摘要:
Broadly, the present invention comprises a solventless process wherein blends of thermoset polyphenylene oxide and epoxy can be processed into fiber reinforced laminates, and especially laminates prepared by the Wiggins Teape process. One aspect of the present inventive process comprises blending the polyphenylene powder with a liquid epoxy material, optionally with flame retardants and catalysts, preferably in a high shear mixer at elevated temperature, e.g. in the range of about 100°-130°C. The resultant up-staged or partially-cured blend is sufficiently solidified to be granulated into a powder for Wiggins Teape processing or, optionally, conventional press processing into a fiber reinforced laminates. Resin systems thus-prepared exhibit both improved solderability resistance and improved resistance to organic solvents when compared to thermoplastic systems.
摘要:
The present invention is directed to a method for making a chopped fiber-reinforced composite. The method comprises dispersing a polyamide acid/epoxy blend and greater than 50 wt-% chopped fiber in an aerated surfactant foam. The foam is deposited on a foraminous layer and collapsed to form a web. The web is consolidated at a temperature of greater than about 280°C and a pressure of greater than about 500 psi. The resulting composite typically has a flexural modulus of greater than 2,000 ksi and flexural strength values of greater than about 30,000 psi and typically between about 30,000 and 50,000 psi. The composite should find use in applications requiring effective high mechanical stiffness and strength, and flame resistance.
摘要:
Curable compositions containing a reaction product of at least one bisphenol polyglycidyl ether, at least one epoxidized novolak and at least one brominated bisphenol, in combination with a polyphenylene ether and further components including specific catalysts and hardeners, may be used in the preparation of laminates useful as printed circuit boards and having excellent physical and electrical properties.
摘要:
A flexible laminate comprising metal (4) and fabric (8) having an adhesive copolyetherester resin in the form of a film (6) between the metal and the fabric. In a preferred embodiment, a copolyetherester resin in the form of a film is used as an adhesive for a flexible laminate made of copper foil and flexible fabric made of aromatic polyamide resin fibers. Encapsulant film may be applied to the outer surface of the fabric to enhance moisture resistance of the laminate and/or to improve the handling of the laminate.
摘要:
Polyesters, especially poly(ethylene terephthalate) and poly(butylene terephthalate), having a substantial proportion of free carboxylic acid groups are caused to react with polyepoxy compounds, especially poly(O- or N-epoxyalkyl-substituted) cyclic amides, imides and amidates and preferably triglycidyl isocyanurate, in the presence of various amines or salts as catalysts. The preferred catalysts are fatty acid salts such as sodium stearate. The products have very high melt viscosities and are useful in such operations as blow molding.
摘要:
Molding compositions comprising poly(cyclohexanedimethanol terephthalate), a reinforcing agent, optionally, a crystallization promoting agent, optionally a flame retardant agent and tribranched epoxy and/or triallyl isocyanurates as melt stabilizers, are disclosed. These compositions are characterized by substantially higher melt stability and improved thermal aging properties.
摘要:
Thermoformable composites comprised of polycarbonate/woven glass cloth and methods for their preparation are provided. The composites have good flammability characteristics and physical properties and are suitable for use in aircraft interiors.