Delayed activity supported olefin polymerization catalyst compositions and method for making and using the same

    公开(公告)号:US07012121B2

    公开(公告)日:2006-03-14

    申请号:US10880582

    申请日:2004-07-01

    Abstract: Supported catalyst compositions use for use in the gas-phase polymerization of one or more α-olefins and methods for making and using the same, the catalyst composition including A) an inert support; B) a Group 4–10 metal complex corresponding to the formula: where M is a metal from one of Groups 4 to 10 of the Periodic Table of the Elements in the +2 or +4 formal oxidation state, Cp is a π-bonded anionic ligand group, Z is divalent moiety bound to Cp and bound to M by either covalent or coordinate/covalent bonds and contains boron or a member of Group 14 of the Periodic Table of the Elements, and also nitrogen, phosphorus, sulfur or oxygen, and X is a neutral conjugated diene ligand group having up to 60 atoms, or a dianionic derivative thereof; and C) an ionic cocatalyst capable of converting the metal complex into an active polymerization catalyst represented by the formula: [L*-H]+[(C6F5)3BC6H4—O—MORCx-1Xay]−, wherein L* is a neutral Lewis base, Mo is a metal or metalloid selected from Groups 1–14 of the Periodic Table of the Elements, RC independently each occurrence is a hydrogen or a hydrocarbyl, hydrocarbylsilyl, or hydrocarbysilylhydrocarbyl group having from 1 to 80 nonhydrogen atoms; Xa is a halo-substituted hydrocarbyl, hydrocarbylamino-substituted hydrocarbyl, hydrocarbyloxy-substituted hydrocarbyl, hydrocarbylamino, di(hydrocarbyl)amino, hydrocarbyloxy or halide noninterfering group having from 1 to 100 nonhydrogen atoms; x is an integer which ranges from 1 to an integer equal to the valence of MO; y is an integer which ranges from 0 to an integer equal to 1 less than the valence of MO; and x+y equals the valence of MO.

    Thiocyanomethyloxy (and thiocyanothiomethyl)-1,2,3-benzatriazin-4(3H)
ones, compositions containing them and their use as antimicrobial and
marine antifouling agents
    7.
    发明授权
    Thiocyanomethyloxy (and thiocyanothiomethyl)-1,2,3-benzatriazin-4(3H) ones, compositions containing them and their use as antimicrobial and marine antifouling agents 失效
    硫氰酸甲氧基(和硫氰硫基甲基)-1,2,3-苯并三嗪-4(3H),含有它们的组合物及其作为抗微生物剂和船用防污剂

    公开(公告)号:US5885991A

    公开(公告)日:1999-03-23

    申请号:US883622

    申请日:1997-06-26

    CPC classification number: A01N43/707 C09D5/14 C09D5/1625

    Abstract: Disclosed are thiocyanomethyloxy(or thiocyanomethylthio)-1,2,3-benzatriazin-4(3H)-one compounds corresponding to one of the formulae: ##STR1## wherein Z represents oxygen or sulfur; X represents --C1, --F, --I, C.sub.1 -C.sub.7 straight or branched chain alkyl, C.sub.1 -C.sub.7 straight or branched chain alkoxy, --CF.sub.3, --OCF.sub.3, --CN, --COOR wherein R is C.sub.1 -C.sub.7 straight or branched chain alkyl and n is an integer of from 0-4.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed. e

    Abstract translation: 公开了对应于下式之一的硫代氰基甲氧基(或硫代氰基甲硫基)-1,2,3-苯并三嗪-4(3H) - 酮化合物:其中Z表示氧或硫; X表示-C1,-F,-I,C1-C7直链或支链烷基,C1-C7直链或支链烷氧基,-CF3,-OCF3,-CN,-COOR,其中R为C1-C7直链或支链 烷基,n为0-4的整数。 已经发现这些化合物在工业和商业应用中表现出抗微生物和海洋防污性,并且使用含有这些化合物的组合物。

    ((4-phenyl-1,2,5-thiadiazol-3-yl)oxy)methyl ester thiocyanic acid
compounds, compositions containing them and their use as antimicrobial
and marine antifouling agents
    8.
    发明授权
    ((4-phenyl-1,2,5-thiadiazol-3-yl)oxy)methyl ester thiocyanic acid compounds, compositions containing them and their use as antimicrobial and marine antifouling agents 失效
    ((4-苯基-1,2,5-噻二唑-3-基)氧基)甲酯硫氰酸化合物,含有它们的组合物及其作为抗微生物和海洋防污剂的用途

    公开(公告)号:US5661165A

    公开(公告)日:1997-08-26

    申请号:US676619

    申请日:1996-07-10

    CPC classification number: C07D285/10 A01N43/82

    Abstract: Disclosed are ((4-phenyl-1,2,5--thiadiazol-3-yl)oxy)methyl ester thiocyanic acid compounds corresponding to the formula: ##STR1## wherein X represents --Br, --Cl, --F, --CF.sub.3, --OCF.sub.3, --CN, C.sub.1 -C.sub.7 straight or branched chain alkyl, C.sub.1 -C.sub.7 straight or branched chain alkoxy or --COOR wherein R is --H or C.sub.1 -C.sub.7 straight or branched chain alkyl and n is an integer of from 0-5.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.

    Abstract translation: 公开了对应于下式的((4-苯基-1,2,5-噻二唑-3-基)氧基)甲基酯硫氰酸化合物:其中X表示-Br,-Cl,-F ,-CF 3,-OCF 3,-CN,C 1 -C 7直链或支链烷基,C 1 -C 7直链或支链烷氧基或-COOR,其中R为-H或C 1 -C 7直链或支链烷基,n为 从0-5。 已经发现这些化合物在工业和商业应用中表现出抗微生物和海洋防污性,并且使用含有这些化合物的组合物。

    1-substituted-5-thiomethylthiocyanato-1H-tetrazoles, compositions
containing them and their use as antimicrobial and marine antifouling
agents
    9.
    发明授权
    1-substituted-5-thiomethylthiocyanato-1H-tetrazoles, compositions containing them and their use as antimicrobial and marine antifouling agents 失效
    1-取代-5-硫代甲硫基氰化1H-四唑,含有它们的组合物及其作为抗微生物和海洋防污剂的用途

    公开(公告)号:US5455222A

    公开(公告)日:1995-10-03

    申请号:US360491

    申请日:1994-12-21

    CPC classification number: C07D257/04

    Abstract: Disclosed are substituted-5-thiomethylthiocyanato-1H-tetrazole compounds corresponding to the formula ##STR1## wherein R represents a C.sub.1 -C.sub.6 straight or branched chain alkyl radical, a C.sub.3 -C.sub.6 cycloalkyl or a phenyl radical of the formula ##STR2## wherein each X independently represents hydrogen, halo, a C.sub.1 -C.sub.6 straight or branched chain alkyl radical, a C.sub.3 -C.sub.6 cycloalkyl radical, a C.sub.1 -C.sub.6 straight or branched chain alkoxy radical, a C.sub.3 -C.sub.6 cycloalkoxy radical, cyano or nitro and n is 0-5.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.

    Abstract translation: 公开了对应于下式的取代-5-硫代甲硫基氰硫基-1H-四唑化合物,其中R表示C1-C6直链或支链烷基,C3-C6环烷基或具有式IMAGE的苯基,其中各 X独立地表示氢,卤素,C1-C6直链或支链烷基,C3-C6环烷基,C1-C6直链或支链烷氧基,C3-C6环烷氧基,氰基或硝基,n为0 -5。 已经发现这些化合物在工业和商业应用中表现出抗微生物和海洋防污性,并且使用含有这些化合物的组合物。

    Preparation of
5,7-dihydroxy-1,2,4-triazolo[1,5-a]pyrimidine-2-sulfonanilides
    10.
    发明授权
    Preparation of 5,7-dihydroxy-1,2,4-triazolo[1,5-a]pyrimidine-2-sulfonanilides 失效
    5,7-二羟基-1,2,4-三唑并[1,5-a]嘧啶-2-磺酰苯胺的制备

    公开(公告)号:US5006656A

    公开(公告)日:1991-04-09

    申请号:US484960

    申请日:1990-02-26

    CPC classification number: C07D487/04

    Abstract: 5,7-Dihydroxy-N-(aryl)-1,2,4-triazolo[1,5-a]pyrimidine-2-sulfonamides are prepared by the cyclization of N-(3-(((aryl)amino)sulfonyl)-1H-1,2,4-triazol-5-yl)amines with malonyl halides under acidic conditions. With the addition of a phosphorus oxyhalide, malonic acid can be used in place of the malonyl halides and the 5,7-dihydroxy-1,2,4-triazolo[1,5-a]pyrimidine can be directly converted to the corresponding 5,7-dihalo derivative.

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