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    Method for the Preparation of Olefin Polymerisation Catalyst
    2.
    发明申请
    Method for the Preparation of Olefin Polymerisation Catalyst 失效
    烯烃聚合催化剂的制备方法

    公开(公告)号：US20080249263A1

    公开(公告)日：2008-10-09

    申请号：US11597865

    申请日：2005-06-02

    申请人： Thomas Garoff ,  Paivi Waldvogel

    发明人： Thomas Garoff ,  Paivi Waldvogel

    IPC分类号： C08F2/00 ,  C08F4/44

    CPC分类号： C08F10/00 ,  C08F4/6548 ,  C08F4/6546 ,  C08F4/6555

    摘要： The invention is directed to a process for producing an olefin polymerization catalyst wherein a solution of a soluble magnesium complex containing an element of is Group 13 or 14 of the Periodic Table (IUPAC) is contacted with a halogen containing transition metal compound of Group 3 to 10 of the Periodic Table (IUPAC) to obtain a solid catalyst complex comprising as essential components Mg, said element of is Group 13 or 14 of the Periodic Table (IUPAC) and said transition metal compound.

    摘要翻译： 本发明涉及一种生产烯烃聚合催化剂的方法，其中将含有元素周期表（IUPAC）的第13或14族的可溶性镁络合物的溶液与第3族的含卤素的过渡金属化合物接触， 10的元素周期表（IUPAC），以获得包含作为必需组分Mg的固体催化剂络合物，所述元素是元素周期表（IUPAC）的第13或14族和所述过渡金属化合物。

    Process for preparing a Ziegler-Natta catalyst
    4.
    发明授权
    Process for preparing a Ziegler-Natta catalyst 失效
    齐格勒 - 纳塔催化剂的制备方法

    公开(公告)号：US06818584B2

    公开(公告)日：2004-11-16

    申请号：US10182371

    申请日：2002-07-29

    申请人： Thomas Garoff ,  Solveig Johansson ,  Paivi Waldvogel

    发明人： Thomas Garoff ,  Solveig Johansson ,  Paivi Waldvogel

    IPC分类号： B01J3100

    CPC分类号： C08F10/00 ,  C08F4/6548 ,  C08F4/6555 ,  C08F4/6546

    摘要： Especially homogeneous supported Ziegler-Natta catalysts may be prepared in a simple one reaction vessel process from a magnesium hydrocarbyloxy starting material which is soluble in a hydrocarbon solvent. The process comprises: (I) reacting a magnesium hydrocarbyloxy compound with a chlorine-containing compound in a non-polar hydrocarbon solvent in which said magnesium hydrocarbyloxy compound is soluble whereby to produce a solution (A); and then either: (II) contacting the solution (A) with a chlorine containing tetravalent titanium compound to produce a solution (B); (III) impregnating solution (B) into a porous particulate support; or (II) impregnating solution (A) into a porous particulate support; and (III) contacting the solid support with a chlorine containing tetravalent titanium compound; or (II) impregnating solution (A) into a porous particulate support pretreated with a chlorine containing tetravalent titanium compound.

    摘要翻译： 特别均匀的齐格勒 - 纳塔催化剂可以在简单的一种反应容器方法中由可溶于烃溶剂的镁烃氧基起始原料制备。 该方法包括：（I）使镁烃氧基化合物与含氯化合物在其中所述镁烃氧基化合物可溶的非极性烃溶剂中反应，从而产生溶液（A）; 然后：（II）使溶液（A）与含氯的四价钛化合物接触以产生溶液（B）; （III）浸渍溶液（B）加入到多孔颗粒载体中; 或（II）浸渍溶液（A）进入多孔颗粒载体; 和（III）使固体载体与含氯四价钛化合物接触; 或（II）浸渍溶液（A）加入用含氯四价钛化合物预处理的多孔颗粒载体中。

    Method for the preparation of catalyst components for the polymerization of ethylene with a relatively narrow molecular weight distribution and protocatalyst composition
    5.
    发明授权
    Method for the preparation of catalyst components for the polymerization of ethylene with a relatively narrow molecular weight distribution and protocatalyst composition 失效
    制备具有较窄分子量分布和原始催化剂组合物的乙烯聚合催化剂组分的方法

    公开(公告)号：US5322830A

    公开(公告)日：1994-06-21

    申请号：US762635

    申请日：1991-09-18

    申请人： Pekka Sormunen ,  Jukka Koskinen ,  Paivi Waldvogel

    发明人： Pekka Sormunen ,  Jukka Koskinen ,  Paivi Waldvogel

    IPC分类号： C08F10/02 ,  C08F4/60 ,  C08F4/658 ,  C08F10/00 ,  B01J35/08

    CPC分类号： C08F10/00 ,  Y10S526/904

    摘要： The invention relates to a method for the preparation of a supported procatalyst intended for the polymerization of olefins, in which particles are formed from magnesium halide and alcohol, the particles are reacted with an organometallic compound of any of the metals of the groups I to III, the thus obtained particulate product is activated by means of a titanium(IV) compound, and optionally a prepolymerization is carried out for the activated particles. A problem with this kind of a method is, how to form particles from magnesium dihalide and alcohol having an advantageous structure for the polymerization of ethylene and particularly ethylene with a narrow molecular weight distribution. The problem has in the present invention been solved so that the particles are formed by spray-crystallizing a mixture of magnesium dihalide and alcohol to complex particles of magnesium dihalide and alcohol and that titanium(IV) alcoxyhalide has been used as the titanium compound. The catalytic properties of the particles thus obtained are improved, especially after the prepolymerization carried out by means of ethylene, which leads in the polymerization to a still more active, very hydrogen and comonomer sensible procatalyst having a better molecular weight selectivity.The invention also relates to the specific use of the procatalyst prepared by such a method for the polymerization of alpha-olefins. By a procatalyst is meant in this context the catalyst component of the Ziegler-Natta-catalyst which is based on the transition metal and which before the polymerization is combined with the organometallic compound of aluminium or some other metal acting as a cocatalyst.

    摘要翻译： 本发明涉及用于制备用于聚合烯烃的负载型前催化剂的方法，其中颗粒由卤化镁和醇形成，颗粒与I至III族金属中的任何金属的有机金属化合物反应 ，由此获得的颗粒产物通过钛（IV）化合物活化，并且任选地对活化颗粒进行预聚合。 这种方法的问题在于，如何从具有有利结构的二卤化镁和醇形成颗粒，用于聚合乙烯，特别是具有窄分子量分布的乙烯。 解决了本发明的问题，使得通过将二卤化镁和醇的混合物喷雾结晶到二卤化镁和醇的复合颗粒中形成颗粒，并且已经使用钛（IV）二氧化铝作为钛化合物。 由此获得的颗粒的催化性能得到改善，特别是在通过乙烯进行预聚合之后，其导致聚合反应更具有更高分子量选择性的更活泼，非常氢和共聚单体的显性前催化剂。 本发明还涉及通过这种α-烯烃聚合方法制备的前催化剂的具体用途。 主催化剂是指在本文中，基于过渡金属并在聚合之前的齐格勒 - 纳塔催化剂的催化剂组分与作为助催化剂的铝或其它金属的有机金属化合物组合。

    Multi-stage process for producing multi-modal linear low density polyethylene
    6.
    发明授权
    Multi-stage process for producing multi-modal linear low density polyethylene 有权
    生产多模式线性低密度聚乙烯的多阶段工艺

    公开(公告)号：US08409681B2

    公开(公告)日：2013-04-02

    申请号：US13126496

    申请日：2010-02-22

    申请人： Thomas Garoff ,  Paivi Waldvogel ,  Kalle Kallio ,  Virginie Eriksson ,  Aki Aittola ,  Esa Kokko

    发明人： Thomas Garoff ,  Paivi Waldvogel ,  Kalle Kallio ,  Virginie Eriksson ,  Aki Aittola ,  Esa Kokko

    IPC分类号： B32B1/08 ,  C08F2/14 ,  C08F2/34 ,  C08F210/14 ,  C08F4/685

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2410/03 ,  Y10T428/139 ,  C08F4/6357 ,  C08F4/685 ,  C08F2/001 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/05 ,  C08F2500/18 ,  C08F210/14 ,  C08F2500/08

    摘要： A process is disclosed for producing a multi-modal linear low density polyethylene in at least two staged reactors connected in series, comprising (i) polymerizing in a first slurry phase stage ethylene monomers with a Ziegler-Natta polymerization catalyst system to obtain a first polyethylene fraction component (A); and (ii) polymerizing in a second gas or slurry phase stage ethylene monomers with a Ziegler-Natta polymerization catalyst system to obtain a second polyethylene fraction component (B). The Ziegler-Natta polymerization catalyst system comprises: 1) a solid procatalyst formed by contacting at least: a) a Mg-alcoholate complex of formula (I) b) an aluminum compound of formula (II); and c) a vanadium compound and a titanium compound having a molar ratio (V:Ti) from 10:90 to 90:10; and 2) one or more organometallic cocatalvsts of formula (III). The linear low density polyethylene shows an improved comonomer composition distribution Formulas (I), (II), and (III) are described herein.

    摘要翻译： 公开了一种用于在至少两个分级反应器中串联生产多模式线性低密度聚乙烯的方法，其包括（i）在第一浆液阶段中聚合乙烯单体与齐格勒 - 纳塔聚合催化剂体系以获得第一聚乙烯 级分组分（A）; 和（ii）在齐格勒 - 纳塔聚合催化剂体系中在第二气体或浆料相阶段中聚合乙烯单体以获得第二聚乙烯级分组分（B）。 齐格勒 - 纳塔聚合催化剂体系包括：1）通过使至少a）使式（I）的Mg-醇合物络合物b）式（II）的铝化合物与式 和c）钒化合物和摩尔比（V:Ti）为10:90至90:10的钛化合物; 和2）式（III）的一种或多种有机金属助催化剂。 线性低密度聚乙烯显示改进的共聚单体组成分布本文描述了式（I），（II）和（III）。

    Procatalyst for ethylene polymer production, method for its preparation and use
    9.
    发明授权
    Procatalyst for ethylene polymer production, method for its preparation and use 失效
    用于乙烯聚合物生产的主催化剂，其制备和使用方法

    公开(公告)号：US6034026A

    公开(公告)日：2000-03-07

    申请号：US14674

    申请日：1998-01-28

    申请人： Thomas Garoff ,  Solveig Johansson ,  Ulf Palmqvist ,  Daniel Lindgren ,  Marita Sutela ,  Paivi Waldvogel ,  Arja Kostiainen

    发明人： Thomas Garoff ,  Solveig Johansson ,  Ulf Palmqvist ,  Daniel Lindgren ,  Marita Sutela ,  Paivi Waldvogel ,  Arja Kostiainen

    IPC分类号： C08F4/654 ,  B01J37/00 ,  C08F4/02 ,  C08F4/64 ,  C08F4/646 ,  C08F4/651 ,  C08F4/655 ,  C08F4/658 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F110/06 ,  B01J31/00

    CPC分类号： C08F110/02 ,  C08F110/06

    摘要： The invention relates to a process for the preparation of a high activity procatalyst for the production of ethylene polymers. The process according to the present invention comprises the following steps:(a) contacting the inorganic support with an alkyl metal chloride which is soluble in non-polar hydrocarbon solvents, and has the formula(R.sub.n MeCl.sub.3-n).sub.m (1)wherein R is a C.sub.1 -C.sub.20 aklyl group, Me is a metal of group III(13) of the periodic table, n=1 or 2 and m=1 or 2, to give a first reaction product,(b) contacting said first reaction product with a compound or mixture containing hydrocarbyl and hydrocarbyl oxide linked to magnesium which is soluble in non-polar hydrocarbon solvents, to give a second reaction product, and(c) contacting said second reaction product with a titanium compound which contains chlorine, having the formulaCl.sub.x Ti(OR.sup.IV).sub.4-x (2)wherein R.sup.IV is a C.sub.2 -C.sub.20 hydrocarbyl group and x is 3 or 4, to give said procatalyst.

    摘要翻译： 本发明涉及制备用于生产乙烯聚合物的高活性前催化剂的方法。 根据本发明的方法包括以下步骤：（a）使无机载体与可溶于非极性烃溶剂的烷基金属氯化物接触，并具有式（RnMeCl 3-n）m（1）其中R为 C 1 -C 20亚烷基，Me是周期表III（13）的金属，n = 1或2，m = 1或2，得到第一反应产物，（b）使所述第一反应产物与 与可溶于非极性烃溶剂的镁连接的烃基和烃基氧化物的化合物或混合物，得到第二反应产物，和（c）使所述第二反应产物与含有氯的钛化合物接触，所述钛化合物具有式Cl x Ti（ ORIV）4-x（2）其中RIV为C 2 -C 20烃基，x为3或4，得到所述前催化剂。

    Linear low density polyethylene with uniform or reversed comonomer composition distribution
    10.
    发明授权
    Linear low density polyethylene with uniform or reversed comonomer composition distribution 有权
    具有均匀或反相共聚单体组成分布的线性低密度聚乙烯

    公开(公告)号：US08546499B2

    公开(公告)日：2013-10-01

    申请号：US13318101

    申请日：2010-04-26

    申请人： Thomas Garroff ,  Paivi Waldvogel ,  Kallio Kalle ,  Virginie Eriksson ,  Aki Aittola ,  Esa Kokko

    发明人： Thomas Garroff ,  Paivi Waldvogel ,  Kallio Kalle ,  Virginie Eriksson ,  Aki Aittola ,  Esa Kokko

    IPC分类号： C08F4/44

    CPC分类号： C08F210/16 ,  C08L2314/02 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/08 ,  C08F2500/10

    摘要： Ziegler-Natta catalyzed linear low density polyethylene which satisfies the following conditions:a) a density, according to ISO 1183, of from 900 to 925 kg/m3,b) a C4-C10-comonomer content, determined by Fourier transform infrared spectroscopy, of 1 to 16 wt %c) a weight average molecular weight Mw, determined by gel permeation chromatography, of at least 200 000,d) wherein the linear low density polyethylene comprises, by Crystallisation Analysis Fractionation (CRYSTAF) an amorphous fraction soluble at a temperature below 30° C. of at most 10 wt % and a fraction crystallising between 60 to 75° C. of at least 35 wt % ande) by temperature rising elution fractionation (TREF) analysis, at least 70 wt % of a crystallising polymer component having an elution temperature range from 60° C. to 94° C. and less than 10 wt % of a crystallising polymer component having an elution temperature range from 30° C. to 60° C. and,f) by Gel Permeation chromatography coupled with Fourier transform infrared spectroscopy detector (GPC-FTIR), a substantially constant short chain branching profile across the molecular weight distribution (MWD) org) by Gel Permeation chromatography coupled with Fourier transform infrared spectroscopy instruments (GPC-FTIR), a reverse short chain branching profile across the molecular weight distribution (MWD),the linear low density polyethylene being produced in the presence of a special Ziegler-Natta procatalyst and a halogenated aluminium alkyl cocatalyst of the formula (IV) (C1-C4- alkyl)m-Al-X3−m, wherein X is chlorine, bromine, iodine or fluorine and m is 1 or 2.

    摘要翻译： 齐格勒 - 纳塔催化的线性低密度聚乙烯，其满足以下条件：a）根据ISO 1183的密度为900至925kg / m 3，b）通过傅立叶变换红外光谱测定的C 4 -C 10共聚单体含量， c）通过凝胶渗透色谱测定的至少200000重量平均分子量Mw，d）其中线性低密度聚乙烯通过结晶分析分馏（CRYSTAF）包含在 温度低于30℃，至多10重量％，并且在60至75℃之间结晶至少35重量％的级分，e）通过升温洗脱分级（TREF）分析，至少70重量％的结晶 具有洗脱温度范围为60℃至94℃且小于10重量％的具有洗脱温度范围为30℃至60℃的结晶聚合物组分的聚合物组分，以及f）通过凝胶渗透 色谱与傅里叶变换耦合 （GPC-FTIR），通过分子量分布（MWD）基本上恒定的短链支化分子，或g）通过凝胶渗透色谱法与傅立叶变换红外光谱仪（GPC-FTIR），反向短链支化 在分子量分布（MWD）的范围内，线性低密度聚乙烯是在特殊的齐格勒 - 纳塔前催化剂和式（Ⅳ）的卤化烷基铝助催化剂（C 1 -C 4烷基）m-Al- X3-m，其中X是氯，溴，碘或氟，m是1或2。