公开(公告)号：EP3233966A1

公开(公告)日：2017-10-25

申请号：EP15813764.6

申请日：2015-12-15

Applicant: BASF SE

Inventor： ERNST, Martin

IPC: C08G65/14 ,  C08G65/26 ,  C08G65/332

CPC classification number: C08G65/2609 ,  C04B24/2647 ,  C04B24/267 ,  C04B24/32 ,  C04B2103/30 ,  C08G65/14 ,  C08G65/3324 ,  C08G2650/08

Abstract: The invention relates to a method for producing monoethylenically unsaturated closed alkyl polyalkylene glycols, said polyalkylene glycols obtained according to said method and to the use thereof.

Abstract translation: 本发明涉及生产单烯属不饱和闭合烷基聚亚烷基二醇的方法，所述聚亚烷基二醇根据所述方法获得，并涉及其用途。

公开(公告)号：EP3209707A1

公开(公告)日：2017-08-30

申请号：EP15784296.4

申请日：2015-10-08

Applicant: BASF SE

Inventor： ERNST, Martin ,  FESSENBECKER, Achim

IPC: C08G65/336 ,  C08G65/22 ,  C04B24/42

CPC classification number: C04B24/42 ,  C04B14/02 ,  C04B28/006 ,  C04B28/02 ,  C04B2103/408 ,  Y02P40/165

Abstract: The invention relates to mono- and bisalkylene trialkoxysilanes of general formula (I), wherein –Y– stands for –O– or –N(R
9 )
2-a –; each –Z– is the same or different and is selected from the group consisting of –O– and –CHR
4b –; a stands for 1 if –Y– equals –O– and for 1 or 2 if –Y– equals –N(R
9 )
2-a –; m is a natural number from 1 to 20; n is a natural number from 7 to 200; each R
1 is the same or different and is selected from the group consisting of methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, and phenyl; and R
2 , R
3 , R
4a , R
4b , R
5 , R
6 , R
7 , R
8 , and R
9 each stand independently for H, suitable linear or branched C
1 -C
20 alkyl or possibly C
2 -C
20 alkenyl, C
2 -C
20 alkynyl, C
1 -C
20 alkanoyl, C
3 -C
20 alkenoyl, ω-carboxy-(C
1 -C
6 alkyl)carbonyl, and ω-carboxy-(C
2 -C
6 alkenyl)carbonyl and/or C
7 -C
20 aryloyl. The invention further relates to methods for producing said mono- and bisalkylene trialkoxysilanes, the to use of said mono- and bisalkylene trialkoxysilanes as dispersants in aqueous suspensions of gravels and of hydraulic binders, and to said aqueous suspensions as such.

Abstract translation: 本发明涉及通式（I）的单和双亚烷基三烷氧基硅烷，其中-Y-代表-O-或-N（R 9）2-a-; 每个-Z-相同或不同，并且选自-O-和-CHR4b-; 如果-Y-等于-O-，则a代表1;如果-Y-等于-N（R9）2-a-，则代表1或2; m是1至20的自然数; n是7至200的自然数; 每个R 1相同或不同并且选自甲基，乙基，正丙基，异丙基，正丁基，异丁基，仲丁基，叔丁基和苯基; 和R 2，R 3，R 4a，R 4b，R 5，R 6，R 7，R 8和R 9各自独立代表H，适合的直链或支链C 1 -C 20烷基或可能的C 2 -C 20烯基，C 2 -C 20炔基， （C 1 -C 6烷基）羰基和ω-羧基 - （C 2 -C 6烯基）羰基和/或C 7 -C 20芳酰基。 本发明还涉及生产所述单亚烷基三烷氧基硅烷和双亚烷基三烷氧基硅烷的方法，所述单亚烷基三烷氧基硅烷和双亚烷基三烷氧基硅烷作为分散剂在砾石和水硬性粘结剂的水悬浮液中的用途，以及所述含水悬浮液本身。

公开(公告)号：EP3063188A1

公开(公告)日：2016-09-07

申请号：EP14790620.0

申请日：2014-10-30

Applicant: BASF SE

Inventor： MAITRO-VOGEL, Sophie ,  ERNST, Martin ,  SCHADE, Christian ,  TUZINA, Pavel ,  TRAN-THIEN, Hoang Trang ,  REIS-WALTHER, Eva-Maria ,  SHABELINA, Natalia ,  HILLESHEIM, Nina Susanne ,  SCHOLZ, Christian

IPC: C08F220/06 ,  C08F228/02

CPC classification number: C08F28/04 ,  C04B24/16 ,  C04B24/165 ,  C04B24/32 ,  C04B2103/30 ,  C04B2103/52 ,  C07C323/14 ,  C08F220/06 ,  C08F228/02

Abstract: Unsaturated compounds of the general formula (I) where R
1 , R
2 , R
3 are the same or different and are each independently H, CH
3 , R
4 is linear or branched C
1 -C
30 -alkylene, R
5 , R
6 are the same or different and are each independently, H, C
1 -C
20 -alkyl, C
3 -C
15 -cycloalkyl, aryl, -CH
2 -O-C
1 -C
20 -alkyl, -CH
2 -O-C
2 -C
20 -alkenyl, where R5 and R6 may together also form a C
3 -C
6 -alkylene, R
7 is the same or different and is independently H, C
1 -C
4 -alkyl, R
8 is C
1 -C
22 -alkyl, C
2 -C
22 -alkenyl, and n is an integer from 2 to 200. Mixtures and polymers comprising compounds of the general formula (I). A method for preparing polymers wherein a free-radical polymerization of monomers comprising unsaturated compounds of the general formula (I) is carried out. A method for preparing polymers comprising polymer-analogous reactions. The use of polymers containing compounds (I) as cement additives, grinding aids in the production of cement, additive to hydraulic binders, concrete plasticizers, reactive plasticizers for the production of plastics, rubber or latex, associative thickeners and antioxidants, or for the production of polyether siloxanes. Mixtures comprising such polymers.

Abstract translation: 包含通式（I）化合物的混合物和聚合物。 一种制备聚合物的方法，其中进行包含通式（I）的不饱和化合物的单体的自由基聚合。 一种制备包含聚合物 - 类似反应的聚合物的方法。 使用包含化合物（I）作为水泥添加剂的聚合物，水泥粘合剂的添加剂，混凝土增塑剂，用于制备塑料的反应性增塑剂，橡胶或胶乳，缔合增稠剂和抗氧化剂，或用于制备聚醚硅氧烷的助剂。 包含这种聚合物的混合物。

公开(公告)号：EP2125696B1

公开(公告)日：2012-10-31

申请号：EP07857794.7

申请日：2007-12-19

Applicant: BASF SE

Inventor： ERNST, Martin ,  HILL, Thomas ,  MAKARCZYK, Piotr ,  MELDER, Johann-Peter

IPC: C07C209/48 ,  C07C209/52

CPC classification number: C07C209/48 ,  C07C209/52 ,  C07C2601/14 ,  C07C211/36

公开(公告)号：EP1945603B1

公开(公告)日：2012-05-30

申请号：EP06819191.5

申请日：2006-10-31

Applicant: BASF SE

Inventor： ERNST, Martin ,  OEHLENSCHLÄGER, Steffen ,  KUHNKE, Frank ,  ROSS, Karl-Heinz ,  DEEG, Roland ,  MELDER, Johann-Peter

IPC: C07C209/48 ,  C07C211/11 ,  B01J10/00 ,  B01J8/20 ,  B01D3/14

CPC classification number: B01J8/20 ,  B01D3/14 ,  B01J2219/00006 ,  B01J2219/00029 ,  B01J2219/0004 ,  C07C209/48 ,  C07C211/11

Abstract: The invention relates to a diamine industrially producing method from a corresponding alkenile-nitrile which contains at least one C-C double bond consisting (a) in reacting the alkenile-nitrile in a first reactor with a corresponding monoamine by exothermally adding a monoamine to said double bond in such a way that an aminoalkyle nitrile is obtained, wherein the monoamine and water are provided and the alkenile-nitrile is added, (b) in evaporating the unreacted alkenile-nitrile and aminoalkyle for enriching the aminoalkyle nitrile produces in the sump of the first reactor, (c) in transferring the aminoalkyle nitrile bottom product of the step (b) to a second reactor, (d) in batchwisely catalytically hydrogenating the aminoalkyle nitrile transferred at the step (c) in such a way that a diamine is produced in the second reactor, wherein for each batch, an appropriate catalyst and water for hydrogenating nitrils into amines, a desired diamine and a base are provided, the second reactor is supplied with hydrogen and the aminoalkyle nitrile transferred at the step (c) is proportioned therein, and (e) in extracting the diamine and in possibly repeating the steps from (a) to (e). A device for producing the diamine and the use of the devices are also disclosed. The preferred diamine is embodied in the form of a 3-dimethylaminopropylamine (DMAPA).

Abstract translation: 本发明涉及由含有至少一个CC双键的相应烯烃腈制备工业二胺的方法，其包括（a）通过将单胺向所述双键放热加成，使第一反应器中的烯烃腈与相应的单胺反应 从而获得氨基亚烷基腈，其中提供单胺和水并且加入烯烃腈，（b）蒸发未反应的烯烃腈和氨基烷烃以富集在第一槽的槽中产生的氨基亚烷基腈 （c）将步骤（b）的氨基亚烷基腈底部产物转移至第二反应器中，（d）分步催化氢化在步骤（c）中转移的氨基亚烷基腈，使得二胺在 第二反应器，其中对于每批次，提供用于将氮化合物氢化成胺的合适的催化剂和水，提供期望的二胺和碱，第二反应器 （c）中转移的氨基亚烷基腈在其中成比例，和（e）提取二胺，并且可能重复从（a）到（e）的步骤。 还公开了用于生产二胺的装置和这些装置的用途。 优选的二胺以3-二甲基氨基丙胺（DMAPA）的形式体现。

公开(公告)号：EP2346602A1

公开(公告)日：2011-07-27

申请号：EP09782817.2

申请日：2009-09-09

Applicant: BASF SE

Inventor： ERNST, Martin ,  STEIN, Bernd ,  MAAS, Steffen ,  PASTRE, Jörg ,  JOHANN, Thorsten ,  MELDER, Johann-Peter

IPC: B01J21/04 ,  B01J23/72 ,  C07C209/16 ,  C07C209/26 ,  C07C213/02 ,  C07D207/06 ,  C07D211/06 ,  C07D223/04 ,  C07D295/00 ,  C07C211/08 ,  C07C211/14 ,  C07C217/08 ,  C07C211/35

CPC classification number: B01J23/72 ,  B01J21/04 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/18 ,  C07C209/16 ,  C07C209/26 ,  C07C2601/14 ,  Y02P20/582 ,  C07C211/08 ,  C07C211/10 ,  C07C211/12 ,  C07C211/14 ,  C07C211/35

Abstract: The invention relates to a method for the continuous production of an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group comprising ammonia, and primary and secondary amines, at a temperature of between 60 and 300°C, in the presence of a catalyst containing copper and aluminium oxide, wherein the reaction takes place in the gas phase and the catalytically active mass of the catalyst before the reduction thereof with hydrogen contains between 20 and 75 wt. % of aluminium oxide (AI
2 O
3 ), between 20 and 75 wt. % of oxygen-containing compounds of copper, as CuO, between 0 and 2 wt. % of oxygen-containing compounds of sodium, as Na
2 O, and less than 5 wt. % of oxygen-containing compounds of nickel, as NiO. The catalyst moulded body has a tablet shape with a diameter of between 1 and 4 mm and a height of between 1 and 4 mm.

Abstract translation: 过程通过使伯醇或仲醇，醛和/或酮与氢气和范围选自氨，伯和仲cardamines的在温度选自60〜300的氮化合物的反应连续制备的胺 ℃，在催化剂包含氧化铜和氧化铝的存在，worin反应发生在气相中和之前用氢还原（重量）氧化铝的包含20至75％的催化剂的催化活性组合物（氧化铝 ），从20至75重量％的铜的含氧化合物，计算以CuO，从0％至2％（重量）钠的含氧化合物，以Na计2 O的，且小于5重量％的氧的 包含镍的化合物，计算方法为NiO和成型体催化剂具有的范围内的直径为1至4毫米，高度范围为1至4毫米的丸粒形状。

公开(公告)号：EP2197830A2

公开(公告)日：2010-06-23

申请号：EP08787270.1

申请日：2008-08-15

Applicant: BASF SE

Inventor： ERNST, Martin ,  HOFFER, Bram Willem ,  MELDER, Johann-Peter

IPC: C07C209/16 ,  C07D241/02 ,  C07D295/00 ,  C07C211/10 ,  C07C211/11

CPC classification number: C07C209/16 ,  C04B24/122 ,  C04B28/02 ,  C07C213/02 ,  C07D241/04 ,  C07D295/02 ,  C07D295/023 ,  C07C211/09 ,  C07C211/10 ,  C07C211/11 ,  C07C215/08

Abstract: The invention relates to a method for producing amines by reacting sugar alcohols with hydrogen and an amination agent, selected from the group containing ammonia, primary and secondary amines, in the presence of a catalyst at a temperature of between 100°C and 400°C and at a pressure of between 1 and 40 MPa (10 to 400 bar). The catalyst preferably contains a metal or several metals or one or more oxygen-containing compounds of metals in groups 8 and/or 9 and/or 10 and/or 11 of the periodic table of elements. Preferably, the sugar alcohol is obtained by the hydrogenation of the corresponding sugars. The invention also relates to the use of the reaction product as an additive in cement or concrete production and in other application areas.

Abstract translation: 本发明涉及通过使糖醇与氢和选自氨和伯胺和仲胺的胺化剂在催化剂存在下在100℃至400℃的温度下反应制备胺的方法 压力为1〜40MPa（10〜400巴）。 催化剂优选包含元素周期表第8和/或9族和/或10和/或11族的金属或多种金属或一种或多种氧化合物。 糖醇优选通过氢化相应的糖获得。 本发明还涉及反应产物在水泥或混凝土生产中和在其它使用领域中作为添加剂的用途。

公开(公告)号：EP1996322A1

公开(公告)日：2008-12-03

申请号：EP07726607.0

申请日：2007-03-02

Applicant: BASF SE

Inventor： ERNST, Martin ,  HAHN, Thilo ,  MELDER, Johann-Peter

IPC: B01J23/75 ,  B01J23/78 ,  B01J23/83 ,  B01J23/92 ,  B01J23/94 ,  C07C209/48 ,  C07C211/09

CPC classification number: B01J23/78 ,  B01J23/94 ,  B01J37/18 ,  C07C5/03 ,  C07C29/145 ,  C07C209/48 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2601/14 ,  C07C2601/18 ,  Y02P20/584 ,  C07C13/26 ,  C07C211/05 ,  C07C211/11 ,  C07C211/12 ,  C07C35/08

Abstract: Catalysts which are prepared by reduction of catalyst precursors and comprise a) cobalt and b) one or more elements of the alkali metal group, the alkaline earth metal group, the group of the rare earths or zinc or mixtures thereof, the elements a) and b) being present at least partly in the form of their mixed oxides, and a process for preparing these catalysts and their use for hydrogenating unsaturated organic compounds. Furthermore, a process is described for regenerating these catalysts by treating the catalyst with a liquid.

Abstract translation: 通过还原催化剂前体制备的催化剂，其包含a）钴和b）由稀土或锌组成的组中的碱金属基团的一种或多种元素或其混合物，元素a ）和b）至少部分以其混合氧化物的形式存在，以及制备这些催化剂的方法及其用于不饱和有机化合物氢化的用途。 此外，描述了通过用液体处理催化剂再生这些催化剂的方法。

公开(公告)号：EP1926702A2

公开(公告)日：2008-06-04

申请号：EP06793409.1

申请日：2006-09-11

Applicant: BASF SE

Inventor： HAHN, Thilo ,  ERNST, Martin ,  MELDER, Johann-Peter

IPC: C07C209/48 ,  C07C253/30 ,  B01J25/02

CPC classification number: C07C209/48 ,  B01J25/02 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The invention relates to a method for the hydrogenation of oligonitriles comprising at least two nitrile groups, in the presence of a catalyst, which is pre-treated by being brought into contact with a compound A prior to the hydrogenation process, said compound being selected from the following: alkaline metal carbonates, alkaline-earth metal carbonates, ammonium carbonate, alkaline metal hydrogencarbonates, alkaline-earth metal hydrogencarbonates, ammonium hydrogencarbonate, alkaline-earth metal oxocarbonates, alkaline metal carboxylates, alkaline-earth metal carboxylates, ammonium carboxylates, alkaline metal dihydrogen phosphates, alkaline-earth metal dihydrogen phosphates, alkaline metal hydrogen phosphates, alkaline-earth metal hydrogen phosphates, alkaline metal phosphates, alkaline-earth metal phosphates and ammonium phosphate, alkaline metal acetates, alkaline-earth metal acetates, ammonium acetate, alkaline metal formiates, alkaline-earth metal formiates, ammonium formiate, alkaline metal oxalates, alkaline-earth metal oxalates and ammonium oxalate.