from 2 to 30% by weight of a copolymer of B1) from 35 to 89.9% by weight of ethylene, B2) from 10 to 60% by weight of 1-octene or 1-butene or propylene or a mixture thereof and B3) from 0.05 to 5% by weight of functional monomers selected from the group consisting of carboxylic acid, carboxylic anhydride, carboxylic ester, carboxamide, carboximide, amino, hydroxyl, epoxide, urethane and oxazoline groups and mixtures thereof, C) from 1 to 50% by weight of fibrous or particulate fillers or mixtures thereof, D) from 0.1 to 10% by weight of D1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg of KOH/g of polycarbonate (in accordance with DIN 53240, Part 2) or D2) at least one highly branched or hyperbranched polyester of the AxBy type where x is at least 1.1 and y is at least 2.1 or a mixture thereof, E) from 0 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of further additives, where the sum of the percentages by weight of the components A) to F) is 100%.
Abstract:
Thermoplastic molding materials comprising A) from 10 to 69% by weight of a thermoplastic polyester, B) from 30 to 79% by weight of an aluminum oxide, C) from 0.01 to 10% by weight of an organic or inorganic acid or mixtures thereof, D) from 0 to 10% by weight of D1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2) or D2) at least one highly branched or hyperbranched polyester of the AxBy type where x is at least 1.1 and y is at least 2.1 or mixtures thereof, E) from 0 to 50% by weight of further additives, where the sum of the percentages by weight of components A) to E) adds up to 100%.
Abstract:
Thermoplastic moulding compositions comprising A) from 40 to 96.2% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of an impact-modifying polymer which contains functional groups, C) from 1 to 50% by weight of fibrous or particulate fillers or a mixture of these, D) from 0.2 to 5% by weight of a lubricant, E) from 0.5 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of other additives, where the total of the percentages by weight of components A) to F) is 100%.
Abstract:
The present invention relates to a process for preparation of polysulphones with Yellowness Index to DIN 6167 smaller than 19 and of polyether sulphones with Yellowness Index to DIN 6167 smaller than 30, characterized in that the polymerization reaction is carried out in basic, aprotic solvents, using a mechanical agitator which passes close to the wall. The present invention also relates to the polyether sulphones and polysulphones obtainable for the first time by this process, and to the use of these polymers for production of mouldings, foils, membranes and foams.
Abstract:
A thermoplastic moulding composition with improved metal plating properties is provided. This thermoplastic moulding composition is produced from a graft copolymer (A) a thermoplastic polymer (B) and a thermoplastic polymer (C) that is not, or only to a limited amount miscible with the thermoplastic polymer (B). The thermoplastic polymer (C) contains from 1 to 10 % by weight of at least one monoethylenically unsaturated monomer, like acrylic acid, methacrylic acid, or dicarboxylic acids, such as maleic acid and fumaric acid and their anhydrides, such as maleic anhydride. The vinyl aromatic content of component (C) is at least 5 units lower compared to that of component (B). The graft copolymer is produced from a soft elastomeric particulate graft base with a glass transition temperature below 0°C obtained by emulsion polymerization of a conjugated diene alone or with a small amount of a monoethylenically unsaturated monomer or of at least one C1-8-alkyl acrylate, or of mixtures of these, upon which is grafted a vinyl aromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer.