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公开(公告)号：EP3687964A1
公开(公告)日：2020-08-05
申请号：EP18740988.3
申请日：2018-07-11
IPC分类号： C07C29/136 , C07C31/125
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公开(公告)号：EP2548858B2
公开(公告)日：2020-01-08
申请号：EP10847750.6
申请日：2010-11-04
发明人： ZHANG, Tao , TAI, Zhijun , WANG, Aiqin , ZHENG, Mingyuan
IPC分类号： C07C29/00 , C07C29/132 , C07C29/136 , C07C31/20 , B01J23/30 , B01J23/64
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3.发明授权PROCESS FOR PREPARING ETHYLENE GLYCOL FROM POLYHYDRIC COMPOUNDS 有权工艺生产乙烯二醇包含POLYHYDROXIDVERBINDUNGEN
公开(公告)号：EP2548858B1
公开(公告)日：2017-01-11
申请号：EP10847750.6
申请日：2010-11-04
发明人： ZHANG, Tao , TAI, Zhijun , WANG, Aiqin , ZHENG, Mingyuan
IPC分类号： C07C29/00 , C07C29/132 , C07C29/136 , C07C31/20 , B01J23/30 , B01J23/64
摘要： This invention provides methods for producing ethylene glycol from polyhydroxy compounds such as cellulose, starch, hemicellulose, glucose, sucrose, fructose, fructan, xylose and soluble xylooligosaccharides. The methods uses polyhydroxy compounds as the reactant, a composite catalyst having active components comprising one or more transition metals of Groups 8, 9, or 10, including iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, as well as tungsten oxide, tungsten sulfide, tungsten hydroxide, tungsten chloride, tungsten bronze oxide, tungsten acid, tungstate, metatungstate acid, metatungstate, paratungstate acid, paratungstate, peroxotungstic acid, pertungstate, heteropoly acid containing tungsten. Reacting at a temperature of 120-300 °C and a hydrogen pressure of 1-13 MPa under hydrothermal conditions to accomplish one-step catalytic conversion. It realizes efficient, highly selective, high yield preparation of ethylene glycol and proplyene glycol from polyhydroxy compounds. The advantage of processes disclosed in this invention include renewable raw material and high atom economy. At the same time, compared with other technologies that converts biomass raw materials into polyols, methods disclosed herein enjoy advantages including simple reaction process, high yield of targeted products, as well as easy preparation and low cost for the catalysts.
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公开(公告)号：EP2352713A2
公开(公告)日：2011-08-10
申请号：EP09831054.3
申请日：2009-12-02
发明人： HOLTZAPPLE, Mark, T. , GRANDA, Cesar, B. , TACO, Sebastian , ROSS, Michael, Kyle , LUCE, Gary , SPENCER, Rae Lynn , SPENCER, John Alanson
IPC分类号： C07C29/136 , C07C2/12 , C12P7/26 , C10L1/04
CPC分类号： C12P7/40 , C07C1/24 , C07C2/02 , C07C29/149 , C07C67/04 , C10G3/00 , C10G50/00 , C10G2300/1011 , C10G2300/4081 , C10G2300/42 , C10G2400/20 , C10G2400/22 , Y02P30/20 , C07C31/08 , C07C69/14
摘要： A method of producing alcohols, hydrocarbons, or both from biomass by converting biomass into a carboxylic acid, reacting the carboxylic acid with an olefin to produce an ester and hydrogenolyzing the ester to produce alcohol. A method of producing hydrocarbons from biomass by converting at least a portion of the biomass into a carboxylic acid, a ketone, or an ammonium carboxylate salt, reacting at least one of a portion of the carboxylic acid, a portion of the ketone, or a portion of the ammonium carboxylate salt in an oligomerization reactor as at least part of a process that produces an oligomerization product and separating hydrocarbons from the oligomerization product.
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5.发明公开PRODUCING METHANOL AND ITS PRODUCTS EXCLUSIVELY FROM GEOTHERMAL SOURCES AND THEIR ENERGY 审中-公开甲醇和产品来源的独家THEREOF生产和他们的能源地热
公开(公告)号：EP2300401A2
公开(公告)日：2011-03-30
申请号：EP09800788.3
申请日：2009-07-10
IPC分类号： C07C29/136 , C07C31/04 , C07C43/04 , C07C11/06
CPC分类号： C07C1/20 , C07C29/1518 , C07C41/09 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C43/043 , C07C31/04
摘要： The invention provides a method for producing methanol and its products exclusively from a geothermal source as the sole source material also using the needed energy from the geothermal energy source. The method includes separating or isolating carbon dioxide accompanying hot water or steam of the source, generating hydrogen from the water and preparing subsequently methanol from the carbon dioxide and hydrogen. The methanol can be further reacted to form dimethyl ether or other products.
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6.发明授权Fluoroalcohol preparation method, fluorinated monomer, polymer, resist composition and patterning process 有权一种用于氟醇，氟化单体，聚合物的制备过程中，抗蚀剂组合物，和图案化工艺
公开(公告)号：EP2070901B1
公开(公告)日：2010-12-22
申请号：EP08021787.0
申请日：2007-01-31
IPC分类号： C07C29/136 , C07C31/42 , C07C31/44 , G03F7/004 , C08F220/24 , C08F22/28
CPC分类号： G03F7/0395 , C07C29/147 , C07C69/54 , C07C69/653 , C07C69/753 , C07C2601/08 , C07C2601/14 , C07C2602/42 , C08F220/24 , C08F220/28 , C08F232/08 , G03F7/0046 , G03F7/0397 , C07C31/44 , C07C31/42 , C07C35/48
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公开(公告)号：EP1914218A1
公开(公告)日：2008-04-23
申请号：EP07112341.8
申请日：2007-07-12
申请人： Evonik Degussa GmbH
IPC分类号： C07C29/136 , C07C31/20
CPC分类号： C07C29/147 , C07C31/20
摘要： Es wird ein Verfahren zur Herstellung von 1,2-Diolen aus Carbonylverbindungen beschrieben, welches dadurch gekennzeichnet ist, dass man
a) zunächst eine Carbonylverbindung der allgemeinen Formel (I), worin R 1 und R 2 für H, einen ggf. substituierten geradkettigen oder verzweigten C 1 -C 18 -Alkylrest, einen ggf. substituierten Phenyl- oder C 5 -C 6 -Cycloalkylrest stehen, mit Blausäure zum entsprechenden Cyanhydrin umsetzt, dann
b) dass aus dem Verfahrensschritt a) erhaltene Cyanhydrin einer sauren Hydrolyse unterwirft und abschließend
c) die aus Verfahrensschritt b) erhaltene 2-Hydroxycarbonsäure mit Hilfe eines Edelmetallkatalysators auf Basis von Ruthenium und Rhenium katalytisch hydriert.
Auf diese Weise lassen sich 1,2-Diole in guten Ausbeuten und in sehr hoher Reinheit auf technisch einfache Weise (d. h. ohne Spezialapparaturen) herstellen.摘要翻译： 在0-100℃，在溶剂，碱性催化剂或有机胺的存在下使羰基化合物和氢氰酸反应制得1,2-戊二醇，得到氰醇; 使羟腈在30-130℃和升高的压力下进行酸性水解; 并在含有100-300℃和50-300巴的钌和/或铼金属催化剂存在下催化氢化所得的2-羟基羧基20小时。 在0-100℃下，在溶剂，碱性催化剂或有机胺的存在下使式R 1 -C（= O）-R 2和氢氰酸的羰基化合物反应制备1,2-戊二醇，得到 氰醇; 使羟腈在30-130℃和升高的压力下进行酸性水解; 并在铱和/或铼金属催化剂存在下在100-300℃和50-300巴下催化氢化所得的2-羟基羧基20小时。 R 1，R 2H，1-8C烷基，5-6C环烷基（两者任选被OH，NH 2和OR 3>取代）或苯基（任选被OH或NH 2取代）; R 3> 1-8烷基。
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8.发明公开Fluoroalcohol preparation method, fluorinated monomer, polymer, resist composition and patterning process 有权维生素Zur Herstellung von Fluoralkohol，fluoriertes Monomer，Polymer，Resistzusammensetzung und Strukturierungsverfahren
公开(公告)号：EP1829850A3
公开(公告)日：2007-09-12
申请号：EP07250422.8
申请日：2007-01-31
发明人： Hasegawa, Koji, c/o Shin-Etsu Chemical Co., Ltd , Kinsho, Takeshi, c/o Shin-Etsu Chemical Co., Ltd , Nishi, Tsunehiro, c/o Shin-Etsu Chemical Co., Ltd , Ohashi, Masaki, c/o Shin-Etsu Chemical Co., Ltd , Watanabe, Takeru, c/o Shin-Etsu Chemical Co., Ltd
IPC分类号： C07C29/136 , C07C31/42 , C07C31/44 , G03F7/004 , C08F220/24 , C08F22/28
CPC分类号： G03F7/0395 , C07C29/147 , C07C69/54 , C07C69/653 , C07C69/753 , C07C2601/08 , C07C2601/14 , C07C2602/42 , C08F220/24 , C08F220/28 , C08F232/08 , G03F7/0046 , G03F7/0397 , C07C31/44 , C07C31/42 , C07C35/48
摘要： Fluoroalcohol compounds of formula (4) are prepared by reacting a fluorine compound of formula (1) with reducing agents or organometallic reagents of formulas (2) and (3) wherein R 1 is H or a monovalent C 1 -C 20 hydrocarbon group in which any -CH 2 - moiety may be replaced by -O- or -C(=O)-, R 2 is H or a monovalent C 1 -C 6 hydrocarbon group, R 3 and R 4 are H or a monovalent C 1 -C 8 hydrocarbon group, and M 1 is Li, Na, K, Mg, Zn, Al, B, or Si. From the fluoroalcohol compounds, fluorinated monomers can be produced in a simple and economic way, which are useful in producing polymers for the formulation of radiation-sensitive resist compositions.
摘要翻译： 式（4）的氟化合物通过使式（1）的氟化合物与式（2）和（3）的还原剂或有机金属试剂反应来制备，其中R 1是H或一价C 1 -C 20烃基 其中任何-CH 2 - 部分可被-O-或-C（= O） - ，R 2为H或一价C 1 -C 6烃基，R 3和R 4为H或一价C 1 -C 8烃基，M 1为Li，Na，K，Mg，Zn，Al，B或Si。 从氟代醇化合物可以以简单和经济的方式制备氟化单体，其可用于制备用于制备辐射敏感抗蚀剂组合物的聚合物。
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9.发明公开
公开(公告)号：EP1000658A3
公开(公告)日：2000-06-28
申请号：EP99121980.9
申请日：1999-11-10
申请人： CHINA PETROCHEMICAL CORPORATION , Fushun Research Institute of Petroleum and Petrochemicals, Sinopec
发明人： Zhao, Leping, Inst. Petroleum & Petrochemicals , Zhang, Lijuan, Inst. Petroleum & Petrochemicals , Chen, Yuzhuo, Inst. Petroleum & Petrochemicals , Wang, Yuliang, Inst. Petroleum & Petrochemicals
IPC分类号： B01J23/72 , B01J35/10 , B01J37/03 , B01J23/80 , C07C29/136 , C07C29/145 , C07C45/00
CPC分类号： C07C29/145 , B01J23/72 , B01J23/80 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/1019 , B01J35/1038 , B01J35/1061 , C07C29/141 , C07C29/154 , C07C45/002 , Y02P20/52 , C07C31/04 , C07C31/12
摘要： This invention discloses a copper-containing catalyst, a process for the preparation thereof and uses of said catalyst. Said catalyst comprises copper oxide of 30-70wt%, zinc oxide of 30-70wt%, alumina of 0-30wt% and no sodium, and has a specific surface area of 30-50m 2 /g, a pore volume of 0.10-0.25ml/g, and an average pore diameter of 10-25nm and has an uniform crystallite distribution wherein the crystallites having a diameter of less than 1.0nm account for 0-10%, those of 1.0-2.0nm account for 80-95%, and those of more than 2.0nm account for 0-10%. Said process comprises a coprecipitation method using an organic acid and/or an ammonium salt thereof as precipitant to provide a copper-containing catalyst having a relatively large specific surface area and pore volume, and a uniform crystallite distribution. The process according to the present invention has overcome the problems involved in environmental protection and the disadvantages of complexity in the preparation process existing in the prior art, and the costs for materials and production are reduced.
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公开(公告)号：EP0895980A1
公开(公告)日：1999-02-10
申请号：EP98900435.3
申请日：1998-01-20
IPC分类号： C07C35/02 , C07C35/08 , C07C29/136 , C07C29/17
CPC分类号： C07C49/757 , C07C29/145 , C07C35/02 , C07C35/08 , C07C45/33 , C07C45/34 , C07C49/523 , C07C2601/14
摘要： A 3-hydroxymethylcycloalkanol of the formula (1)
wherein Y 1 represents a saturated aliphatic hydrocarbon group. The 3-hydroxyethylcycloalkanol can be obtained by subjecting a 3-formylcycloalkanone or 3-formylcycloalkenone to reduction.
Amended Abstract
The present invention relates to a 3-hydroxymethylcycloalkanol of the following formula (1), and a process for production of a 3-hydroxymethylcycloalkanol of the formula (1) by reduction of 3-formylcycloalkanone or 3-formylcycloalkenone.
In accordance with the present invention, 3-hydroxymethylcycioalkanol, which is useful as the starting material for the production of polymers, can be produced with high conversion and high selectivity.摘要翻译： 式（1）的3-羟甲基环烷醇，其中Y1表示饱和脂族烃基。 3-羟甲基环烷醇可以通过使3-甲酰基环烷酮或3-甲酰基环烯酮还原来获得。 （1）的3-羟甲基环烷醇和通过还原3-甲酰基环烷酮或3-甲酰基环烯酮制备式（1）的3-羟甲基环烷醇的方法本发明涉及下式（1）的3-羟甲基环烷醇。 根据本发明，可以高转化率和高选择性生产可用作生产聚合物的原料的3-羟甲基环烷醇。
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