摘要:
Disclosed is a reactive filter, that is a selective catalytic reduction filter or an oxidative reaction filter, including a porous substrate including internal pores having their inner surface, totally or partially, directly coated with a catalytic zeolite material resulting from an in situ hydrothermal synthesis. Also disclosed is a process for preparing such a reactive filter and the use thereof in an engine exhaust depolluting system.
摘要:
The present invention is directed to catalytic cracking additives comprising a metals trapping material; and a high activity catalyst. The present invention is directed to processes for the catalytic cracking of feedstock comprising contacting said feedstock under catalytic cracking conditions with a composition comprising a bulk catalyst and a catalytic cracking additive, wherein the catalytic cracking additive comprises a metals trapping material; and a high activity catalyst. The invention is also directed to processes for increasing the performance of a bulk catalyst in the presence of at least one metal comprising contacting a feedstock with a catalytic cracking additive comprising a metals trapping material; and a high activity catalyst.
摘要:
A reforming process, selective for the dehydrocyclization of paraffins to aromatics, is improved by using a bound catalyst containing multiple Group VIII (8-10) noble metals having different gradients within the catalyst and a nonacidic large-pore molecular sieve. The use of this catalyst results in greater selectivity of conversion of paraffins to aromatics and improved catalyst stability, particularly in the presence of small amounts of sulfur.
摘要:
A process for alkylating an isoparaffin containing up to 20 carbon atoms with an olefin containing from 2 to 12 carbon atoms comprises contacting the isoparaffin and olefin with a catalyst comprising a large pore zeolite and a Lewis acid at a temperature of -40 DEG C to 500 DEG C and a pressure up to 5000 psig (35000 kPa), wherein the molar ratio of the isoparaffin to the olefin is from 1:1 to 50:1 and the contacting takes place in the presence of water.
摘要:
A method for synthesizing a zeolite is described. The method may include the steps of: (a) preparing an aqueous mixture comprising water, a substituted hydrocarbon, and a 1-oxa-4-azacyclohexane derivative; (b) reacting the aqueous mixture; (c) obtaining a solution comprising an organo-1-oxa-4-azoniumcyclohexane compound; (d)) forming a reaction mixture comprising reactive sources of Al, and Si, and the solution; and (e) heating the reaction mixture to form the zeolite.
摘要:
A process for halogenation of benzene or benzene derivatives, by which dihalogenated benzene derivatives having halogen atoms at positions para to each other or trihalogenated derivatives having halogen atoms at the 1-, 2-, and 4-positions can be selectively produced. In halogenating benzene or a benzene derivative by using a zeolite catalyst, a zeolite (such as zeolite L) which either contains fluorine or has a crystallite diameter of 100 nm or below is used as the catalyst. The reaction is preferably conducted in the presence of a solvent, the solvent being preferably a halogen-containing compound.
摘要:
A process for treating a molecular sieve-containing alkylation catalyst to increase its selectivity for monoalkylation in which the alkylation catalyst is contacted with a feedstock comprising at least one organic compound under conditions such that a sufficient amount of carbonaceous material evenly deposits on the alkylation catalyst to substantially suppress its alkylation activity. The carbon-containing catalyst particles are then subjected to combustion by contacting them with a gaseous oxidizing agent at an elevated temperature to remove at least a portion of the carbonaceous material, preferably substantially all of the carbonaceous material, thereby increasing the selectivity of the catalyst for monoaklylation by at least about 1.0 percentage point. The resulting alkylation catalyst can be used to alkylate benzene and other aromatic compounds with ethylene, propylene or other olefins to produce high yields of ethylbenzene, cumene and other alkylated products. Preferably, the alkylation catalyst contains an ammonium-exchanged and steam stabilized Y zeolite.