VERFAHREN ZUR HERSTELLUNG VON EXPANDIERTEM GRANULAT

    公开(公告)号:EP3008122A1

    公开(公告)日:2016-04-20

    申请号:EP14729348.4

    申请日:2014-06-11

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing expanded granulate from a thermoplastic elastomer having a breaking elongation of more than 100% measured according to DIN EN ISO 527-2, comprising the steps: (a) pressing a polymer melt comprising a propellant through a perforated plate (18) which is temperature-controlled to a temperature between 150°C and 280 °C into a granulating chamber (26), (b) reducing the polymer melt pressed through the perforated plate (18) by means of a cutting device (20) into individual, expanding granulate grains, (c) removal of the granulate grains from the granulating chamber (26) by means of a fluid flow (36), wherein the propellant contains CO2 or N2 or a combination of CO2 and N2 and the volume of propellant in the polymer melt comprising propellant lies in the range from 0.5 to 2.0 wt% and wherein a liquid which is temperature-controlled to a temperature between 5°C 20 and 90°C, having a pressure of 0.1 bar to 20 bar above the environmental pressure, flows through the granulating chamber (26), wherein the pressure and temperature of the liquid in the granulating chamber (26) and the temperature of the perforated plate (18) are selected such that the granulate grains in the pressurized liquid are expanded by the contained propellant such that expanded granulate grains having a closed skin result.

    Abstract translation: 本发明涉及从根据DIN EN 150 527-2测量的断裂伸长率大于100%的热塑性弹性体生产发泡颗粒的方法,所述方法包括以下步骤:(a)将包含 发泡剂通过控制在150℃和280℃之间的温度的多孔盘(18)进入造粒室(26),(b)使用切割装置(20)粉碎通过 (18)分成单独的膨胀颗粒,(c)使用液体流(36)从造粒室(26)排出颗粒,其中发泡剂包括CO 2或N 2或CO 2和N 2的组合, 在包含发泡剂的聚合物熔体中的发泡剂在0.5至2.5重量%的范围内,并且其中造粒室(26)被流动的液体流动,该液体流被控制在5℃和90℃之间的温度 ,其压力为0.1b 在高于环境压力的情况下,选择造粒室(26)中的液体的压力和温度以及多孔板(18)的温度,使得颗粒在加压液体中由发泡剂膨胀, 包含以产生具有不间断皮肤的发泡颗粒。

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