公开(公告)号：JP2010053222A

公开(公告)日：2010-03-11

申请号：JP2008218307

申请日：2008-08-27

Applicant: Terumo Clinical Supply Co Ltd ,  テルモ・クリニカルサプライ株式会社

Inventor： NOSHIRO TAKESHI ,  OMAE KOJI ,  MANABE TOMOYUKI

IPC: C08F8/12 ,  C08F218/14 ,  C08F220/18

Abstract: PROBLEM TO BE SOLVED: To provide water-absorbing polymer particles little in toxicity. SOLUTION: There is provided a method for producing the water-absorbing polymer particles, comprising copolymerizing a vinyl ester-based compound with an ethylene-based unsaturated carboxylate and then saponifying the obtained copolymer, characterized by using a water-alcohol mixture solvent containing the water in an amount of ≤30 mass% as a saponification solvent on the saponification reaction, and performing the saponification reaction using an alkali in an amount of ≥1.5 mol per mole of the monomers for the copolymer as the saponification alkali. The obtained water-absorbing polymer particles have a physiological salt solution absorption of ≤40 g/g. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：提供吸水性聚合物颗粒的毒性很小。 提供一种吸水性聚合物粒子的制造方法，其特征在于，使乙烯基酯系化合物与乙烯系不饱和羧酸酯共聚，然后皂化所得共聚物，其特征在于使用水 - 醇混合溶剂 在皂化反应中含有≤30质量％的水作为皂化溶剂，并且使用每摩尔共聚物单体≥1.5摩尔的碱作为皂化碱进行皂化反应。 得到的吸水性聚合物粒子的生理盐溶液吸收率为≤40g/ g。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP4221456B2

公开(公告)日：2009-02-12

申请号：JP25091898

申请日：1998-09-04

Applicant: 豊 常盤 ,  独立行政法人産業技術総合研究所 ,  甲南化工株式会社

Inventor： 豊 常盤 ,  隆生 楽

IPC: B01F17/52 ,  C08F218/14 ,  C08F218/04 ,  C11D1/74

公开(公告)号：JP3147988B2

公开(公告)日：2001-03-19

申请号：JP12857992

申请日：1992-05-21

IPC: C08F2/50 ,  C08F2/48 ,  C08F18/14 ,  C08F218/14 ,  C08F220/10 ,  C08F220/18

公开(公告)号：JP3091366B2

公开(公告)日：2000-09-25

申请号：JP16310494

申请日：1994-06-22

IPC: C08F8/12 ,  C08F16/02 ,  C08F18/02 ,  C08F18/14 ,  C08F216/06 ,  C08F218/02 ,  C08F218/04 ,  C08F218/08 ,  C08F218/14

公开(公告)号：JPH08505606A

公开(公告)日：1996-06-18

申请号：JP51252594

申请日：1994-01-28

IPC: C07C407/00 ,  C07C409/34 ,  C08F4/34 ,  C08F10/00 ,  C08F18/14 ,  C08F18/24 ,  C08F210/02 ,  C08F212/00 ,  C08F214/06 ,  C08F214/08 ,  C08F218/02 ,  C08F218/08 ,  C08F218/14 ,  C08F218/16 ,  C08F220/10

公开(公告)号：JPH0681770B2

公开(公告)日：1994-10-19

申请号：JP26577688

申请日：1988-10-20

Applicant: SUMITOMO SEIKA KK

Inventor： ARAKAWA TSUTOMU ,  MINORIKAWA NAOKI ,  MARUYAMA SATOSHI ,  TAKOSHI HIROTAKA ,  YOSHIDA HARUO

IPC: G02B1/04 ,  C08F18/14 ,  C08F20/10 ,  C08F20/38 ,  C08F218/14 ,  C08F220/38 ,  C08J7/04 ,  C09D4/00 ,  C09D4/02 ,  C09J4/02

公开(公告)号：JPH06211941A

公开(公告)日：1994-08-02

申请号：JP2364493

申请日：1993-01-18

Applicant: NITTO KASEI CO LTD

Inventor： TABUCHI HITOSHI ,  MORI KIYOMI ,  TAKESAWA TOSHIYUKI

IPC: C08F212/14 ,  C08F12/00 ,  C08F16/32 ,  C08F18/14 ,  C08F20/10 ,  C08F212/34 ,  C08F216/12 ,  C08F218/14 ,  C08F220/28 ,  C09D4/00 ,  C09D5/14 ,  C09D5/16 ,  C09D125/00 ,  C09D129/00 ,  C09D129/10 ,  C09D131/04 ,  C09D133/00 ,  C09D133/04

Abstract: PURPOSE:To obtain the subject composition capable of giving a coating film which can keep a suitable solubility in seawater for a long time by copolymerizing a specified crosslinking monomer with an ethylenically unsaturated monomer in the presence of a polymerization modifier. CONSTITUTION:100 pts.wt. monomer mixture comprising a cross-linking monomer of formula I (wherein X and Y are groups of formulas II-VI; R is H or methyl; (m) is 1-5; and (n) is 0-2) and other copolymerizable and ethylenically unsaturated monomers in the presence of 1-20 pts.wt. polymerization modifier to obtain a hydrolyzable resin composition of a weight-average molecular weight of 10000-100000. 5-200wt.% antifouling component is added to this composition to obtain the objective composition.

公开(公告)号：JPH05241212A

公开(公告)日：1993-09-21

申请号：JP1929592

申请日：1992-02-05

Applicant: MITSUBISHI PETROCHEMICAL CO

Inventor： KISHIMOTO MANABU ,  ODA ATSUSHI ,  NAKAJIMA KENJI ,  SEO IWAO

IPC: C08F8/12 ,  C08F8/18 ,  C08F8/30 ,  C08F8/34 ,  C08F18/02 ,  C08F218/14 ,  C08F220/42 ,  C08F222/34 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361

Abstract: PURPOSE:To enhance a nonlinear optical effect and to improve moldability by constituting the above material with specific structural units. CONSTITUTION:This org. nonlinear optical material is a polymer which consists of the structural units expressed by formulas I and II and in which the unit I is 5 to 100mol%, the unit II is 0 to 95mol% and the mol. wt. is 10,000 to 2,000,000. In the formula, m denotes an integer from 1 to 10; n denotes 0, 1; X denotes formula III; A denotes-NO2,-CN,-CF3 etc,; Y denotes a hydrogen atom, halogen atom,-NO2,-CN,-CF3 etc.; p denotes an integer from 1 to 10. This polymer is synthesized by, for example, three stages; a polymerizing stage, hydrolyzing stage and photofunctional group introducing stage. The org. nonlinear optical material is obtd. by residsolving the resulted copolymer in an org. solvent, such as sulfolane, adding a base, such as pyridine triethylamine, to the soln. and heating the soln. together with the nonlinear optical compd. to be introduced. The nonlinear optical compd. to be introduced includes, for example, P-nitroaniline and its deriv., 4-methyl sulfone biphenyl deriv., etc.

公开(公告)号：JPH0312282B2

公开(公告)日：1991-02-19

申请号：JP10195680

申请日：1980-07-25

Applicant: SEIKO EPSON CORP

Inventor： KASAI YOSHIHIKO ,  SUMI HIROO

IPC: C08F12/00 ,  C08F18/00 ,  C08F18/14 ,  C08F20/00 ,  C08F20/10 ,  C08F212/14 ,  C08F218/14 ,  C08F220/00 ,  C08F220/30 ,  C08F220/38 ,  C08F220/40 ,  C08F299/02 ,  G02B1/04

公开(公告)号：JPS61115915A

公开(公告)日：1986-06-03

申请号：JP23776984

申请日：1984-11-12

Applicant: Mitsubishi Rayon Co Ltd

Inventor： NAKAMOTO HIDEO ,  FUKUSHIMA HIROSHI

IPC: C08F18/00 ,  C08F16/32 ,  C08F18/14 ,  C08F20/26 ,  C08F216/12 ,  C08F218/00 ,  C08F218/14 ,  C08F220/30 ,  G02B1/04

Abstract: PURPOSE: The titled material having a high transmittance to visible light, a high refractive index and being excellent in scratch resistance, solvent resistance, etc., prepared by copolymerizing a biphenyl (meth)acrylate monomer with a monomer containing a plurality of (meth)allyl groups.
CONSTITUTION: A plastic lens material is prepared by copolymerizing a monomer of formula I (wherein R
1 is H or CH
3 , R
2 is a group of formula II and n is 0W2), e.g., o-biphenyl (meth)acrylate, with a monomer containing at least two (meth)allyl groups in the molecule (e.g., diethylene glycol bisallyl carbonate). This lens material has a visible light transmittance ≥88% and a refractive index as high as 1.55 or above and can well meet various properties necessary for a spectacle lens, such as scratch resistance, solvent resistance and grindability with diamond wheels.
COPYRIGHT: (C)1986,JPO&Japio

Abstract translation: 目的：通过使（甲基）丙烯酸联苯酯单体与含有多个（甲基）丙烯酸酯的单体共聚而制备的，对可见光透射率高，折射率高，耐刮擦性优异，耐溶剂性优异的标题材料， 烯丙基。 构成：通过使式I的单体（其中R 1是H或CH 3，R 2是式II的基团，n是0-2），例如，邻 - （甲基）丙烯酸邻苯二甲酸酯共聚合制备塑料透镜材料， 在分子中含有至少两个（甲基）烯丙基的单体（例如二甘醇双烯丙基碳酸酯）。 该透镜材料的可见光透射率> 88％，折射率高达1.55以上，可以很好地满足眼镜镜片的各种特性，例如耐刮擦性，耐溶剂性和金刚石砂轮的研磨性。