公开(公告)号：US10378146B2

公开(公告)日：2019-08-13

申请号：US15620219

申请日：2017-06-12

Applicant: AGC Inc.

Inventor： Akira Isobe ,  Minako Shimada ,  Yuuichi Oomori

IPC: C09D5/00 ,  C09D5/16 ,  C09K3/18 ,  D06M15/29 ,  C08F214/06 ,  C08F214/18 ,  C08F220/12 ,  C08F220/18 ,  C08F220/22 ,  C08F220/24 ,  C08F222/18 ,  C09D127/14 ,  C09D133/04 ,  C09D133/16 ,  C09D133/24 ,  D06M101/34 ,  D06M15/248 ,  D06M15/256 ,  D06M15/263 ,  D06M15/277 ,  D06M15/353 ,  D06M15/576

Abstract: To provide a water/oil repellent composition whereby it is possible to obtain an article which is excellent in each of water repellency, oil repellency and heavy rain durability, a method for its production, and an article which is excellent in each of water repellency, oil repellency, heavy rain durability and texture. The water/oil repellent composition comprises a copolymer containing structural units based on a monomer (a), structural units based on a monomer (b) and structural units based on a monomer (c). Here, the monomer (a) is a compound represented by (Z—Y)nX (wherein Z is a C1-6perfluoroalkyl group, etc.; Y is a bivalent organic group, etc.; n is 1 or 2; and X is a polymerizable unsaturated group). The monomer (b) is a (meth)acrylate having no polyfluoroalkyl group and having an alkyl group with at least 12 carbon atoms. The monomer (c) is a monomer having a poly(oxypolyfluoroalkylene) chain.

公开(公告)号：US10829666B2

公开(公告)日：2020-11-10

申请号：US16715155

申请日：2019-12-16

Applicant: AGC Inc.

Inventor： Taiki Hoshino ,  Kiyotaka Takao ,  Kazue Toda ,  Kenji Ishizeki ,  Akira Isobe

IPC: C09D201/04 ,  C08G65/336 ,  C08G65/00 ,  C08G65/329 ,  C07F7/18 ,  C07F7/10 ,  C09D171/00 ,  B32B33/00 ,  C08F259/08 ,  C09D201/10

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1-Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.

公开(公告)号：US10550288B2

公开(公告)日：2020-02-04

申请号：US15877489

申请日：2018-01-23

Applicant: AGC Inc.

Inventor： Taiki Hoshino ,  Kiyotaka Takao ,  Kazue Toda ,  Kenji Ishizeki ,  Akira Isobe

IPC: C09D201/04 ,  B32B33/00 ,  C08F259/08 ,  C09D201/10 ,  C07F7/10 ,  C07F7/12

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1-Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.

公开(公告)号：US12071563B2

公开(公告)日：2024-08-27

申请号：US17038304

申请日：2020-09-30

Applicant: AGC Inc.

Inventor： Taiki Hoshino ,  Kiyotaka Takao ,  Kazue Toda ,  Kenji Ishizeki ,  Akira Isobe

IPC: C09D201/04 ,  B32B33/00 ,  C07F7/18 ,  C08F259/08 ,  C08G65/00 ,  C08G65/329 ,  C08G65/336 ,  C09D171/00 ,  C09D201/10

CPC classification number: C09D201/04 ,  B32B33/00 ,  C07F7/1804 ,  C08F259/08 ,  C08G65/007 ,  C08G65/329 ,  C08G65/336 ,  C09D171/00 ,  C09D201/10 ,  B32B2307/7265 ,  B32B2307/746

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.

公开(公告)号：US11643572B2

公开(公告)日：2023-05-09

申请号：US17118665

申请日：2020-12-11

Applicant: AGC Inc.

Inventor： Taiki Hoshino ,  Kiyotaka Takao ,  Kazue Toda ,  Kenji Ishizeki ,  Akira Isobe

IPC: C09D201/04 ,  C08G65/336 ,  C08G65/00 ,  C08G65/329 ,  C07F7/18 ,  C09D171/00 ,  B32B33/00 ,  C08F259/08 ,  C09D201/10

CPC classification number: C09D201/04 ,  B32B33/00 ,  C07F7/1804 ,  C08F259/08 ,  C08G65/007 ,  C08G65/329 ,  C08G65/336 ,  C09D171/00 ,  C09D201/10 ,  B32B2307/7265 ,  B32B2307/746

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1-Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.

公开(公告)号：US11504740B2

公开(公告)日：2022-11-22

申请号：US16431202

申请日：2019-06-04

Applicant: AGC Inc.

Inventor： Yukiko Shiota ,  Hiroyuki Hara ,  Akira Isobe ,  Reika Fukuda

IPC: B05D5/08 ,  C09D127/14 ,  C09D133/10 ,  C08L27/12 ,  C09D201/04 ,  C09D133/04 ,  C09D5/00 ,  C08L71/00 ,  C09K3/18 ,  D06M15/256 ,  C09D123/28 ,  C09D171/00 ,  D06M15/277 ,  D06M15/53

Abstract: To provide a water/oil repellent article which presents little burden on the environment, while being excellent in water/oil repellency, washing durability of the water repellency and friction durability of the water repellency; a method for producing such a water/oil repellent article; and a water/oil repellent composition and a water/oil repellent kit to be used for producing such a water/oil repellent article. A water/oil repellent article that comprises a substrate and, as adhered to the surface of the substrate, a fluorinated polymer having structural units based on monomer (a) having a C1-6 perfluoroalkyl group, and a specific fluorinated ether compound; a method for producing the water/oil repellent article, which comprises letting the fluorinated polymer and fluorinated ether compound be adhered to the substrate; a water/oil repellent composition which comprises the fluorinated polymer and fluorinated ether compound; and a water/oil repellent kit which comprises a first container accommodating a first liquid containing the fluorinated polymer and a second container accommodating a second liquid containing the fluorinated ether compound.

公开(公告)号：US10324234B2

公开(公告)日：2019-06-18

申请号：US14878054

申请日：2015-10-08

Applicant: AGC Inc.

Inventor： Kenji Ishizeki ,  Akira Isobe ,  Yuki Hatanaka ,  Yohei Kawai ,  Takashige Yoneda ,  Keisuke Abe

IPC: G02B1/111 ,  C09D127/24 ,  C09D5/00 ,  C01B33/18 ,  C03C17/00 ,  C03C17/25 ,  G02B1/18 ,  C09D7/40 ,  G02B27/00 ,  B01J13/18

Abstract: The present invention provides a substrate with an antireflection layer not only which is excellent in the antireflection properties but also which has high water repellency and oil repellency and favorable oil and fat stain removability, and a display device provided with a substrate with an antireflection layer.A substrate with an antireflection layer, which comprises an antireflection layer on at least one surface of the substrate, wherein the antireflection layer contains a silica porous film having fluorinated organic groups, and the surface of the antireflection layer on the opposite side from the substrate has an element number ratio F/Si of at least 1 as obtained from the peak height of F1s and the peak height of Si2p in surface analysis by scanning X-ray photoelectron spectroscopy (ESCA) and has an arithmetic mean roughness (Sa) of at most 3.0 nm.