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    Process for the monosulfonation of aromatic phosphines, and zwitterionic product derived therefrom
    1.
    发明授权
    Process for the monosulfonation of aromatic phosphines, and zwitterionic product derived therefrom 有权
    芳香膦单磺化的方法和由其衍生的两性离子产物

    公开(公告)号：US07754924B2

    公开(公告)日：2010-07-13

    申请号：US12064064

    申请日：2006-09-14

    申请人： Donald L. Morrison ,  Kurt D. Olson ,  Walter C. Reed ,  Anthony G. Abatjoglou

    发明人： Donald L. Morrison ,  Kurt D. Olson ,  Walter C. Reed ,  Anthony G. Abatjoglou

    IPC分类号： C07F5/02

    CPC分类号： C07F9/5022 ,  C07F9/5442 ,  C07F9/5449

    摘要： A method of preparing an aromatic phosphine monosulfonate in zwitterionic form, such as dicyclohexylphenylphosphine monosulfonate zwitterion, involving contacting an aromatic phosphine with a sulfonating agent to provide a reaction mixture containing aromatic phosphine monosulfonate in acid form and unconverted sulfonating agent; quenching or removing substantially all of the unconverted sulfonating agent; partially neutralizing the aromatic phosphine monosulfonate in acid form to phase separate aromatic phosphine monosulfonate in zwitterionic form as a solid or neat liquid layer; and collecting the zwitterion as a solid or neat liquid. The zwitterion may be neutralized to form the corresponding aromatic phosphine monosulfonate metal salt, which is useful in preparing catalysts for hydroformylation processes.

    摘要翻译： 一种以两性离子形式制备芳族膦单磺酸盐如二环己基苯基膦单磺酸盐两性离子的方法，包括使芳族膦与磺化剂接触以提供含有酸形式的芳族膦单磺酸盐和未转化的磺化剂的反应混合物; 淬火或去除基本上所有未转化的磺化剂; 部分中和酸形式的芳族膦单磺酸盐作为固体或纯液体层以两性离子形式相分离芳香族膦单磺酸盐; 并收集两性离子作为固体或纯净液体。 两性离子可以被中和形成相应的芳族膦单磺酸盐金属盐，其可用于制备用于加氢甲酰化方法的催化剂。

    Process for the production of amines, hydroxyamines and aziridines
    3.
    发明授权
    Process for the production of amines, hydroxyamines and aziridines 失效
    制备胺，羟基胺和氮丙啶的方法

    公开(公告)号：US4973709A

    公开(公告)日：1990-11-27

    申请号：US134815

    申请日：1987-12-18

    申请人： Kurt D. Olson ,  Steven W. Kaiser

    发明人： Kurt D. Olson ,  Steven W. Kaiser

    IPC分类号： C07D487/08

    CPC分类号： C07D487/08

    摘要： Alkanolamines can be converted to a cyclic or a cyclic alkylamines and aziridines and/or other cyclic or acyclic alkanolamines by contacting the alkanolamines with a molecular sieve selected from the group consisting of (a) non-zeolitic molecular sieves; and (b) zeolites having a silicon:aluminum ratio of at least about 6, the contacting of the alkanolamine starting material with the molecular sieve being effected under conditions effective to convert the alkanolamine starting material into at least one of the specified products.

    摘要翻译： 通过使链烷醇胺与选自（a）非沸石分子筛的分子筛接触，可将烷醇胺转化为环状或环状烷基胺和氮丙啶和/或其它环状或非环状烷醇胺; 和（b）具有至少约6的硅：铝比的沸石，所述链烷醇胺原料与分子筛的接触在有效将烷醇胺原料转化为至少一种特定产物的条件下进行。

    Process for the production of amides
    4.
    发明授权
    Process for the production of amides 失效
    酰胺生产工艺

    公开(公告)号：US4873325A

    公开(公告)日：1989-10-10

    申请号：US878215

    申请日：1986-06-25

    申请人： Kurt D. Olson

    发明人： Kurt D. Olson

    IPC分类号： B01J29/04 ,  B01J29/84 ,  B01J29/85 ,  B01J29/86 ,  C07B31/00 ,  C07B43/06 ,  C07C67/00 ,  C07D201/04

    CPC分类号： C07D201/04 ,  B01J29/84 ,  B01J29/86

    摘要： Oximes can be converted to the corresponding amides by contacting the oximes with a non-zeolitic molecular sieve, which has in its calcined form an adsorption of isobutane of at least about 2 percent by weight of the non-zeolitic molecular sieve at a partial pressure of 500 torr and a temperature of 20.degree. C. The process is especially useful for the conversion of cyclohexanone oxime to caprolactam. The non-zeolitic molecular sieves can achieve improved conversion rates and selectivities as compared with conventional zeolite catalysts for the reaction.

    摘要翻译： 肟可以通过使肟与非沸石分子筛接触而转化为相应的酰胺，该非沸石分子筛在其煅烧形式下吸附至少约2重量％的非沸石分子筛的异丁烷，分压 500托，温度为20℃。该方法特别适用于将环己酮肟转化为己内酰胺。 与用于反应的常规沸石催化剂相比，非沸石分子筛可以实现改进的转化率和选择性。

    Process for the condensation of aldehydes
    5.
    发明授权
    Process for the condensation of aldehydes 失效
    醛缩合过程

    公开(公告)号：US4701562A

    公开(公告)日：1987-10-20

    申请号：US878201

    申请日：1986-06-25

    申请人： Kurt D. Olson

    发明人： Kurt D. Olson

    IPC分类号： B01J29/04 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  C07C45/00 ,  C07C45/62 ,  C07C45/72 ,  C07C45/73 ,  C07C45/74 ,  C07C45/75 ,  C07C47/20 ,  C07C49/04 ,  C07C67/00

    CPC分类号： C07C45/73 ,  C07C45/002 ,  C07C45/62 ,  C07C45/74 ,  C07C45/75

    摘要： Aldehydes can be condensed with ketones or aldehydes to produce higher aldehydes or ketones by contacting the materials to be condensed with a nonzeolitic molecular sieve. The condensation may be carried out in the presence of hydrogen to give as product a saturated aldehyde or ketone. The ketone and/or aldehyde may be generated in situ by dehydrogenation of an alcohol, and the hydrogen thus liberated used to effect hydrogenation of the immediate unsaturated product of the condensation, thereby producing as the final product a saturated aldehyde or ketone. The non-zeolitic molecular sieves can achieve improved conversion rates and selectivities as compared with conventional catalysts for the reaction.

    摘要翻译： 醛可以与酮或醛缩合，以通过使待冷凝的材料与非沸石分子筛接触而产生更高级的醛或酮。 缩合可以在氢的存在下进行，得到饱和的醛或酮的产物。 酮和/或醛可以通过醇的脱氢和由此释放的氢原位产生，从而实现缩合的直接不饱和产物的氢化，由此产生饱和醛或酮的最终产物。 与用于反应的常规催化剂相比，非沸石分子筛可以实现改进的转化率和选择性。

    Process for the Monosulfonation of Aromatic Phosphines, and Zwitterionic Product Derived Therefrom
    7.
    发明申请
    Process for the Monosulfonation of Aromatic Phosphines, and Zwitterionic Product Derived Therefrom 有权
    芳香膦单磺化方法及其衍生的两性离子产物

    公开(公告)号：US20080221363A1

    公开(公告)日：2008-09-11

    申请号：US12064064

    申请日：2006-09-14

    申请人： Donald L. Morrison ,  Kurt D. Olson ,  Walter C. Reed ,  Anthony G. Abatjoglou

    发明人： Donald L. Morrison ,  Kurt D. Olson ,  Walter C. Reed ,  Anthony G. Abatjoglou

    IPC分类号： C07F9/54

    CPC分类号： C07F9/5022 ,  C07F9/5442 ,  C07F9/5449

    摘要： A method of preparing an aromatic phosphine monosulfonate in zwitterionic form, such as dicyclohexylphenylphosphine monosulfonate zwitterion, involving contacting an aromatic phosphine with a sulfonating agent to provide a reaction mixture containing aromatic phosphine monosulfonate in acid form and unconverted sulfonating agent; quenching or removing substantially all of the unconverted sulfonating agent; partially neutralizing the aromatic phosphine monosulfonate in acid form to phase separate aromatic phosphine monosulfonate in zwitterionic form as a solid or neat liquid layer; and collecting the zwitterion as a solid or neat liquid. The zwitterion may be neutralized to form the corresponding aromatic phosphine monosulfonate metal salt, which is useful in preparing catalysts for hydroformylation processes.

    摘要翻译： 一种以两性离子形式制备芳族膦单磺酸盐如二环己基苯基膦单磺酸盐两性离子的方法，包括使芳族膦与磺化剂接触以提供含有酸形式的芳族膦单磺酸盐和未转化的磺化剂的反应混合物; 淬火或去除基本上所有未转化的磺化剂; 部分中和酸形式的芳族膦单磺酸盐作为固体或纯液体层以两性离子形式相分离芳香族膦单磺酸盐; 并收集两性离子作为固体或纯净液体。 两性离子可以被中和形成相应的芳族膦单磺酸盐金属盐，其可用于制备用于加氢甲酰化方法的催化剂。

    Process for the condensation of ketones
    8.
    发明授权
    Process for the condensation of ketones 失效
    酮缩合的方法

    公开(公告)号：US4704478A

    公开(公告)日：1987-11-03

    申请号：US878268

    申请日：1986-06-25

    申请人： Kurt D. Olson

    发明人： Kurt D. Olson

    IPC分类号： B01J29/04 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  C07B31/00 ,  C07B37/04 ,  C07C45/00 ,  C07C45/62 ,  C07C45/73 ,  C07C45/74 ,  C07C67/00 ,  C07C45/72

    CPC分类号： C07C45/74 ,  C07C45/002 ,  C07C45/62 ,  C07C45/73

    摘要： Two ketone molecules (which can be the same or different) can be condensed together in the presence of hydrogen to produce a higher ketone by contacting the materials to be condensed with a hydrogenation catalyst and with a non-zeolitic molecular sieve, which has in its calcined form an adsorption of isobutane of at least about 2 percent by weight of the non-zeolitic molecular sieve at a partial pressure of 500 torr and a temperature of 20.degree. C. One or both ketones may be generated in situ by dehydrogenation of an alcohol. The non-zeolitic molecular sieves can achieve improved conversions and selectivities as compared with most conventional catalysts for the reaction.

    摘要翻译： 两个酮分子（其可以相同或不同）可以在氢的存在下一起冷凝，通过使待冷凝的材料与氢化催化剂和非沸石分子筛接触而产生较高的酮， 煅烧形成非沸石分子筛的至少约2重量％的异丁烷的吸附，分压为500托，温度为20℃。一种或两种酮可以通过醇的脱氢原位产生 。 与用于反应的大多数常规催化剂相比，非沸石分子筛可以实现改进的转化率和选择性。

    HYDROFORMYLATION PROCESS AND PRODUCT SEPARATION WITH IMPROVED RECOVERY OF RHODIUM
    9.
    发明申请
    HYDROFORMYLATION PROCESS AND PRODUCT SEPARATION WITH IMPROVED RECOVERY OF RHODIUM 有权
    氢氧化工艺和产品分离与改进的RHODIUM恢复

    公开(公告)号：US20090118548A1

    公开(公告)日：2009-05-07

    申请号：US12299853

    申请日：2007-04-17

    申请人： Wei-Jun Peng ,  Kurt D. Olson ,  Donald L. Morrison ,  Brian M. Roesch ,  Donald L. Bunning ,  Jeffrey G. Hippler ,  Vincent J. Stricker

    发明人： Wei-Jun Peng ,  Kurt D. Olson ,  Donald L. Morrison ,  Brian M. Roesch ,  Donald L. Bunning ,  Jeffrey G. Hippler ,  Vincent J. Stricker

    IPC分类号： C07C45/50

    CPC分类号： C07C45/80 ,  C07C45/50 ,  C07C67/347 ,  Y02P20/584 ,  C07C69/738 ,  C07C69/716 ,  C07C47/02

    摘要： A non-aqueous hydroformylation process with liquid catalyst recycle involving a hydroformylation step and one or more stages of phase separation to recover a high molecular weight aldehyde product with efficient recovery of rhodium catalyst. The process includes a hydroformylation step to prepare a non-aqueous hydroformylation reaction product composition comprising one or more aldehyde products, one or more conjugated polyolefins, a rhodium-organophosphorus ligand complex, free organophosphorus ligand, and an organic solubilizing agent for said complex and said free ligand, and thereafter one or more stages of phase separation using added water under a carbon monoxide gas, hydrogen gas, or a mixture thereof. The process requires a specific range of total pressure for the hydroformylation, a specific range of total pressure for at least one of the separation stages, and a minimum sum of the total pressure of the hydroformylation step and the total pressure of the separation stage containing said gas.

    摘要翻译： 具有液体催化剂循环的非水羰基化方法，其涉及加氢甲酰化步骤和一个或多个相分离阶段以回收高分子量醛产物并有效回收铑催化剂。 该方法包括加氢甲酰化步骤，以制备包含一种或多种醛产物，一种或多种共轭聚烯烃，铑 - 有机磷配体络合物，游离有机磷配体和用于所述络合物的有机增溶剂的非水羰基化反应产物组合物和所述 游离配体，然后在一氧化碳气体，氢气或其混合物中使用加入的水进行一个或多个相分离阶段。 该方法需要加氢甲酰化的总压力的特定范围，至少一个分离阶段的总压力的特定范围，以及加氢甲酰化步骤的总压力和含有所述分离阶段的分离阶段的总压力的最小总和 加油站。