公开(公告)号：EP3200891A2

公开(公告)日：2017-08-09

申请号：EP15777839.0

申请日：2015-09-29

申请人： Rennovia Inc.

发明人： DIAMOND, Gary M. ,  DIAS, Eric L. ,  ARCHER, Raymond H. ,  MURPHY, Vincent J. ,  BOUSSIE, Thomas R.

IPC分类号： B01D15/36 ,  C07C51/47

摘要： Processes for separating a di-carboxylic acid or salt thereof from a mixture containing the di-carboxylic acid or salt thereof and one or more other components are provided. Also separation media useful for these separation processes is provided. In particular, processes for preparing an aldaric acid are described, such as glucaric acid from glucose, which includes separating the aldaric acid from the reaction product. Also, various glucaric acid products are described.

摘要翻译： 提供了从含有二羧酸或其盐和一种或多种其它组分的混合物中分离二羧酸或其盐的方法。 还提供了用于这些分离过程的分离介质。 具体而言，描述了制备醛糖酸的方法，例如来自葡萄糖的葡糖二酸，其包括从反应产物中分离醛糖酸。 另外，描述了各种葡糖二酸产品。

公开(公告)号：EP2542519A1

公开(公告)日：2013-01-09

申请号：EP10812827.3

申请日：2010-12-13

申请人： Rennovia, Inc.

发明人： BOUSSIE, Thomas, R. ,  DIAS, Eric, L. ,  FRESCO, Zachary, M. ,  MURPHY, Vincent, J. ,  SHOEMAKER, James ,  ARCHER, Raymond ,  JIANG, Hong

IPC分类号： C07C55/14

CPC分类号： C07C55/14 ,  C07C51/377 ,  C07C51/43 ,  C07D309/30 ,  C08G63/12 ,  C08G69/26 ,  C07C55/10

摘要： Disclosed are compositions of matter comprising an adipic acid product of formula (1) wherein R is independently a salt-forming ion, hydrogen, hydrocarbyl, or substituted hydrocarbyl, and at least one constituent selected from the group consisting of formula (2) wherein R is as defined above and each of R1 is, independently, H, OH, acyloxy or substituted acyloxy provided, however, that at least one of R1 is OH, and formula (3) wherein R is as above defined and R1 is OH, acyloxy or substituted acyloxy. Also disclosed are compositions of matter comprising at least about 99 wt% adipic acid and least two constituents selected from the group consisting of formula (2) and formula (3), above.

摘要翻译： 公开了包含式（1）的己二酸产物的组合物，其中R独立地为成盐离子，氢，烃基或取代的烃基，和至少一种选自式（2）的成分，其中R 如上所定义且每个R 1独立地为H，OH，酰氧基或取代的酰氧基，然而，提供了至少一个R 1为OH和式（3）其中R如上所定义且R 1为OH，酰氧基 或取代的酰氧基。 还公开了包含至少约99重量％的己二酸和选自以上式（2）和式（3）的至少两种成分的物质组合物。

公开(公告)号：EP3099670A2

公开(公告)日：2016-12-07

申请号：EP15703214.5

申请日：2015-01-27

申请人： Rennovia Inc.

发明人： BOUSSIE, Thomas, R. ,  DIAS, Eric, L. ,  MURPHY, Vincent, J. ,  SHOEMAKER, James, A.

IPC分类号： C07D307/46

CPC分类号： C07D307/46 ,  B01D61/027 ,  B01D61/145 ,  B01D2311/02 ,  B01D2311/25 ,  C07D307/50

摘要： The present invention relates generally to processes for converting fructose-containing feedstocks to a product comprising 5-(hydroxymethyl)furfural (HMF) and water in the presence of water, solvent and an acid catalyst. In some embodiments, the conversion of fructose to HMF is controlled at a partial conversion endpoint characterized by a yield of HMF from fructose that does not exceed about 80 mol %. In these and other embodiments, the processes provide separation techniques for separating and recovering the product, unconverted fructose, solvent and acid catalyst to enable the effective recovery and reutilization of reaction components.

摘要翻译： 本发明一般涉及在水，溶剂和酸催化剂的存在下将含果糖的原料转化成包含5-（羟甲基）糠醛（HMF）和水的产物的方法。 在一些实施方案中，将果糖转化成HMF的部分转化终点被控制，其特征在于果糖的HMF的产率不超过约80mol％。 在这些和其它实施方案中，该方法提供了用于分离和回收产物，未转化的果糖，溶剂和酸催化剂的分离技术，以使得能够有效地回收和再利用反应组分。

公开(公告)号：EP2697202B1

公开(公告)日：2015-07-22

申请号：EP12712859.3

申请日：2012-03-29

申请人： Rennovia, Inc.

发明人： MURPHY, Vincent, J. ,  DIAS, Eric, L. ,  SHOEMAKER, James, A.W. ,  BOUSSIE, Thomas, R. ,  FRESCO, Zachary, M.

IPC分类号： C07D223/10 ,  C07C233/47

CPC分类号： C07D223/10 ,  C07C227/16 ,  C07C231/02 ,  C07C231/12 ,  C08G69/16 ,  C07C233/47 ,  C07C229/08

公开(公告)号：EP2817293A1

公开(公告)日：2014-12-31

申请号：EP13705896.2

申请日：2013-02-13

申请人： Rennovia, Inc.

发明人： DIAS, Eric L. ,  MURPHY, Vincent J. ,  LONGMIRE, James ,  JIANG, Hong

IPC分类号： C07D223/10 ,  C07D201/08 ,  B01J21/06 ,  B01J23/36 ,  B01J23/46

CPC分类号： C07D223/10 ,  B01J23/40 ,  B01J23/6525 ,  B01J23/6567 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/8926 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/18 ,  C07D201/08 ,  Y02P20/52

摘要： Processes are disclosed for the conversion of adipic acid to caprolactam employing a chemocatalytic reaction in which an adipic acid substrate is reacted with ammonia and hydrogen, in the presence of particular heterogeneous catalysts and employing unique solvents. The present invention also enables the conversion of other adipic acid substrates, such as mono-esters of adipic acid, di-esters of adipic acid, mono-amides of adipic acid, di-amides of adipic acid, and salts thereof to caprolactam. Solvents useful in the process that do not react with ammonia are also disclosed. Catalyst supports are disclosed which catalyze the reaction of the substrate with ammonia in the absence of added metal. Metals on the catalyst supports comprise ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir), and/or platinum (Pt). Heterogeneous catalysts comprising ruthenium (Ru) and rhenium (Re) on titania and/or zirconia supports are also disclosed. Further, disclosed are products produced by such processes, as well as products producible from such products.

公开(公告)号：EP2858748B1

公开(公告)日：2018-04-11

申请号：EP13730095.0

申请日：2013-06-11

申请人： Rennovia Inc.

发明人： DIAS, Eric, L. ,  MURPHY, Vincent, J. ,  SHOEMAKER, James, A.W.

IPC分类号： B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  C07C51/235 ,  C07C55/14 ,  B01J21/06 ,  B01J35/10

CPC分类号： C07C51/235 ,  B01J21/066 ,  B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  B01J23/6527 ,  B01J23/687 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  C07C55/14

摘要： Processes are disclosed for the conversion of 1,6-hexanediol to adipic acid employing a chemocatalytic reaction in which 1,6-hexanediol is reacted with oxygen in the presence of particular heterogeneous catalysts including at least one of platinum or gold. The metals are preferably provided on a support selected from the group of titania, stabilized titania, zirconia, stabilized zirconia, silica or mixtures thereof, most preferably zirconia stabilized with tungsten. The reaction with oxygen is carried out at a temperature from about 100° C. to about 300° C. and at a partial pressure of oxygen from about 50 psig to about 2000 psig.

公开(公告)号：EP3227268A2

公开(公告)日：2017-10-11

申请号：EP15819920.8

申请日：2015-12-02

申请人： Rennovia Inc.

发明人： SOKOLOVSKII, Valery ,  LAVRENKO, Mayya ,  HAGEMEYER, Alfred ,  DIAS, Eric L. ,  SHOEMAKER, James A.W. ,  MURPHY, Vincent J.

IPC分类号： C07D307/12 ,  C07D307/28 ,  C07D307/42 ,  C07C29/132 ,  C07C29/60 ,  C07C31/20 ,  C07C31/22

CPC分类号： C07D307/28 ,  B01J8/04 ,  B01J2208/027 ,  C07C29/09 ,  C07C29/103 ,  C07C29/132 ,  C07C29/172 ,  C07C29/60 ,  C07D307/12 ,  C07D307/42 ,  C07C31/22 ,  C07C31/20

摘要： Industrial scale conversions of 5-hydroxymethylfurfural to commodity chemicals such as 1,2,6-hexanetriol and 1,6-hexanediol by chemocatalytic conversions using hydrogen and a heterogeneous reduction catalyst are provided. The reactions are suitable for use in continuous flow reactors. Methods of carrying out the conversions are provided, as are product and catalyst compositions.

摘要翻译： 提供了通过使用氢和非均相还原催化剂的化学催化转化将5-羟甲基糠醛转化为商品化学品如1,2,6-己三醇和1,6-己二醇的工业规模转化。 该反应适用于连续流动反应器。 提供了进行转化的方法，以及产物和催化剂组合物。

公开(公告)号：EP3036213A1

公开(公告)日：2016-06-29

申请号：EP14772484.3

申请日：2014-08-22

申请人： Rennovia Inc.

发明人： MURPHY, Vincent J. ,  DIAS, Eric L. ,  SHOEMAKER, James A. W.

IPC分类号： C07C29/149 ,  B01J23/42

CPC分类号： C07C29/149 ,  B01J23/6525 ,  B01J23/6527 ,  B01J23/6567 ,  B01J37/08 ,  B01J37/18 ,  C07C31/20

摘要： Processes are disclosed for the conversion of adipic acid to 1,6-hexanediol employing a chemocatalytic reaction in which an adipic acid substrate is reacted with hydrogen in the presence of particular heterogeneous catalysts including a first metal and a second metal on a support. The adipic acid substrate includes adipic acid, mono-esters of adipic acid, di-esters of adipic acid, and salts thereof. The first metal is selected form the group of Pt, Rh and mixtures thereof and the second metal is selected from the group of Mo, W, Re and mixtures thereof.

公开(公告)号：EP2858748A2

公开(公告)日：2015-04-15

申请号：EP13730095.0

申请日：2013-06-11

申请人： Rennovia, Inc.

发明人： DIAS, Eric, L. ,  MURPHY, Vincent, J. ,  SHOEMAKER, James, A.W.

IPC分类号： B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  C07C51/235 ,  C07C55/14 ,  B01J21/06 ,  B01J35/10

CPC分类号： C07C51/235 ,  B01J21/066 ,  B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  B01J23/6527 ,  B01J23/687 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  C07C55/14

摘要： Processes are disclosed for the conversion of 1,6-hexanediol to adipic acid employing a chemocatalytic reaction in which 1,6-hexanediol is reacted with oxygen in the presence of particular heterogeneous catalysts including at least one of platinum or gold. The metals are preferably provided on a support selected from the group of titania, stabilized titania, zirconia, stabilized zirconia, silica or mixtures thereof, most preferably zirconia stabilized with tungsten. The reaction with oxygen is carried out at a temperature from about 100° C. to about 300° C. and at a partial pressure of oxygen from about 50 psig to about 2000 psig.

摘要翻译： 公开了使用化学催化反应将1,6-己二醇转化为己二酸的方法，其中1,6-己二醇在特定的非均相催化剂（包括至少一种铂或金）存在下与氧反应。 金属优选提供在选自二氧化钛，稳定的二氧化钛，氧化锆，稳定的氧化锆，二氧化硅或其混合物，最优选用钨稳定的氧化锆的载体上。 与氧的反应在约100℃至约300℃的温度和约50psig至约2000psig的氧分压下进行。

公开(公告)号：EP2791104A2

公开(公告)日：2014-10-22

申请号：EP12799459.8

申请日：2012-11-30

申请人： Rennovia, Inc.

发明人： ARCHER, Raymond ,  DIAMOND, Gary, M. ,  DIAS, Eric, L. ,  MURPHY, Vincent, J. ,  PETRO, Miroslav ,  SUPER, John, D.

IPC分类号： C07C209/00 ,  C07C253/00 ,  C07C51/377 ,  C07C51/41

CPC分类号： C07C51/347 ,  C07C51/09 ,  C07C51/377 ,  C07C51/412 ,  C07C209/00 ,  C07C55/14 ,  C07C211/12

摘要： The present disclosure relates generally to water concentration reduction processes within an adipic acid process. The present invention also includes process for converting a glucose-containing feed derived from a carbohydrate source to an adipic acid product wherein the process includes the steps of: converting glucose in the feed to a reaction product including a hydrodeoxygenation substrate and a first concentration of water; reducing the concentration of water in the reaction product to produce a feedstock including the hydrodeoxygenation substrate and second concentration of water, wherein the second concentration of water is less than the first concentration of water; and converting at least a portion of the hydrodeoxygenation substrate in the feedstock to an adipic acid product. Processes are also disclosed for producing hexamethylene diamine and caprolactam from the adipic acid product.

摘要翻译： 本公开一般涉及己二酸方法中的水浓缩还原方法。 本发明还包括将源自碳水化合物源的含葡萄糖的饲料转化为己二酸产物的方法，其中该方法包括以下步骤：将饲料中的葡萄糖转化为包括加氢脱氧底物和第一浓度的水的反应产物 ; 降低反应产物中的水分浓度以产生包括加氢脱氧底物和第二浓度水的原料，其中第二浓度的水小于第一浓度的水; 并将原料中的至少一部分加氢脱氧底物转化为己二酸产物。 还公开了从己二酸产物制备己二胺和己内酰胺的方法。