摘要:
A process for producing metallic fine particles having a superior reproducibility of a partice size and light absorption characteristics, metallic fine particles, a metallic fine particles-containing composition, and the use thereof, are provided. In the process for producing the metallic ions, the reduction of the metallic ions is performed in two steps using two types of reducing agents which significantly differ in reducing ability thereof, in which a reducing agent in which the reduction ability is strong is used in the first reduction step, and a reducing agent in which the reduction ability is weak is used in the second reduction step, and thereby the nano-sized metallic fine particles are produced. Preferably in the process, an aqueous metallic salt solution containing a surfactant is used and a two-step reduction is performed in the same vessel, in which as the reducing agent of the first reduction process, at least one selected from the group consisting of boron hydride, dimethylamine borane, hydrazine, and ascorbic acid is used, and as the reducing agent of the second reduction process, specific alkylamine or alkanolamine is used.
摘要:
The invention provides a composition for forming transparent conductive film, characterized by including a binder component, and a conductive powder and a high-refractive index powder which are dispersed in the binder component, wherein the conductive powder is formed of tin hydroxide powder in an amount of 0.1 to 30 mass% and a conductive powder other than tin hydroxide powder in an amount of 70 to 99.9 mass%. The composition can form a transparent conductive film that exhibits remarkably excellent scratch resistance, excellent antistatic effect, and has very high visible light transmittance and which can impart a desired refractive index to the film. The invention also provides such a transparent conductive film and a display having such a transparent conductive film on a screen thereof.
摘要:
Through employment of a binder component, tin hydroxide powder serving as a conductive powder, and a high-refractive index powder; through dispersal of tin hydroxide powder and light-transmission-ensuring microparticles in a binder component at a predetermined ratio; and through employment of a specific binder component and, as a conductive powder, tin hydroxide powder and a conductive powder other than tin hydroxide powder at a predetermined ratio, there can be provided a composition which can form a transparent conductive film that exhibits excellent antistatic effect, and has very high visible light transmittance and provides transmitted images with natural hue by virtue of no color absorption wherein, if desired, the film also exhibits excellent scratch resistance and high antiglare effect, or the refractive index of the film can be controlled; such a transparent conductive film, and a display having such a transparent conductive film on a screen thereof.
摘要:
Metal microparticles that exhibit selective wavelength absorption capability over a wavelength region from visible light to near infrared light, having sharp light absorption characteristics and that have less influence on ambient wavelengths, realizing color tone of high saturation. There are provided metal microparticles characterized in that the aspect ratio thereof is in the range of 1.1 to 8.0, the maximum absorption wavelength of plasmon absorption in the range of 400 to 1,200 nm and the absorptivity at maximum absorption wavelength peak position in the range of 6,000 to 20,000 L/mol·cm (measurement concentration: 1.6×10-4 mol/L and solvent: water).
摘要:
A method for manufacturing metal nanorods includes: a step of adding a reducing agent to a metallic salt solution; a step of radiating light into the metallic salt solution containing the reducing agent; and a step of leaving the light-radiated metallic salt solution containing the reducing agent stationary in a dark place so as to grow metal nanorods. Metal nanorods can be also grown by forming a mixed solution by fractionating the above light-radiated metallic salt solution and mixing the fractionated metallic salt solution into a non-radiated metallic salt solution containing the reducing agent, or mixing a non-radiated metallic salt solution and the reducing agent into the above light-radiated metallic salt solution; and leaving the mixed solution stationary in a dark place so as to grow metal nanorods.
摘要:
This method for manufacturing metal fine particles includes using an aqueous solution containing an amine having a reducing capacity and an ammonium salt having substantially no reducing capacity so as to reduce metal ions with said amine in a presence of said ammonium salt, thereby manufacturing rod-shaped metal fine particles. This metal fine particles are manufactured by this method for manufacturing metal fine particles, and have a major axis of 400 nm or less, a minor axis of 15 nm or less, and an aspect ratio of more than 1.
摘要:
The present invention provides a zirconium oxide dispersion which contains zirconium oxide particles, a metal complex, and a dispersion medium and which has excellent storage stability; a photo-curing composition containing zirconium oxide particles which contains zirconium oxide particles, a metal complex, an actinic energy ray-curing compound, a photopolymerization initiator, and a dispersion medium and which composition can form, on a surface of a substrate, a cured film having excellent transparency and high refractive index, and which composition does not corrode a metal-made apparatus employed in a dispersion process and a coating apparatus; and a cured film produced by applying onto a substrate the photo-curing composition containing zirconium oxide particles through coating or printing, followed by hardening.
摘要:
The invention provides a transparent-film-forming composition containing at least one microparticle-form inorganic substance having a refractive index of 1.80 or higher and lower than 3.00 (ingredient A), at least one microparticle-form inorganic substance having a refractive index of 1.55 or higher and lower than 1.80 (ingredient B), and a binder having a refractive index lower than that of the ingredient B, and preferably, a dispersion stabilizer, and being capable of forming, on a surface of a transparent substrate, a transparent film having excellent transparency and free from interference-related disturbance. The invention also provides a transparent-film-layered product having a transparent substrate and, on a surface of the substrate, a transparent film formed from the composition, which layered product exhibits a difference in refractive index between the transparent substrate and the transparent film of 0.03 or smaller and excellent transparency, and providing minimized interference-related disturbance.