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1.发明公开
公开(公告)号：EP2014639A1
公开(公告)日：2009-01-14
申请号：EP07742063.6
申请日：2007-04-20
IPC分类号： C07C69/653 , C07C31/44 , C07C67/14 , C07D301/24 , C07D303/30 , C08L101/00 , G02B1/04 , G02B1/11
CPC分类号： C07C31/44 , C07C69/653 , C07C2603/74 , C07D301/24 , C07D305/06 , C08F220/24 , C08F222/1006
摘要： To provide a polymerizable group-containing and fluorine-containing adamantane derivative capable of affording a cured product having good heat resistance, good mechanical properties such as mar resistance and a low refractive index, a resin composition containing such a polymerizable group-containing adamantane derivative, and a fluorine-containing adamantane derivative which is useful as a reaction intermediate used for the production of the polymerizable group-containing and fluorine-containing adamantane derivative.
Specifically provided are a fluorine-containing adamantane derivative represented by the general formula (I) below, a polymerizable group-containing and fluorine-containing adamantane derivative represented by the general formula (II) below, and a resin composition containing such a polymerizable group-containing and fluorine-containing adamantane derivative. In the formula, R 1 and R 2 are each a hydrogen atom, for example, n is an integer of 0 or more, X 1 is a polymerizable group represented by the formula (III-a), for example, Y is a hydrogen atom, for example, s and t are each an integer of 1 to 15, and u is an integer of 0 to 14, with the proviso that s + t + u = 16.摘要翻译： 提供和含氟金刚烷衍生物能够得到具有良好耐热性的固化物的含有聚合性基团的，良好的机械性能：如耐擦伤性和低折射率，含寻求含聚合性基团的金刚烷衍生物的树脂组合物， 和含氟金刚烷衍生物所有作为中间体的反应用于生产含聚合性基团的含氟金刚烷衍生物的，这是有用。 下面具体地提供了由通式（I）表示的含氟金刚烷衍生物，含有聚合性基团和由下面的通式（II）表示的含氟金刚烷衍生物，和树脂组合物包含寻求可聚合基团 - 含有氟和含金刚烷衍生物。 氢在该式中，R 1和R 2各自为氢原子，对于实施例中，n是0以上的整数，X 1是由式（III-A）表示的聚合性基团，例如，Y是 核，例如，s和t各自为1至15的整数，u是0〜14的整数，前提条件做S + T + U = 16
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2.发明公开ADAMANTANE DERIVATIVE, RESIN COMPOSITION CONTAINING SAME, AND OPTOELECTRONIC COMPONENT USING SAME 审中-公开金刚烷，树脂组合物这包含和光电组分，这在过去
公开(公告)号：EP1930327A1
公开(公告)日：2008-06-11
申请号：EP06797201.8
申请日：2006-08-31
发明人： ITO, Hajime
IPC分类号： C07D303/16 , C07D301/30 , C07D303/24 , C07D305/06
CPC分类号： C07D301/30 , C07D303/16 , C07D303/24 , C07D305/06
摘要： Disclosed is an adamantane derivative which enables to obtain a cured product which is excellent in optical characteristics such as transparency and light resistance, long-term heat resistance, and electrical characteristics such as dielectric constant. Also disclosed are a resin composition containing such an adamantane derivative, and a sealing agent for electronic circuits and an optoelectronic member respectively using those. Specifically disclosed are an adamantane derivative represented by the general formula (I) below, a resin composition containing such an adamantane derivative, a sealing agent for electronic circuits and an optoelectronic member respectively using such a resin composition, and an adhesive of those. (I) In the general formula (I), Z represents a group selected from the groups represented by the general formula (II) or (III) below (wherein R 1 represents a hydrogen atom or an alkyl group having 1-4 carbon atoms); X represents a linking group which may contain an oxygen atom and a sulfur atom and is composed of an (m + 1)-valent hydrocarbon, and a part or all of the hydrogen atoms in a hydrocarbon as the linking group may be replaced with fluorine atoms; Y represents a group selected from -CO 2 - and -O-; W represents a group selected from a hydrogen atom, a halogen atom, a hydrocarbon group, a halogen-substituted hydrocarbon group, a cyclic hydrocarbon group, a halogen-substituted cyclic hydrocarbon group, a hydroxyl group, a carboxyl group and =O formed from two Ws combined together; m represents an integer of 2-4; n represents an integer of 1-4; and k represents an integer from 0 to 16 - n.
摘要翻译： 公开的是这使得能够获得固化产品中的所有其具有优异的光学特性的金刚烷衍生物：如透明度和耐光性，长期耐热性和电特性：如介电常数。 所以圆盘游离缺失是一种树脂组合物包含寻求金刚烷衍生物，以及用于电子电路和光电子部件分别使用这些密封剂。 具体地说游离缺失盘分别由通式（I）表示的金刚烷衍生物的下方，含有寻求金刚烷衍生物，电子电路和在光电元件使用寻求的树脂组合物的密封剂的树脂组合物，以及粘合剂的那些。 （I）在通式（I）中，Z表示从由通式（II）或（III）所示（worin R 1表示氢原子或烷基具有1-4个碳原子基团表示的基团中的基团 ）; X darstellt其可含有价的烃对氧原子和硫原子并且由第（m + 1），并且其一部分或全部在烃作为连接基团的氢原子的连接基团可以被氟代替 原子; Y表示选自-CO 2中的基团 - 和-O-; W¯¯darstellt选自氢原子，卤原子，烃基，卤素取代的烃基，环状烃基，卤素取代的环状烃基，羟基，羧基和= O从形成的基团 2个Ws的结合在一起; 米darstellt到2-4整数; Ñdarstellt在1-4整数; N - 并且在整数0至16k的darstellt。
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3.发明公开ADAMANTANE DERIVATIVE AND PROCESS FOR PRODUCING THE SAME 审中-公开ADAMANTANDERATAT VERFAHREN ZU DESSEN HERSTELLUNG
公开(公告)号：EP1731504A1
公开(公告)日：2006-12-13
申请号：EP04792132.5
申请日：2004-10-07
发明人： ITO, Hajime , TANAKA, Shinji
IPC分类号： C07C255/31 , C07C253/30
CPC分类号： G03F7/0397 , C07C255/31 , C07C2603/74
摘要： Provided are an adamantane derivative characterized by having a structure represented by Formula (I) and a process for producing an adamantane derivative in which n is 0 in Formula (I) described above, wherein an adamantane compound is reacted with a nitrile compound and then with acid halide or acid anhydride of (meth)acrylic acids. The adamantane derivative characterized by having a structure represented by Formula (I) is a novel adamantane derivative which is useful as a monomer for functional resins such as a photosensitive resin in the photolithograpy field, and it can efficiently be produced by the production process described above.
摘要翻译： 本发明提供一种金刚烷衍生物，其特征在于具有式（I）表示的结构和上述式（I）中n为0的金刚烷衍生物的方法，其中金刚烷化合物与腈化合物反应，然后与 （甲基）丙烯酸的酰卤或酸酐。 以具有式（I）表示的结构为特征的金刚烷衍生物是一种新颖的金刚烷衍生物，其可用作光刻领域中光敏树脂等功能性树脂的单体，可以通过上述制造方法有效地制造 。
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4.发明公开ADAMANTANE DERIVATIVE, COMPOSITION COMPRISING THE DERIVATIVE, AND OPTICAL AND ELECTRONIC MEMBER USING THE COMPOSITION 审中-公开金刚烷的衍生物，包括成分和光学和电子件，由它使用该组合物
公开(公告)号：EP1985617A1
公开(公告)日：2008-10-29
申请号：EP07707867.3
申请日：2007-02-01
IPC分类号： C07D303/30 , C07D305/06 , C08G59/24 , C08G65/18 , C07B61/00
CPC分类号： C07D303/30 , C07D305/06 , C08G59/24 , C08G59/42
摘要： To provide an adamantane derivative, a compound having an adamantane skeleton, compositions containing them that can provide a cured product having excellent optical properties such as transparency and light resistance, long-term heat resistance and electric characteristics such as dielectric permittivity, and optical electronic members using the compositions.
An adamantane derivative represented by the general formula (I), a compound with an adamantane skeleton represented by the general formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions. In the formulas, W represents, for example, a hydrogen atom, X represents, for example, a group represented by the general formula (II), Yrepresentsagrouprepresented by the formula (V) or (VI), R 1 represents a methyl group or an ethyl group, R 2 represents a C 1 to C 10 hydrocarbon group which may contain O or S, m is an integer of 2 to 4, k is an integer of 0 to (16-m) and p and q are each an integer of 1 to 5.摘要翻译： 以提供金刚烷衍生物，具有金刚烷骨架的化合物，含有它们的组合物也可提供具有优异的光学特性的固化产物：如透明度和耐光性，长期耐热性和电特性：如介电常数和光学电子部件 使用该组合物。 由通式（I）表示的金刚烷衍生物，具有金刚烷在骨架由通式（VII）或（VIII）表示，组合物含有它们，并使用该树脂组合物的光学电子部件的化合物。 在该式中，W darstellt，例如，氢原子，X darstellt，例如，由通式（II）表示的基团，由式（V）或（VI）Yrepresentsagrouprepresented中，R 1表示甲基或 乙基的，R 2表示C 1至C 10烃基，其可以含有O或S，m为2〜4的整数，k为0〜（16-M），p和q的整数各自在 的1至5整数
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5.发明公开
公开(公告)号：EP1985616A1
公开(公告)日：2008-10-29
申请号：EP07707083.7
申请日：2007-01-19
IPC分类号： C07D303/30 , C07C39/14 , C07D301/28 , C08G59/20 , G03F7/004
CPC分类号： C07C39/17 , C07C37/16 , C07C37/20 , C07C2603/74 , C07D301/28 , C07D303/30 , C08G59/24 , C08G59/4215 , C08G59/4223 , C08G59/621 , G03F7/038 , Y10T428/1073 , Y10T428/31511
摘要： Disclosed is an adamantane derivative which provides a cured product excellent in optical characteristics such as transparency and light resistance, long-term heat resistance, electrical characteristics such as and dielectric constant, and low water absorption. Also disclosed are a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent. Specifically disclosed are an adamantane derivative represented by the formula (I-1) below, a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate, all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent.
摘要翻译： 公开的是提供具有优异的光学特性的固化产物的金刚烷衍生物：如透明度和耐光性，长期耐热性，电特性：如介电常数和，以及低吸水性。 所以游离缺失盘是含有金刚烷衍生物，用于电子电路，光学电子部件，半导体装置和包铜层压体的所有使用该树脂组合物的密封剂，并且其含有上述金刚烷衍生物的辐射敏感树脂组合物的树脂组合物 作为交联剂。 具体地说游离缺失盘是在由下式表示的金刚烷衍生物（I-1）所示，将含有金刚烷衍生物的树脂组合物，用于电子电路，光学电子部件，半导体装置和包铜层压板，所有使用该树脂组合物的密封剂， 且其含有作为交联剂的上述金刚烷衍生物的辐射敏感树脂组合物。
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6.发明公开ADAMANTYL GROUP-CONTAINING EPOXY-MODIFIED (METH)ACRYLATE AND RESIN COMPOSITION CONTAINING THE SAME 审中-公开丙烯酸缩水甘油酯（METH）丙烯酸酯在HARZZUSAMMENSETZUNG DAMIT
公开(公告)号：EP2014691A1
公开(公告)日：2009-01-14
申请号：EP07742230.1
申请日：2007-04-24
IPC分类号： C08F290/06 , C08G59/17
CPC分类号： C08F290/06 , C08F222/1006 , C08F290/061 , C08F290/064 , C08G59/186
摘要： The present invention provides an adamantyl group containing epoxy-modified (meth)acrylate and a resin composition containing it which are imparted by transparency, optical characteristics such as (durable) light resistance and the like, heat-resistance, and good mechanical properties.
For example, they are an adamantyl group containing epoxy-modified (meth)acrylate having the following general formula (I) and a composition containing it. In the formula, R 1 represents a hydrogen atom or a methyl group, and R 2 represents a halogen atom or an aliphatic hydrocarbon group which may contain a hetero atom. Plural R 2 may be the same or different, and m represents an integer of 0 to 4 and n represents an integer of 0 or more.摘要翻译： 本发明提供含有环氧改性的（甲基）丙烯酸金刚烷基和含有它的树脂组合物，它们通过透明性，耐光性等光学特性赋予耐热性和良好的机械性能。 例如，它们是含有具有以下通式（I）的环氧改性（甲基）丙烯酸酯和含有它的组合物的金刚烷基。 式中，R 1表示氢原子或甲基，R 2表示卤素原子或可含有杂原子的脂肪族烃基。 多个R 2可以相同或不同，m表示0〜4的整数，n表示0以上的整数。
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7.发明授权PROCESSES FOR PRODUCING RAW POLYCARBONATE RESIN MATERIAL AND PRODUCING POLYCARBONATE RESIN 有权工艺生产粗聚碳酸酯树脂材料及其制造聚碳酸酯树脂
公开(公告)号：EP1178068B1
公开(公告)日：2005-05-18
申请号：EP01908265.0
申请日：2001-03-02
发明人： ITO, Hajime , SUWA, Akio , KOHIRUIMAKI, Jun
CPC分类号： C07C37/66 , C08G64/24 , C07C39/235
摘要： Processes for producing a raw polycarbonate resin material and a polycarbonate resin at low cost through simple steps. The process for producing a raw polycarbonate resin material through interfacial polymerization is characterized in that (I) a bisphenol compound in a molten state is mixed with and dissolved in an aqueous alkali solution at 20 to 80 DEG C or (II) a bisphenol compound in a molten state is mixed with water, without being solidified, to make the compound liquid at a temperature not higher than the melting point thereof and then the compound is dissolved in an aqueous alkali solution.
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8.发明公开ADAMANTANE DERIVATIVE, EPOXY RESIN, AND OPTICAL ELECTRONIC MEMBER USING RESIN COMPOSITION COMPRISING THEM 审中-公开金刚烷，环氧和光学电子元器件在此组成的含树脂
公开(公告)号：EP1923416A1
公开(公告)日：2008-05-21
申请号：EP06797202.6
申请日：2006-08-31
发明人： ITO, Hajime
IPC分类号： C08G59/24 , C07D301/00 , C07D303/27 , C08G65/18 , H01L23/29 , H01L23/31
CPC分类号： H01L23/293 , C08G59/24 , C08G65/18 , C08G65/329 , H01L31/0216 , H01L2924/0002 , H01L2924/12044 , H01L2924/00
摘要： This invention provides an adamantane derivative that can provide a cured product having optical properties such as transparency and lightfastness, long-term resistance, electric characteristics such as permittivity, and an epoxy resin having an adamantane skeleton, a composition comprising them, and an optical electronic member using the resin composition. The adamantane derivative is represented by general formula (I). The epoxy resin having an adamantane skeleton is represented by general formula (V) or (VI). The composition comprises them. The optical electronic uses the resin composition. In the formula, W represents, for example, a hydrogen atom, X represents a group represented by general formula (II), Y represents, for example, -O-, Z represents a group represented by formula (III) or (IV), R 1 represents a methyl or ethyl group, R 2 represents an alkyl group having 1 to 4 carbon atoms, k is an integer of 0 to 10, m is an integer of 0 to 14, n is an integer of 2 to 16, m + n = 16, and p and q are an integer of 0 to 5.
摘要翻译： 本发明对金刚烷衍生物提供确实可提供具有光学性质的固化产物：如透明度和耐光性，长期性，电特性：如介电常数，在环氧树脂上具有金刚烷骨架，组合物包含它们，以及光学电子 构件使用树脂组合物。 的金刚烷衍生物是由通式（I）表示。 具有金刚烷骨架的环氧树脂，是通过通式（V）或（VI）表示。 该组合物包括他们。 光学电子使用树脂组合物。 在该式中，W darstellt，例如，氢原子，X表示由通式表示的基团（II）中，Y darstellt，例如，-O - ，Z表示由下式表示的基团或式（III）（IV） R 1表示甲基或乙基，具有1至4个碳原子，k为0至10的整数，m为0〜14的整数，n为2〜16的整数的烷基的R 2中darstellt， M + N = 16，以及p和q为上至第五0整数
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