-
1.发明公开
公开(公告)号：EP1187867A1
公开(公告)日：2002-03-20
申请号：EP00928904.2
申请日：2000-05-08
发明人： BRUNELLE, Daniel, Joseph , SURIANO, Joseph, Anthony , JANG, Taeseok , SICLOVAN, Tiberiu, Mircea , PICKETT, James, Edward , O'NEIL, Gregory, Allen
IPC分类号： C08G63/19 , C08G63/79 , C08J7/04 , C09D167/03 , B32B27/08
CPC分类号： B32B27/08 , B32B27/06 , B32B27/18 , B32B27/20 , B32B27/36 , B32B27/365 , B32B2307/4026 , B32B2367/00 , B32B2369/00 , B32B2605/00 , C08G63/19 , C08G63/64 , C08G63/676 , C08G63/6956 , C08G63/79 , C08G63/85 , C08J7/047 , C08J2467/00 , C09D167/03 , F02B61/045 , Y10T428/1355 , Y10T428/1359 , Y10T428/25 , Y10T428/254 , Y10T428/2942 , Y10T428/31507 , Y10T428/31565 , Y10T428/31786
摘要： Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: (a) combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; and (b) adding to the mixture from (a) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.
-
公开(公告)号：EP1175455B1
公开(公告)日：2005-10-05
申请号：EP00913647.4
申请日：2000-02-28
IPC分类号： C08G63/199
CPC分类号： C08G63/78 , C08G63/199 , C08G63/672 , C08G63/6856 , C08G63/826 , C08G63/83 , C08G63/84 , C08G63/85
摘要： Polyesters such as poly(1,4-cyclohexanedimethyl-1,4-cyclohexanedicarboxylate) are prepared by the reaction of at least one relatively non-volatile diol, preferably 1,4-cyclohexanedimethanol, with a 1,4-cyclohexanedicarboxylic acid ester in the presence of a catalyst such as a tetraalkyl titanate. Maximum molecular weight and crystallinity are provided by at least one of two options: conducting the reaction at a series of progressively increasing temperatures below 265 DEG C, with a residence time in the range of 40-120 minutes at temperatures above 250 DEG C; and conducting an initial stage of the reaction in the presence of at least one C2-6 aliphatic diol such as ethylene glycol, diethylene glycol or 1,4-butanediol.
-
3.发明授权
公开(公告)号：EP1187867B1
公开(公告)日：2005-08-17
申请号：EP00928904.2
申请日：2000-05-08
发明人： BRUNELLE, Daniel, Joseph , SURIANO, Joseph, Anthony , JANG, Taeseok , SICLOVAN, Tiberiu, Mircea , PICKETT, James, Edward , O'NEIL, Gregory, Allen
IPC分类号： C08G63/19 , C08G63/79 , C08J7/04 , C09D167/03 , B32B27/08
CPC分类号： B32B27/08 , B32B27/06 , B32B27/18 , B32B27/20 , B32B27/36 , B32B27/365 , B32B2307/4026 , B32B2367/00 , B32B2369/00 , B32B2605/00 , C08G63/19 , C08G63/64 , C08G63/676 , C08G63/6956 , C08G63/79 , C08G63/85 , C08J7/047 , C08J2467/00 , C09D167/03 , F02B61/045 , Y10T428/1355 , Y10T428/1359 , Y10T428/25 , Y10T428/254 , Y10T428/2942 , Y10T428/31507 , Y10T428/31565 , Y10T428/31786
-
公开(公告)号：EP1175455A2
公开(公告)日：2002-01-30
申请号：EP00913647.4
申请日：2000-02-28
IPC分类号： C08G63/199
CPC分类号： C08G63/78 , C08G63/199 , C08G63/672 , C08G63/6856 , C08G63/826 , C08G63/83 , C08G63/84 , C08G63/85
摘要： Polyesters such as poly(1,4-cyclohexanedimethyl-1,4-cyclohexanedicarboxylate) are prepared by the reaction of at least one relatively non-volatile diol, preferably 1,4-cyclohexanedimethanol, with a 1,4-cyclohexanedicarboxylic acid ester in the presence of a catalyst such as a tetraalkyl titanate. Maximum molecular weight and crystallinity are provided by at least one of two options: conducting the reaction at a series of progressively increasing temperatures below 265 °C, with a residence time in the range of 40-120 minutes at temperatures above 250 °C; and conducting an initial stage of the reaction in the presence of at least one C2-6 aliphatic diol such as ethylene glycol, diethylene glycol or 1,4-butanediol.
-
-
-
搜索结果
4 条记录 (耗时 0.01 秒)
