摘要:
This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
摘要:
Provided is a hydrogen production apparatus enabling reduction of energy needed for separation and collection of CO 2 in the hydrogen production. The hydrogen production apparatus includes a reformer, a heating device heating the reformer, a transformer, a hydrogen separation device separating and taking out hydrogen from transformed gas, a CO 2 separation device separating and taking out CO 2 from off-gas from which hydrogen was separated by the hydrogen separation device, a heat collecting device collecting heat of the reformed gas, heat of the transformed gas, and waste heat from the heating device, and a heat medium supply device supplying the heat medium having absorbed heat collected by the heat collecting device to the CO 2 separation device. The absorption liquid having absorbed CO 2 in off-gas is heated by the heat medium heated with collected heat, thereby releasing CO 2 .
摘要:
It is an objective of the invention to provide a method for operating hydrogen separation devices which is capable of efficiently suppressing hydrogen embrittlement in a hydrogen separation alloy membrane and to provide a hydrogen separation device that performs favorably during repeated starting/stopping operations thereof. There is provided a method for operating a hydrogen separation device for separating hydrogen from a mixture hydrogen gas using a membrane separation technique with a hydrogen separation alloy membrane. The method comprises the successive steps of: stopping supply of the mixture hydrogen gas to the hydrogen separation alloy membrane with a temperature of the membrane within a range from 300 to 600°C; supplying an oxidizing gas over a predetermined duration to at least an upstream side of the membrane with a temperature of the membrane within a range from 300 to 600°C; and lowering the temperature of the membrane to below 200°C.
摘要:
The present invention relates to a material capable of trapping an inflammable gas, such as hydrogen, comprising at least one metal oxide in a cementitious matrix. The present invention also relates to the preparation of such a material and to its various uses.
摘要:
A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.