摘要:
A method for forming a film, characterized in that it comprises a step of forming an F-added carbon film by the use of a raw material gas containing C and F, a step of modifying the above F-added carbon film by a radical, and a step of modifying the above F-added carbon film, wherein the raw material gas has a ratio (F/C) of the number of F atoms to the number of C atoms contained therein of more than 1 and less than 2.
摘要:
A plasma film-forming method and apparatus in which an upper opening of a vacuum chamber is closed with a dielectric and a planar antenna member is provided on the top of the dielectric. A coaxial waveguide is provided on the top of the planar antenna member. Microwave generator means is connected to the coaxial waveguide. A multitude of slits having a length equal to, e.g., half the wavelength of the microwave are provided concentrically in the planar antenna member. For example, a circularly polarized microwave is emitted through these slits into a process atmosphere to produce a plasma from a material gas. The electron temperature the plasma defined by mean-square velocity is 3 eV or less, and the electron density is 5×1011/cm3 or more. Thus, a fluorine-added carbon film is formed. It is preferable that the process pressure is 19.95 Pa or less.
摘要:
A semiconductor device having an insulating film comprising a fluorine-doped carbon film having experienced a thermal history under a temperature of 420°C or less, characterized in that the fluorine-doped carbon film has a hydrogen atom content of 3 atomic % or less before the experience of the thermal history.