摘要:
In a semi-organic insulation coating comprising an inorganic component and an organic resin, a Zr compound and an Si compound containing a plate-like silica as an inorganic component are included in a ratio in a dry coating of 20 to 70 mass% of Zr compound (converted to ZrO 2 ) and 10 to 50 mass% of Si compound containing plate-like silica (converted to SiO 2 ), and the remainder is substantially an organic resin, whereby there can be provided a magnetic steel sheet with a semi-organic insulation coating having no deterioration of corrosion resistance and water resistance without containing a chromium compound and being excellent in the powdering resistance, scratch resistance, sticking resistance, TIG weldability and punchability but also the coating appearance.
摘要:
The electrical steel sheet having an insulation coating having excellent corrosion resistance and punchability even without containing chromium is prepared by applying a coating liquid on the surface of an electrical steel sheet, followed by baking the applied coating liquid, which coating liquid contains 100 parts by weight of polysiloxane polymer prepared by copolymerizing polysiloxane with one or more resins selected from the group consisting of acrylic resin, styrene resin, vinyl acetate resin, polyester resin, urethane resin, polyethylene resin, polypropylene resin, polyamide resin, polycarbonate resin, phenol resin, alkyd resin, and epoxy resin, and 1 to 50 parts by weigh of one or more compounds selected from the group consisting of melamine, isocyanate, silane coupling agent, and oxadoline, as the cross-linking agent.
摘要:
A stacked electrical steel sheet used for a stacked iron core of an automotive motor and the like required to have high-temperature bond property and high-temperature oil resistance is provided. An electrical steel sheet for stacking includes: an electrical steel sheet; and a bond-type insulating coating formed on at least one surface of the electrical steel sheet and having Martens hardness HM of 50 or more and less than 500.
摘要:
An electrical steel sheet provided with insulating coating excellent in punchability and adhesion property is obtained. The electrical steel sheet provided with insulating coating comprises an electrical steel sheet and an insulating coating formed on the electrical steel sheet. The insulating coating contains Si and Fe. The coating weight of Si in the insulating coating in terms of SiO 2 is 50% to 99% of the total coating weight. The ratio (Fe/Si) of the content of Fe to the content of Si in the insulating coating ranges from 0.01 to 0.6 on a molar basis. The insulating coating preferably contains an organic resin and/or a lubricant. In the insulating coating, the ratio (C (the organic resin + the lubricant)/(Fe 2 O 3 + SiO 2 )) of the coating weight of the organic resin and/or the lubricant in terms of C to the sum of the coating weight of Fe in terms of Fe 2 O 3 and the coating weight of Si in terms of SiO 2 preferably ranges from 0.05 to 0.8.
摘要:
An insulation coating containing a composite resin composed of polysiloxane and a polymer containing carbon element is formed on the surface of an electrical steel sheet, thus obtaining an electrical steel sheet having an insulation coating that gives corrosion resistance and punchability equivalent to or higher than those of Cr-containing insulation coating.
摘要:
A stacked electrical steel sheet used for a stacked iron core of an automotive motor and the like required to have high-temperature bond property and high-temperature oil resistance is provided. An electrical steel sheet for stacking includes: an electrical steel sheet; and a bond-type insulating coating formed on at least one surface of the electrical steel sheet and having Martens hardness HM of 50 or more and less than 500.
摘要:
In a semi-organic insulation coating comprising an inorganic component and an organic resin, a Zr compound and an Si compound containing a plate-like silica as an inorganic component are included in a ratio in a dry coating of 20 to 70 mass% of Zr compound (converted to ZrO 2 ) and 10 to 50 mass% of Si compound containing plate-like silica (converted to SiO 2 ), and the remainder is substantially an organic resin, whereby there can be provided a magnetic steel sheet with a semi-organic insulation coating having no deterioration of corrosion resistance and water resistance without containing a chromium compound and being excellent in the powdering resistance, scratch resistance, sticking resistance, TIG weldability and punchability but also the coating appearance.
摘要:
An electrical steel sheet with an insulation coating excellent in punchability, coating adhesion property and coating film property after annealing, even without containing any chromium compound in the insulation coating. The insulation coating is formed by applying a surface-treatment agent to at least one side of the electrical steel sheet and drying the surface-treatment agent. The surface-treatment agent contains trialkoxysilane and/or dialkoxysilane (A) in which a substituent bound to Si is constituted only by at least one non-reactive substituent selected from the group consisting of hydrogen, an alkyl group, and a phenyl group; and a silane coupling agent (B), at a mass ratio (A/B) of 0.05 to 1.0.
摘要:
The disclosure provides an electrical steel sheet with an insulating coating excellent in both punchability and powdering resistance, without any chromium compound being contained in the insulating coating. The electrical steel sheet with an insulating coating includes an electrical steel sheet and an insulating coating formed on the electrical steel sheet. The insulating coating contains Si and particulate organic resin. The organic resin contains primary particles having an average primary particle size of 1.0 µm or less, and 5 % or more and 50 % or less of the primary particles of the organic resin are agglomerated particles.