摘要:
The present invention provides processes for making a bimodal solid polymer composition suitable for use as a viscosity index improver. Ethylene and an alpha-olefin comonomer are polymerized in the presence of a metallocene catalyst to form first and second copolymers, in series or parallel reactors, ehich are combined to form an intimate blend of relatively high and relatively low ethylene content copolymers in the solvent use. The composition can be further grafted and derivatized to provide a viscosity index improver, the composition being produced directly with the correct viscosity, without the need for additional blending, shearing or masticating steps.
摘要:
An interpolymer composition comprising monomer-derived units of (i) at least one of an aliphatic olefin containing from 2 to 30 carbon atoms and a vinyl aromatic monomer, and (ii) at least one alpha, beta-unsaturated acylating agent; wherein a portion of said acylating agent monomers is esterified and wherein a portion of said acylating agent monomers is condensed with at least one aromatic amine, provides good viscosity modification and dispersancy performance.
摘要:
Graft copolymers, particularly useful as dispersant viscosity index improvers in lubricating oil compositions have a polymer backbone selected from the group consisting of olefin polymers, diene polymers, vinyl polymers and vinylidene polymers, which is grafted with an amine selected from N-p-diphenylamine,1,2,3,6-tetrahydrophthalimide; 4-anilinophenyl methacrylamide; 4-anilinophenyl maleimide; 4-anilinophenyl itaconamide; acrylate and methacrylate esters of 4-hydroxydiphenylamine; the reaction product of p-aminodiphenylamine or p-alkylaminodiphenylamine with glycidyl methacrylate; the reaction product of p-aminodiphenylamine with isobutyraldehyde, derivatives of p-hydroxydiphenylamine; derivatives of phenothiazine; vinylogous derivatives of diphenylamine; and mixtures thereof and may be prepared in a single step process using solution or bulk grafting conditions.
摘要:
The present invention provides processes for making a bimodal solid polymer composition suitable for use as a viscosity index improver. Ethylene and an alpha-olefin comonomer are polymerized in the presence of a metallocene catalyst to form first and second copolymers, in series or parallel reactors, ehich are combined to form an intimate blend of relatively high and relatively low ethylene content copolymers in the solvent use. The composition can be further grafted and derivatized to provide a viscosity index improver, the composition being produced directly with the correct viscosity, without the need for additional blending, shearing or masticating steps.
摘要:
An aqueous cutting liquid comprises a cationic water-soluble resin having an amine value of 20 to 200 mgKOH/g, and at least one members of a rheology control agent selected from the group consisting of an inorganic bentonite, an organic bentonite and an aqueous silica sol, wherein the content of a nonvolatile matter of the rheology control agent is 0.1 to 30 percent by weight of the amount of the nonvolatile matter of the cationic water-soluble resin. An aqueous cutting agent comprises the aqueous cutting, and an abrasive grain, wherein the content of the abrasive grain is 100 to 1000 percent by weight of the amount of the nonvolatile matter of the aqueous cutting liquid. A hard and brittle material is cut by a cutting device using the aqueous cutting agent. The present invention provides an aqueous cutting agent which is excellent in dispersion stability of the abrasive grain and viscosity stability during cutting/cutting operations, aqueous cutting liquid usable for the aqueous cutting agent, and a cutting/cutting method excellent in cutting performance, cleanability and the like of the work material on cutting/cutting hard and brittle material by using the cutting agent.
摘要:
Die Erfindung betrifft Schmieröladditive mit einem Gehalt an Pfropfpolymeren mit Viskositäts-Index-verbessernder Wirkung wobei die Pfropfpolymeren PFP aufgebaut sind aus Polyalkylmethacrylat-Makromonomeren (A) in Anteilen von 10 - 90 Gew.-% bezogen auf PFP, die copolymerisiert sind mit Alkyl(meth)acrylsäureestern (AMA) mit C 6 -C 30 -Alkylresten in Anteilen von 0 - 90 Gew.-% bezogen auf PFP und mit nicht-funktionalisierten Comonomeren (B) ausgewählt aus der Gruppe bestehend aus Alkyl(meth)acrylsäureestern mit C 1 -C 5 -Alkylresten, Styrol, Alkylstyrolen mit C 1 - C 4 -Alkylresten und Fettsäurevinylestern mit 2 bis 12 C-Atomen im Fettsäurerest in Anteilen von 0 - 60 Gew.-% bezogen auf PFP sowie mit funktionalisierten Comonomeren (C) ausgewählt aus der Gruppe bestehend aus funktionalisierten (Meth)acrylsäureestern und -amiden und der Vinyl-Heterocyclen in Anteilen von 0 - 40 Gew.-% bezogen auf PFP mit der Maßgabe, daß die Summe der copolymeri-sierten Monomeren bezogen auf PFP 10 bis 90 Gew.-% ausmacht in einem Trägermedium TM.
摘要:
Lubricant additives having dispersant and anti-oxidant properties can be prepared: (A) by reacting (i) homopolymers of alpha-monoolefins having 2 to 10 carbon atoms, or copolymers of such olefins with non-conjugated dienes or trienes, said homopolymers or copolymers having molecular weights of 300 to 3500, with (ii) at least one olefinic carboxylic acid acylating agent to form a reaction intermediate having a carboxylic acid acylating function, and (B) reacting the resulting intermediate from (A) with an amino-aromatic polyamine selected from (a) an N-arylphenylene diamine, (b) an aminothiazole, (c) an aminocarbazole, (d) an amino-indazolinone, (e) an aminomercaptotriazole, or (f) an aminoperimidine. i
摘要:
Improved dispersant/VI improver luboil additives are produced by reacting a star polymer with an alpha, beta unsaturated carboxylic acid or derivative to form an activated star polymer, which is then reacted with a) an alkyl carboxylic acid and b) an alkylamine or alkane polyol, or with the preformed product of reactants a) and b).
摘要:
The novel polymers of the present invention are prepared by graft polymerization of at least one aromatic nitrogen-containing monomer onto an amino-substituted polymer (e.g., an ethylene alpha-olefin interpolymer substituted by primary amino or secondary amino groups). Preferred aromatic nitrogen-containing moieties are illustrated by aniline, and preferred amino-substituted interpolymers comprise amino-substituted ethylene propylene norbornene terpolymers. The polymers of this invention are oil soluble and are useful as dispersant and antioxidant additives in oleaginous compositions and are further useful in electrical, textile and other applications.