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1.发明公开VERFAHREN ZUR HEMMUNG DER UNERWÜNSCHTEN RADIKALISCHEN POLYMERISATION VON IN EINER FLÜSSIGEN PHASE P BEFINDLICHER ACRYLSÄURE 审中-公开一种用于在液相P BEFINDLICHER丙烯酸抑制不想要自由基聚合
公开(公告)号：EP2625159A1
公开(公告)日：2013-08-14
申请号：EP11771064.0
申请日：2011-10-04
Applicant: BASF SE
Inventor： BLUM, Till , ZUROWSKI, Peter , KORN, Tobias, Johannes , HAREMZA, Sylke , FRIESE, Thorsten , MARTIN, Friedrich-Georg , JÄGER, Ulrich , RISSEL, Steffen , SCHLIEPHAKE, Volker
Abstract: A process for inhibiting unwanted free-radical polymerization of acrylic acid present in a liquid phase P whose acrylic acid content is at least 10% by weight and which, based on the weight of the acrylic acid present therein, additionally comprises at least 100 ppm by weight of propionic acid and at least 100 ppm by weight of glyoxal, in which at least one chemical compound of the element copper is added to the liquid phase P, and the resulting liquid phases P to which a chemical compound of the element copper has been added.
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公开(公告)号：EP3331847B1
公开(公告)日：2019-10-09
申请号：EP16747502.9
申请日：2016-08-03
Applicant: BASF SE
Inventor： KORN, Tobias Johannes , BLUM, Till , CARLINE, Travis , FUCHS, Christopher , WELCH, Darryl , ZUROWSKI, Peter , SCHLIEPHAKE, Volker , RISSEL, Steffen , FRIESE, Thorsten , JAEGER, Ulrich , HAREMZA, Sylke
IPC: C07C51/235 , C07C57/04
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3.发明公开VERFAHREN ZUR ÜBERTRAGUNG VON WÄRME AUF EINE MONOMERE ACRYLSÄURE, ACRYLSÄURE-MICHAEL-OLIGOMERE UND ACRYLSÄUREPOLYMERISAT GELÖST ENTHALTENDE FLÜSSIGKEIT 审中-公开PROCEDURE用于将热量传递到MONOMERS丙烯酸，丙烯酸ACID MICHAEL低聚物和分辨丙烯酸聚合物含液体
公开(公告)号：EP2271422A2
公开(公告)日：2011-01-12
申请号：EP09738086.9
申请日：2009-04-27
Applicant: BASF SE
Inventor： BLUM, Till , ZUROWSKI, Peter , RISSEL, Steffen , HAREMZA, Sylke , FRIESE, Thorsten , JÄGER, Ulrich , SCHLIEPHAKE, Volker , MÜLLER-ENGEL, Klaus, Joachim , RUMPF, Bernd
CPC classification number: B01J19/0013 , B01J2219/00094
Abstract: A method is disclosed for transferring heat to a liquid F containing dissolved monomeric acrylic acid, acrylic acid oligomers obtained by Michael addition, and acrylic acid polymer with the help of an indirect heat exchanger to which the liquid F is fed at a temperature T
F ≥ 150°C and a heat transfer fluid W is fed at a temperature T
w > T
F . In said method, gas bubbles or thin layers of liquid F bordering a gas phase are generated in the liquid F while said liquid F flows through the heat exchanger.-
公开(公告)号：EP2782888B1
公开(公告)日：2018-01-03
申请号：EP12778343.9
申请日：2012-10-25
Applicant: BASF SE
Inventor： CRONE, Sven , RYLL, Oliver , BLUM, Till , WECK, Alexander , PAPP, Rainer , KROKOSZINSKI, Roland , BLANKERTZ, Heinrich-Josef
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5.发明公开VERFAHREN ZUR AUFTRENNUNG VON IN EINEM PRODUKTGASGEMISCH EINER PARTIELLEN HETEROGEN KATALYSIERTEN GASPHASENOXIDATION EINER C3-VORLÄUFERVERBINDING DER ACRYLSÄURE ALS HAUPTBESTANDTEIL ENTHALTENER ACRYLSÄURE UND ALS NEBENPRODUKT ENTHALTENEM GLYOXAL 有权FOR产品而产生的部分气相氧化的混合气体催化异类C3-VORLÄUFERVERBINDING丙烯酸为主要成分的分离法处理含丙烯酸和AS-产品含有乙二醛
公开(公告)号：EP2334631A1
公开(公告)日：2011-06-22
申请号：EP09780561.8
申请日：2009-07-14
Applicant: BASF SE
Inventor： BLUM, Till , ZUROWSKI, Peter , RISSEL, Steffen , HAREMZA, Sylke , FRIESE, Thorsten , JÄGER, Ulrich , SCHLIEPHAKE, Volker , MÜLLER-ENGEL, Klaus, Joachim , HAMMON, Ulrich , HEILEK, Jörg , MÜLLER, Imke, Britta
CPC classification number: C07C51/252 , C07C51/43 , C07C57/04
Abstract: The invention relates to a method for separating acrylic acid, contained as the main constituent and glyoxal, contained as a by-product from a gaseous product mixture of a partial gas phase oxidation of a C
3 precursor compound of acrylic acid. According to said method, a liquid phase P is created, 70 % of the total weight of which consists of acrylic acid and which contains at least 200 mol ppm of glyoxal in relation to the contained molar quantity of acrylic acid. The glyoxal is separated from the acrylic acid by crystallisation from the liquid phase P.Abstract translation: 一种用于分离丙烯酸本酸作为主要产物和乙二醛存在过程的副产物在C3前体化合物的部分气相氧化，其中液体相P被获得，其中besteht丙烯酸的产物气体混合物 到在它的重量，并且基于丙烯酸其中存在的摩尔量的至少70％的程度，包括乙二醛至少200摩尔ppm，其中乙二醛从丙烯酸在液相P通过结晶分离 ，
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Patent Agency Ranking
公开(公告)号：EP2004742A1
公开(公告)日：2008-12-24
申请号：EP07727567.5
申请日：2007-03-30
Applicant: BASF SE
Inventor： BLUM, Till , GLASER, Alban , SCHAMBONY, Simon , APPEL, Manfred
CPC classification number: C08K5/3435 , C08K5/0041 , C09B67/0002 , C09B67/0061
Abstract: The invention relates to a composition containing at least one piperidine compound of formula (I) as a stabiliser. In said formula (I) the variables R1, R2, R3, R4, R5, R6, R7, R8,Y and the index n have the meanings cited in claim 1 and the description. Said composition also comprises a polymer component and a colouring agent. The invention further relates to a method for producing pigment-containing polymer compositions and to the use of the compounds of formula (I) as dispersing auxiliary agents.
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7.发明授权VERFAHREN ZUR LAGERUNG EINER UNTER DEN BEDINGUNGEN DER LAGERUNG FLÜSSIGEN MONOMERENPHASE 有权METHOD FOR STORAGE STORAGE液体单体的条款
公开(公告)号：EP2129650B1
公开(公告)日：2016-08-24
申请号：EP08717908.1
申请日：2008-03-17
Applicant: BASF SE
Inventor： HEILEK, Jörg , HAMMON, Ulrich , SCHLIEPHAKE, Volker , MÜLLER-ENGEL, Klaus Joachim , BLUM, Till
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公开(公告)号：EP2004742B1
公开(公告)日：2011-07-27
申请号：EP07727567.5
申请日：2007-03-30
Applicant: BASF SE
Inventor： BLUM, Till , GLASER, Alban , SCHAMBONY, Simon , APPEL, Manfred
CPC classification number: C08K5/3435 , C08K5/0041 , C09B67/0002 , C09B67/0061
Abstract: The invention relates to a composition containing at least one piperidine compound of formula (I) as a stabiliser. In said formula (I) the variables R1, R2, R3, R4, R5, R6, R7, R8,Y and the index n have the meanings cited in claim 1 and the description. Said composition also comprises a polymer component and a colouring agent. The invention further relates to a method for producing pigment-containing polymer compositions and to the use of the compounds of formula (I) as dispersing auxiliary agents.
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9.发明公开VERFAHREN DES TRANSPORTS EINER AUS EINEM LAGERBEHÄLTER ENTNOMMENEN FLÜSSIGEN MONOMERENPHASE IM TANK EINES TANKWAGENS ODER EINES TANKSCHIFFS 有权交通从存储罐的方法中采取的液体单体中的桶的汽车或TANK船舶TANK
公开(公告)号：EP2129649A1
公开(公告)日：2009-12-09
申请号：EP08717909.9
申请日：2008-03-17
Applicant: BASF SE
Inventor： HEILEK, Jörg , HAMMON, Ulrich , SCHLIEPHAKE, Volker , MÜLLER-ENGEL, Klaus Joachim , BLUM, Till
IPC: C07C51/42 , C07C51/47 , C07C51/50 , C07C57/04 , C07C45/78 , C07C45/79 , C07C45/86 , C07C47/22 , C07C67/48 , C07C67/56 , C07C67/62 , C07C59/54
CPC classification number: C07C45/79 , C07C45/78 , C07C51/42 , C07C51/47 , C07C51/50 , C07C67/56 , C07C67/62 , C07C47/22 , C07C57/04 , C07C69/54
Abstract: The invention relates to a method for transporting a liquid monomer phase, which has been removed from a storage container, in a tanker lorry or tanker ship, said phase containing up to ≥ 90 % by weight methacryl monomers. According to said method, the liquid monomer phase is subjected to an isolation operation for isolating polymer contained in dissolved form in the liquid monomer phase from the monomer as said phase is removed from the storage container and transferred to the tank of a tanker lorry or a tanker ship.
Abstract translation: 一种用于输送已经从储存容器中取出，并通过包含甲基单体重量上的≧90％的程度在罐卡车或在油轮液体单体相，其中该液体单体相进行的处理 从储存容器的路线上分离操作进入罐卡车或油轮的罐，以溶解形式在液体单体相分离存在的单体的聚合物。
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公开(公告)号：EP3331847A1
公开(公告)日：2018-06-13
申请号：EP16747502.9
申请日：2016-08-03
Applicant: BASF SE
Inventor： KORN, Tobias Johannes , BLUM, Till , CARLINE, Travis , FUCHS, Christopher , WELCH, Darryl , ZUROWSKI, Peter , SCHLIEPHAKE, Volker , RISSEL, Steffen , FRIESE, Thorsten , JAEGER, Ulrich , HAREMZA, Sylke
IPC: C07C51/235 , C07C57/04
CPC classification number: C07C45/32 , C07C45/33 , C07C45/35 , C07C45/38 , C07C45/39 , C07C45/783 , C07C51/21 , C07C51/235 , C07C51/245 , C07C51/252 , C07C51/42 , C07C51/43 , C07C51/44 , C07C51/47 , C07C57/04
Abstract: A process for production of acrylic acid includes preparing a product gas mixture by a catalytic gas-phase oxidation of a C3 precursor; cooling and contacting the cooled product gas mixture in an absorption column having at least two cooling loops in countercurrent with an absorbent to obtain an absorbate A, containing the absorbent and absorbed acrylic acid; condensing a high boiler fraction of the product gas mixture in a first cooling loop; condensing a low boiler fraction of the product gas mixture in a second cooling loop; maintaining a temperature of the absorbate A in the second cooling loop at a value of at least 56° C.; removing an acid water stream comprising glyoxal from the absorption column at a side take-off located above the second cooling loop; and removing a stream F of absorbate A from the absorption column at a side take-off, located at a height of the absorption column between the first cooling loop and the second cooling loop.
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