摘要:
For example, a development defect reducing composite made of an acidic composite containing a surface-active agent is applied to a chemically amplified photoresist film formed on a substrate of 8 inches or more. As a result, the resist surface is made hydrophilic, and a hardly soluble layer with respect to a developing liquid is prevented from being formed on the resist surface. By the acid diffusion of a proper amount from the developing defect reducing composite, moreover, the reduction in the film thickness of the chemically amplified photoresist after exposed and developed is greater by 10 angstroms to 500 angstroms than that of when the development defect reducing composite is not applied, a resist pattern such as a T-top or a round top having no degradation in the pattern shape is formed.
摘要:
A composition for antireflection coating comprising (a) polyacrylic acid, (b) polyvinylpyrrolidone, (c) CnF2n+1COOH (n is an integer of 3 to 11), and (d) tetramethylammonium hydroxide is applied to a photoresist film to form an antireflection film. The coated photoresist film is exposed to light and developed to obtain a resist pattern of a satisfactory shape free from T-tops, round tops, etc.
摘要:
A composition for preventing development defects which contains (1) a salt of a C4-15 perfluoroalkylcarboxylic acid, C4-10 perfluoroalkylsulfonic acid, or perfluoroadipic acid with ammonium, a tetraalkylammonium, or a C1-4 alkanolamine or (2) a salt of an inorganic acid with a quaternary fluoroalkylammonium salt, and in which the acid/base equivalent ratio is from 1/1 to 1/3. This composition is applied to a positive-acting chemical amplification type photoresist film formed on a substrate having a diameter as large as 8 inches or more. Before and/or after application of the composition for preventing development defects, the chemical amplification type photoresist film is baked. This photoresist film is subjected to exposure and post-exposure baking and is then developed. Thus, the decrease in photoresist film thickness through development can be larger by 100 to 600 Å than that in the case where the composition for preventing development defects is not applied. Development defects on substrates having a diameter as large as 8 inches or more are diminished, and resist patterns having a satisfactory sectional shape free from T-top or the like are formed.
摘要:
The present invention provides a composition for forming a top anti-reflection coating having a low refractive index, realizing a gradual swing curve and giving a small swing ratio. This composition comprises a solvent and an anthracene skeleton-containing polymer having a hydrophilic group. The composition forms an anti-reflection coating on a photoresist film, and can be used in a photolithographic process for forming a pattern by use of light having a wavelength of 160 to 260 nm.