摘要:
The present invention relates to a gas sensor electrode including a conductive particle phase made of Pt or Pt alloy and a ceramic particle phase being mixed and dispersed, wherein a rate of content of the ceramic particle phase is 6.0 to 22.0 mass%, and a void ratio is 2.5 to 10.0%, and a dispersion degree of the conductive particle phase per length of 25 µm on the electrode surface is 0.60 to 0.85 µm, and a dispersion degree of the conductive particle phase in the electrode cross section per length of 100 µm in a direction parallel to the electrode surface is 2.0 to 4.0 µm. This electrode can be produced by firing a metal paste made by dispersing, in a solvent, a conductive particle having a core/shell structure in which a core particle such as Pt is covered with a ceramic shell and ceramic powder. The gas sensor electrode according to the present invention has a high electrode activity.
摘要:
A gas sensor electrode including a conductive particle phase made of Pt or Pt alloy and a ceramic particle phase being mixed and dispersed, wherein a rate of content of the ceramic particle phase is 6.0 to 22.0 mass%, and a void ratio is 2.5 to 10.0%, and a dispersion degree of the conductive particle phase per length of 25 µm on the electrode surface is 0.60 to 0.85 µm, and a dispersion degree of the conductive particle phase in the electrode cross section per length of 100 µm in a direction parallel to the electrode surface is 2.0 to 4.0 µm.
摘要:
The present invention is to provide a metal paste capable of forming electrodes which have sufficient electrode activity and electroconductivity as compared with conventional ones and are useful as the sensor electrodes of various gas sensors. The present invention relates to a metal paste for gas sensor electrode formation formed by dispersing conductive particles including Pt or a Pt alloy and ceramic powder into a solvent and the metal paste further includes inorganic-oxide particles including alumina and insoluble organic particles or carbon or diamond powder, the ceramic powder including a ceramic powder having a particle diameter of 0.5 µm or larger in an amount of 10-80% by mass based on the whole ceramic powder.
摘要:
To be provided is a metal paste from which an electrode having high electrode activity as a sensor electrode of various gas sensors can be produced. The present invention is a metal paste for forming a gas sensor electrode obtained by dispersing a conductive particle including Pt or a Pt alloy and a ceramic powder including zirconia or stabilized zirconia, or any of zirconia and stabilized zirconia and one or more oxides of La, Ce, Pr, Nd, Sm, and Hf in a solvent, the metal paste further including an inorganic oxide particle containing alumina and an insoluble particle that is insoluble in the solvent, in which 0.5 or more to 3.0 mass% or less of the inorganic oxide particle and 1.0 to 5.0 mass% of the insoluble particle are dispersed based on the mass of the solid content of the conductive particle, the ceramic powder, the inorganic oxide particle, and the insoluble particle.
摘要:
To be provided is a metal paste from which an electrode having high electrode activity as a sensor electrode of various gas sensors can be produced. The present invention is a metal paste for forming a gas sensor electrode obtained by dispersing a conductive particle including Pt or a Pt alloy and a ceramic powder including zirconia or stabilized zirconia, or any of zirconia and stabilized zirconia and one or more oxides of La, Ce, Pr, Nd, Sm, and Hf in a solvent, the metal paste further including an inorganic oxide particle containing alumina and an insoluble particle that is insoluble in the solvent, in which 0.5 or more to 3.0 mass% or less of the inorganic oxide particle and 1.0 to 5.0 mass% of the insoluble particle are dispersed based on the mass of the solid content of the conductive particle, the ceramic powder, the inorganic oxide particle, and the insoluble particle.
摘要:
The present invention is an electroconductive particle for forming an electrode including a precious metal particle including Pt or a Pt alloy and having an average particle diameter of 50 to 150 nm, a first ceramic particle including Al 2 O 3 or ZrO 2 dispersed in the precious metal particle and having an average particle diameter of 5 to 50 nm, and a second ceramic particle including Al 2 O 3 or ZrO 2 bonded to an outer periphery of the precious metal particle and having an average particle diameter of 5 to 50 nm. The sum of the volume of the first ceramic particle and the volume of the second ceramic particle is preferably 2 to 40 vol% based on the whole electroconductive particle. A metal paste containing the electroconductive particle according to the invention is one from which an electrode film of low resistance and excellent durability can be manufactured and further excellent in adherence and conformability to a substrate.
摘要:
The present invention relates to a gas sensor electrode including a conductive particle phase made of Pt or Pt alloy and a ceramic particle phase being mixed and dispersed, wherein a rate of content of the ceramic particle phase is 6.0 to 22.0 mass%, and a void ratio is 2.5 to 10.0%, and a dispersion degree of the conductive particle phase per length of 25 µm on the electrode surface is 0.60 to 0.85 µm, and a dispersion degree of the conductive particle phase in the electrode cross section per length of 100 µm in a direction parallel to the electrode surface is 2.0 to 4.0 µm. This electrode can be produced by firing a metal paste made by dispersing, in a solvent, a conductive particle having a core/shell structure in which a core particle such as Pt is covered with a ceramic shell and ceramic powder. The gas sensor electrode according to the present invention has a high electrode activity.
摘要:
The present invention relates to a technique for recovering and recycling a platinum paste. The present invention provides a method for recovering a metal powder from a platinum paste formed by mixing a solid component composed of a metal powder including at least a platinum powder or a platinum alloy powder and an organic component including at least an organic solvent, the method including removing the organic component by heating the platinum paste at a recovery temperature set in a temperature range of 300°C or higher and 500°C or lower. The recovered metal powder can be recycled into a platinum paste equivalent to a new product by mixing the metal powder with a solvent etc.
摘要:
The present invention is an electroconductive particle for forming an electrode including a precious metal particle including Pt or a Pt alloy and having an average particle diameter of 50 to 150 nm, a first ceramic particle including Al 2 O 3 or ZrO 2 dispersed in the precious metal particle and having an average particle diameter of 5 to 50 nm, and a second ceramic particle including Al 2 O 3 or ZrO 2 bonded to an outer periphery of the precious metal particle and having an average particle diameter of 5 to 50 nm. The sum of the volume of the first ceramic particle and the volume of the second ceramic particle is preferably 2 to 40 vol% based on the whole electroconductive particle. A metal paste containing the electroconductive particle according to the invention is one from which an electrode film of low resistance and excellent durability can be manufactured and further excellent in adherence and conformability to a substrate.
摘要翻译:本发明是用于形成包含Pt或Pt合金的平均粒径为50〜150nm的贵金属粒子的电极的导电性粒子,分散在贵金属中的Al 2 O 3或ZrO 2的第一陶瓷粒子 金属颗粒,平均粒径为5〜50nm,和包含Al 2 O 3或ZrO 2的第二陶瓷颗粒结合到贵金属颗粒的外周,平均粒径为5〜50nm。 相对于整个导电性粒子,第一陶瓷粒子的体积和第二陶瓷粒子的体积的总和优选为2〜40体积%。 含有根据本发明的导电颗粒的金属糊是可以制造具有低电阻和优异的耐久性的电极膜,并且对基材的粘附性和贴合性更好。