公开(公告)号：US20240145765A1

公开(公告)日：2024-05-02

申请号：US17768731

申请日：2020-10-14

Applicant: ATTACCATO Limited Liability Company ,  ADEKA Corporation

Inventor： Takashi Mukai ,  Naoto Yamashita ,  Yuta Ikeuchi ,  Taichi Sakamoto ,  Kenji Kakiage ,  Tomofumi Yokomizo ,  Yohei Aoyama

IPC: H01M10/0562 ,  H01M4/04 ,  H01M4/36 ,  H01M4/02

CPC classification number: H01M10/0562 ,  H01M4/0404 ,  H01M4/0471 ,  H01M4/366 ,  H01M2004/021 ,  H01M2300/0068

Abstract: A non-aqueous electrolyte power storage device in which a coating material having a silanol group is present at least on a surface of an electrode active material layer and a sulfur-based material is contained in a cell, the electrode active material layer contains an electrode active material and a resin-based binder, the electrode active material is an active material capable of being alloyed with a metal element identical to an ion species responsible for electrical conduction or an active material capable of absorbing ions responsible for electrical conduction, and the coating material having a silanol group is a silicate containing a siloxane bond as a component or a silica fine particle aggregate (containing a siloxane bond as a component).

公开(公告)号：US12209156B2

公开(公告)日：2025-01-28

申请号：US17763839

申请日：2020-09-14

Applicant: ADEKA CORPORATION

Inventor： Hiromi Takenouchi ,  Kensaku Akimoto ,  Kenji Kakiage ,  Hirokatsu Shinano ,  Tomofumi Yokomizo

IPC: C08F8/34 ,  C08F20/44

Abstract: The present invention provides a method of producing sulfur-modified polyacrylonitrile, including: a step (1) of heating polyacrylonitrile and elemental sulfur in a rotating-type heating container including a discharge pipe and a sulfur vapor recovery unit while rotating the rotating-type heating container; a step (2) of liquefying a sulfur vapor by the sulfur vapor recovery unit while discharging hydrogen sulfide generated in the heating step; and a step (3) of returning the liquefied sulfur to a mixture of the sulfur and the polyacrylonitrile of the step (1).

公开(公告)号：US09881745B2

公开(公告)日：2018-01-30

申请号：US14899129

申请日：2014-08-12

Applicant: ADEKA CORPORATION

Inventor： Kensaku Akimoto ,  Yohei Aoyama ,  Kenji Kakiage

IPC: H01G9/20 ,  C09B23/08 ,  C09B23/06 ,  H01L51/00 ,  C09B23/01 ,  C09B23/10 ,  C09B57/00 ,  C09B57/10

CPC classification number: H01G9/2059 ,  C09B23/0033 ,  C09B23/0058 ,  C09B23/0066 ,  C09B23/06 ,  C09B23/083 ,  C09B23/105 ,  C09B57/00 ,  C09B57/10 ,  H01G9/2013 ,  H01G9/2018 ,  H01G9/2031 ,  H01L51/0064 ,  H01L51/0072 ,  H01L51/0083 ,  Y02E10/542

Abstract: Disclosed is a dye-sensitized solar cell which includes a working electrode and a counter electrode facing each other with an electrolyte layer therebetween, the working electrode having a dye-supporting metal oxide electrode composed of a metal oxide layer having a dye supported thereon. The dye contains a cyanine dye, and the electrolyte of the electrolyte layer contains a cobalt-based electrolyte. It is preferred to use at least one cyanine dye represented by general formula (1) as the cyanine dye. Anq− represents a q-valent anion, wherein q represents 1 or 2, and p represents a coefficient for maintaining overall charge neutrality.

公开(公告)号：US09812263B2

公开(公告)日：2017-11-07

申请号：US15081023

申请日：2016-03-25

Applicant: ADEKA CORPORATION

Inventor： Minoru Hanaya ,  Kenji Kakiage ,  Masafumi Unno ,  Yohei Aoyama ,  Toru Yano ,  Daisuke Sawamoto ,  Hiroyuki Osada

IPC: H01L31/04 ,  H01G9/20 ,  H01L51/00 ,  C07F17/02 ,  C07F7/18 ,  H01L31/0256 ,  C09B1/16 ,  C09B23/01 ,  C09B23/14 ,  C09B23/16 ,  C09B29/08 ,  C09B57/00

CPC classification number: H01G9/2059 ,  C07F7/1804 ,  C07F17/02 ,  C09B1/16 ,  C09B23/0075 ,  C09B23/14 ,  C09B23/145 ,  C09B23/164 ,  C09B29/0808 ,  C09B57/00 ,  H01G9/2031 ,  H01L31/0256 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0055 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0065 ,  H01L51/0068 ,  H01L51/007 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0083 ,  H01L51/0094 ,  Y02E10/542

Abstract: Disclosed is a novel compound represented by formula (1) below. In the formula, A represents an optionally substituted aromatic hydrocarbon ring or aromatic heterocyclic group, B represents a group including a chain of one to four pieces of one or more groups selected from groups represented by specific formulae (B-1) to (B-13) (such as —C═C— or —N═N—, specifically see the description), R1 to R3 each represent an optionally substituted hydrocarbon or hydrocarbonoxy group, at least one of R1 to R3 represents an optionally substituted hydrocarbonoxy group, R4 and R5 each represent an optionally substituted hydrocarbon group, R4 and R5 may be linked together to form a ring, and R4 and R5 may be each independently linked with A to form a ring

公开(公告)号：US11955637B2

公开(公告)日：2024-04-09

申请号：US17295617

申请日：2019-11-22

Applicant: ATTACCATO Limited Liability Company ,  ADEKA Corporation

Inventor： Takashi Mukai ,  Naoto Yamashita ,  Yuta Ikeuchi ,  Taichi Sakamoto ,  Kenji Kakiage ,  Hiroyuki Osada ,  Yohei Aoyama

IPC: H01M4/00 ,  H01M4/04 ,  H01M4/38 ,  H01M4/46 ,  H01M4/58 ,  H01M4/62 ,  H01M4/66

CPC classification number: H01M4/5825 ,  H01M4/0404 ,  H01M4/382 ,  H01M4/466 ,  H01M4/622 ,  H01M4/662

Abstract: To provide an electrode for non-aqueous electrolyte batteries, which traps hydrogen sulfide gas, generated from the inside thereof for some reason, in the electrode, and suppresses the outflow of hydrogen sulfide gas to the outside of the battery. An electrode for lithium ion batteries includes a coating material which contains a silanol group and is present on at least a surface of an active material layer. The active material layer contains a sulfur-based material and a resin-based binder. The sulfur-based material is an active material capable of alloying with lithium metal or an active material capable of occluding lithium ions. The coating material containing the silanol group is a silicate having a siloxane bond or a silica fine particle aggregate having a siloxane bond as a component.

公开(公告)号：US11594732B2

公开(公告)日：2023-02-28

申请号：US16960782

申请日：2019-02-25

Applicant: ADEKA CORPORATION

Inventor： Hiromi Takenouchi ,  Tomofumi Yokomizo ,  Hirokatsu Shinano ,  Kenji Kakiage ,  Yuta Nohara ,  Yohei Aoyama

IPC: H01M4/60 ,  C08F8/36 ,  C08K3/08

Abstract: Disclosed is an electrode active material that has a large charge discharge capacity, a high initial efficiency, as well as excellent cycle characteristics and rate characteristics and is favorably used in a non-aqueous electrolyte secondary battery. An organo sulfur-based electrode active material contains sodium and potassium in a total amount of 100 ppm by mass to 1000 ppm by mass; an electrode for use in a secondary battery, the electrode containing the organo sulfur-based electrode active material as an electrode active material; and a non-aqueous electrolyte secondary battery including the electrode. Preferably, the organo sulfur-based electrode active material further contains iron in an amount of 1 ppm by mass to 20 ppm by mass. Preferably, the organo sulfur-based electrode active material is sulfur-modified polyacrylonitrile, and the amount of sulfur in the organo sulfur-based electrode active material is 25 mass % to 60 mass %.

公开(公告)号：US20220020989A1

公开(公告)日：2022-01-20

申请号：US17295617

申请日：2019-11-22

Applicant: ATTACCATO Limited Liability Company ,  ADEKA Corporation

Inventor： Takashi Mukai ,  Naoto Yamashita ,  Yuta Ikeuchi ,  Taichi Sakamoto ,  Kenji Kakiage ,  Hiroyuki Osada ,  Yohei Aoyama

IPC: H01M4/58 ,  H01M4/62 ,  H01M4/66 ,  H01M4/38 ,  H01M4/46 ,  H01M4/04

Abstract: To provide an electrode for non-aqueous electrolyte batteries, which traps hydrogen sulfide gas, generated from the inside thereof for some reason, in the electrode, and suppresses the outflow of hydrogen sulfide gas to the outside of the battery. An electrode for lithium ion batteries includes a coating material which contains a silanol group and is present on at least a surface of an active material layer. The active material layer contains a sulfur-based material and a resin-based binder. The sulfur-based material is an active material capable of alloying with lithium metal or an active material capable of occluding lithium ions. The coating material containing the silanol group is a silicate having a siloxane bond or a silica fine particle aggregate having a siloxane bond as a component.

公开(公告)号：US11223045B2

公开(公告)日：2022-01-11

申请号：US16756580

申请日：2018-10-30

Applicant: ADEKA CORPORATION

Inventor： Hirokatsu Shinano ,  Kenji Kakiage ,  Yohei Aoyama

IPC: H01M4/60 ,  H01M4/70 ,  H01M4/66

Abstract: Disclosed is a sulfur-based electrode active material with which a nonaqueous electrolyte secondary battery that has a large capacity and exhibits less deterioration of the cycle characteristics can be obtained even when an electrode is employed in which the sulfur-based electrode active material is used as an electrode active material and an aluminum foil is used as a current collector. Also disclosed is a method for producing an organosulfur electrode active material, including a step of obtaining an organosulfur compound by heat-treating an organic compound and sulfur and a step of treating the organosulfur compound with a basic compound. The organosulfur compound is preferably sulfur-modified polyacrylonitrile, and the basic compound is preferably ammonia. The organosulfur compound may be treated with the basic compound after the organosulfur compound is ground, or may be ground in a medium that contains the basic compound.

公开(公告)号：US10734684B2

公开(公告)日：2020-08-04

申请号：US15749513

申请日：2016-09-14

Applicant: ADEKA CORPORATION

Inventor： Yuta Nohara ,  Kenji Kakiage ,  Tomofumi Yokomizo ,  Hiroaki Watanabe ,  Yohei Aoyama ,  Toru Yano

IPC: H01M10/0567 ,  C07F7/18 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/42

Abstract: Disclosed is a nonaqueous secondary battery having a nonaqueous electrolyte containing a lithium salt dissolved in an organic solvent, in which the positive electrode active material is preferably a manganese-containing, lithium transition metal oxide salt. The nonaqueous electrolyte contains at least one compound of general formula (1), preferably at least one compound of general formula (1′). The content of the compound of formula (1) or (1′) in the nonaqueous electrolyte is preferably 0.001 to 10 mass %. The symbols in formulae (1) and (1′) are as defined in the description.