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    FORMMASSE MIT VERMINDERTER LICHTSTREUUNG
    2.
    发明公开
    FORMMASSE MIT VERMINDERTER LICHTSTREUUNG 有权
    具有减少扩频LIGHT成型材料

    公开(公告)号：EP2566921A1

    公开(公告)日：2013-03-13

    申请号：EP11715558.0

    申请日：2011-04-21

    Applicant: BASF SE

    Inventor： NIESSNER, Norbert

    IPC: C08L25/12 ,  C08L33/00 ,  C08L33/08 ,  C08L35/04 ,  C08L35/06

    CPC classification number: C08L25/12 ,  C08L33/00 ,  C08L33/08 ,  C08L33/18 ,  C08L35/04 ,  C08L35/06 ,  C08L2205/02 ,  C08L2205/03 ,  C08L51/003

    Abstract: The present invention relates to a moulding composition comprising (A) 30% to 85% by weight of a copolymer comprising as structural units at least one α,β-unsaturated monocarbonitrile in amounts of at least 30% by weight, based on the total weight of component (A), and at least one aromatic vinyl monomer as component (A), (B) 10% to 40% by weight of a graft rubber having an average particle size of 100 to 280 nm, comprising a graft base b1, composed of at least one α,β-unsaturated monocarboxylic ester, and at least one graft shell b2, composed of at least one aromatic vinyl monomer and at least one α,β-unsaturated monocarbonitrile as component (B), (C) 5% to 30% by weight of a graft rubber having an average particle size of 410 to 1000 nm, comprising a graft base c1, composed of at least one α,β-unsaturated monocarboxylic ester, and at least one graft shell c2, composed of at least one aromatic vinyl polymer and at least one α,β-unsaturated monocarbonitrile as component (C), and (D) 0% to 10% by weight of additives as component (D), the sum of the amounts of components (A), (B), (C) and (D) being 100% by weight, it being essential to the invention that the weight ratio of component (B) to component (C) is in the range from 3:1 to 1 :1 and that the amount of the α,β-unsaturated monocarbonitrile in component (B), in % by weight relative to the total weight of the graft shell b2, and in component (C), in % by weight relative to the total weight of the graft shell c2, is in each case 5 to 10 percentage points below the amount of α,β-unsaturated monocarbonitrile of component (A), in % by weight relative to the total weight of component (A), and also to processes for preparing these moulding compositions, to the use of these moulding compositions for producing films, mouldings or fibres, and also to these films, mouldings or fibres themselves.

    THERMOPLASTIC MOULDING COMPOSITIONS FOR METAL PLATED ARTICLES WITH IMPROVED RESISTANCE AGAINST REPEATED IMPACT
    4.
    发明公开
    THERMOPLASTIC MOULDING COMPOSITIONS FOR METAL PLATED ARTICLES WITH IMPROVED RESISTANCE AGAINST REPEATED IMPACT 审中-公开
    热塑性模塑化合物具有改善耐反复影响影响金属镀覆的产品

    公开(公告)号：EP2652035A1

    公开(公告)日：2013-10-23

    申请号：EP11794523.8

    申请日：2011-12-15

    Applicant: BASF SE

    Inventor： PEPERS, Michel ,  SCHADE, Christian ,  SUWIER, Davy Roger ,  NIESSNER, Norbert

    IPC: C08L25/12 ,  C08L33/20 ,  C08L51/00 ,  C08L55/02 ,  C23C18/31 ,  C08L21/00

    CPC classification number: C08L25/12 ,  C08L9/00 ,  C08L21/00 ,  C08L25/10 ,  C08L51/00 ,  C08L55/02 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2207/04 ,  C23C18/1601 ,  C23C18/1641 ,  C23C18/31 ,  C25D5/14 ,  C25D5/56 ,  Y10T428/31696

    Abstract: Thermoplastic moulding composition (F), comprising: A) from 5 to 80% by weight of a graft polymer (A) having bimodal particle size distribution and a moisture content of 0 to 27 % by weight, made, based on (A), a1) from 40 to 90% by weight of an elastomeric particulate graft base (a1), obtained by emulsion polymerization of, based on (a1), a11) from 70 to 100% by weight of at least one conjugated diene, or of at least one C1-8 -alkyl acrylate, or of mixtures of these, a12) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer and a13) from 0 to 10% by weight of at least one polyfunctional, cross linking monomer; a2) from 10 to 60% by weight of a graft a2), made, based on a2), a21) from 64 to 76% by weight of at least one vinyl aromatic monomer, a22) from 24 to 36% by weight of acrylonitrile, a23) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer, and a24) from 0 to 10% by weight of at least one polyfunctional, cross linking monomer; B) from 10 to 94% by weight of a thermoplastic polymer (B) having a viscosity number VN of from 50 to 120 ml/g, made, based on (B), b1) from 64 to 72% by weight of at least one vinyl aromatic monomer, b2) from 28 to 36% by weight of acrylonitrile, and b3) from 0 to 4 % by weight of at least one other monoethylenically unsaturated monomer; whereby, the difference of the acrylonitrile content in component (B) and that in the graft shell a2) is minimal 2% by weight and maximal 6% by weight and optionally further components, have preferred optical appearance when coated with metal.

    Abstract translation: 热塑性模塑组合物（F）包括：a）5至80重量％的具有双峰粒度分布和按重量计0至27％的水分含量的接枝聚合物（A）的，由基于（A） A1）40至90重量％的（在弹性体颗粒接枝基底a1）中，通过乳液聚合，基于（a1）中，A11）为70〜100％（重量）至少一种共轭二烯，或在获得 至少一个C 1-8烷基丙烯酸酯或论文的混合物，A12）从0至30％的按重量计从0至10％的至少一种其它单烯属不饱和单体和A13）的重量的至少一种多官能，交联的 单体; A2）为10（重量）的接枝a2的），由从64到76％，从24到36％60％，基于a2）中，A21）（重量）的至少一种乙烯基芳族单体，A22）的丙烯腈 ，A23）0至30重量％的至少一种其它单烯属不饱和单体，和A24）0至10重量％的至少一种多官能，交联单体的; B）从10至94％（重量）的粘度值VN的热塑性聚合物（B）的50至120毫升/克，由基于（B），B1）为64〜72％（重量）的至少 一种乙烯基芳族单体，b2）的从28重量丙烯腈36％和b3）0至（重量）的至少一种其它单烯属不饱和单体的4％; 由此，丙烯腈的含量的组分（B）中的接枝外壳A2中的差和所做的那样）为至少2重量％，按重量计最多为6％和任选的其他组分，都优选光学外观当用金属涂覆。

    THERMOPLASTIC MOULDING COMPOSITIONS WITH IMPROVED ADHESION OF ELECTROPLATED METAL LAYER
    10.
    发明公开
    THERMOPLASTIC MOULDING COMPOSITIONS WITH IMPROVED ADHESION OF ELECTROPLATED METAL LAYER 有权
    WITH电镀金属层的改进的责任热塑性模塑材料

    公开(公告)号：EP1940950A1

    公开(公告)日：2008-07-09

    申请号：EP06793488.5

    申请日：2006-09-13

    Applicant: BASF SE

    Inventor： DUIJZINGS, Wil ,  SUWIER, Davy, Roger ,  WEBER, Martin ,  SCHNEIDER, Erich ,  PEPERS, Michel ,  WENDEL, Klaus ,  NIESSNER, Norbert

    IPC: C08L51/00 ,  C08L25/12 ,  C08L33/20

    CPC classification number: C08L25/12 ,  C08L33/20 ,  C08L35/06 ,  C08L51/003 ,  C08L2205/02 ,  C08L2205/035 ,  C08L2666/02 ,  C08L2666/04

    Abstract: A thermoplastic moulding composition with improved metal plating properties is provided. This thermoplastic moulding composition is produced from a graft copolymer (A) a thermoplastic polymer (B) and a thermoplastic polymer (C) that is not, or only to a limited amount miscible with the thermoplastic polymer (B). The thermoplastic polymer (C) contains from 1 to 10 % by weight of at least one monoethylenically unsaturated monomer, like acrylic acid, methacrylic acid, or dicarboxylic acids, such as maleic acid and fumaric acid and their anhydrides, such as maleic anhydride. The vinyl aromatic content of component (C) is at least 5 units lower compared to that of component (B). The graft copolymer is produced from a soft elastomeric particulate graft base with a glass transition temperature below 0°C obtained by emulsion polymerization of a conjugated diene alone or with a small amount of a monoethylenically unsaturated monomer or of at least one C1-8-alkyl acrylate, or of mixtures of these, upon which is grafted a vinyl aromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer.

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