摘要:
A novel and practically excellent process for preparing optically active compounds, such as optically active alcohols or amines, useful for various applications of, for example, synthetic intermediates of pharmaceuticals, liquid crystalline materials, and reagents for optical resolution, wherein a hydrogen transfer type asymmetric reduction is carried out in the presence of both a transition metal complex and an optically active nitrogen compound or a transition metal complex having an optically active nitrogen compound as an asymmetric ligand, and a hydrogen-donating organic or inorganic compound. Further, optically active secondary alcohols are prepared from racemic secondary alcohols or meso-diols by a hydrogen transfer oxidation.
摘要:
The present invention addresses the problem of providing a composition for addition to electrolyte solutions, which improves storage stability of a silyl group-containing compound that is a useful additive for lithium ion secondary batteries. The description of this application sets forth a composition for addition to electrolyte solutions, which contains one or more silyl group-containing compounds (compound (a)) and one or more basic compounds and/or silicon compounds (compound (b)).
摘要:
A membrane/electrode assembly for solid polymer fuel cells is disclosed wherein a fluorinated sulfonic acid polymer having a monomer unit represented by the following general formula (3): (3) (wherein, Rf represents a divalent perfluorohydrocarbon group having 4-10 carbon atoms) is used for at least one of the membrane and the catalyst binder. The fluorinated sulfonic acid polymer has a melt flow rate (MFR) of not more than 100 g/10min at 270˚C when the -SO3H group in the polymer is changed into -SO2F.
摘要:
A perfluorovinyl ether monomer represented by the following formula (1): wherein: m is an integer of from 0 to 5; n is an integer of from 1 to 5; and each of R and R independently represents a hydrogen atom, an unsubstituted or substituted C1-C10 hydrocarbon group, or a substituted silyl group, with the proviso that, when each of R and R is independently the hydrocarbon group or the substituted silyl group, R and R are optionally bonded together, thereby forming a ring. Also disclosed are a method for producing the perfluorovinyl ether monomer; a fluorinated polymer obtained from the monomer and a method for producing the same; a polymer film obtained from the polymer; a modified or crosslinked polymer film obtained from the polymer film; and a solid polymer electrolyte membrane obtained from the modified or crosslinked polymer film.