公开(公告)号：US10677379B2

公开(公告)日：2020-06-09

申请号：US15722625

申请日：2017-10-02

Applicant: AGC Inc.

Inventor： Eiichi Nishi ,  Tomoya Hosoda ,  Toru Sasaki

IPC: B32B7/10 ,  F16L11/12 ,  B32B27/30 ,  B32B1/08 ,  B32B27/08 ,  B32B27/32 ,  B32B27/34 ,  C08F214/26

Abstract: To provide a laminate which is formed from resins and is excellent in heat resistance and excellent in flexibility and mechanical properties under high-temperature conditions and which undergoes no separation of layers even when contacted with oil such as engine oil for a long period of time. The laminate comprises a first layer containing a fluorinated copolymer and a second layer containing a polyamide directly laminated on the first layer, wherein the fluorinated copolymer has units based on tetrafluoroethylene, units based on ethylene, units based on a copolymerizable another monomer not having a carbonyl group, and carbonyl group-containing groups, wherein the amounts of the respective units are in specific ranges, and the tensile elongation at 200° C. of the fluorinated copolymer is at least 200%, and the melting point of the polyamide and the flexural elastic modulus at 23° C. of the second layer are in specific ranges.

公开(公告)号：US10507631B2

公开(公告)日：2019-12-17

申请号：US16152637

申请日：2018-10-05

Applicant: AGC Inc.

Inventor： Tatsuya Terada ,  Toru Sasaki

IPC: B32B27/08 ,  B32B7/02 ,  B32B15/04 ,  B32B15/082 ,  B32B27/30 ,  H05K1/03 ,  B32B15/08 ,  B32B37/18 ,  H05K3/46

Abstract: To provide a laminate having a fluororesin layer and a thermoplastic resin layer laminated with a good adhesive strength.A method for producing a laminate, comprising carrying out heat lamination of a fluororesin film containing the following fluororesin (A) and a thermoplastic resin film containing a thermoplastic resin (B) having a melting point higher by at least 5° C. than the melting point of the fluororesin (A), at a temperature of at least a melting point of the fluororesin (A) and lower than a melting point of the thermoplastic resin (B). The fluororesin (A) is a fluororesin having at least one functional group selected from the group consisting of a carbonyl group-containing group, a hydroxy group, an epoxy group and an isocyanate group, and having a melt flow rate of from 0.5 to 30 g/10 min at 372° C. under a load of 49N.

公开(公告)号：US20190030870A1

公开(公告)日：2019-01-31

申请号：US16152637

申请日：2018-10-05

Applicant: AGC Inc.

Inventor： Tatsuya Terada ,  Toru Sasaki

IPC: B32B27/08 ,  B32B15/08 ,  B32B37/18 ,  H05K3/46 ,  H05K1/03

Abstract: To provide a laminate having a fluororesin layer and a thermoplastic resin layer laminated with a good adhesive strength.A method for producing a laminate, comprising carrying out heat lamination of a fluororesin film containing the following fluororesin (A) and a thermoplastic resin film containing a thermoplastic resin (B) having a melting point higher by at least 5° C. than the melting point of the fluororesin (A), at a temperature of at least a melting point of the fluororesin (A) and lower than a melting point of the thermoplastic resin (B). The fluororesin (A) is a fluororesin having at least one functional group selected from the group consisting of a carbonyl group-containing group, a hydroxy group, an epoxy group and an isocyanate group, and having a melt flow rate of from 0.5 to 30 g/10 min at 372° C. under a load of 49N.

公开(公告)号：US11041053B2

公开(公告)日：2021-06-22

申请号：US16709049

申请日：2019-12-10

Applicant: AGC Inc.

Inventor： Tomoya Hosoda ,  Eiichi Nishi ,  Toru Sasaki ,  Nobutaka Kidera

IPC: C08J3/12 ,  B32B15/08 ,  B32B27/28 ,  B32B27/30 ,  C08J5/10 ,  B32B27/38 ,  B32B15/20 ,  B32B15/18 ,  B32B9/00 ,  C08L79/08 ,  B32B9/04 ,  C08L101/00 ,  B32B27/32 ,  B32B27/18 ,  B32B27/08 ,  C08L63/00 ,  H05K1/03 ,  B32B5/16 ,  B32B7/12 ,  C08J5/24 ,  H05K3/00 ,  H05K3/06 ,  C08F214/26

Abstract: A resin powder having a high bulk density and an average particle size of at most 50 μm from resin particles containing a fluorocopolymer as the main component and having a melting point of 260 to 320° C., where the fluorocopolymer contains a unit containing a carbonyl group-containing group, a unit based on tetrafluoroethylene, and a unit based on a perfluoro(alkyl vinyl ether) or a unit based on hexafluoropropylene. A method of producing the resin powder by subjecting resin particles (A) having an average particle size of at least 100 μm to mechanical pulverization treatment. The resin particles (A) is made of a material (X) having a fluorocopolymer (X1) as the main component, which has a unit (1) based on a monomer containing at least one functional group selected from a carbonyl group-containing group, a hydroxy group, an epoxy group and an isocyanate group, and a unit (2) based on tetrafluoroethylene.

公开(公告)号：US10271428B2

公开(公告)日：2019-04-23

申请号：US15926014

申请日：2018-03-20

Applicant: AGC Inc.

Inventor： Tomoya Hosoda ,  Toru Sasaki ,  Nobutaka Kidera ,  Tatsuya Terada

IPC: H01K3/10 ,  H05K1/03 ,  H05K1/11 ,  H05K3/42 ,  H05K3/46 ,  H05K3/00 ,  H05K3/38

Abstract: To produce a wiring substrate having excellent electrical characteristics with conduction failure in a hole formed in a layer made of a fluororesin material sufficiently suppressed without conducting an etching treatment using metal sodium. A process for producing a wiring substrate, which comprises forming a hole in a laminate comprising a first conductor layer, a layer (A) which is made of a fluororesin material containing a melt-moldable fluororesin having specific functional groups and a reinforcing fiber substrate and which has a dielectric constant from 2.0 to 3.5, a second conductor layer, an adhesive layer and a layer (B) made of a cured product of a thermosetting resin laminated in this order, applying, to an inner wall surface of the hole, either one or both of a treatment with a permanganic acid solution and a plasma treatment without conducting an etching treatment using metal sodium, and then forming a plating layer.

公开(公告)号：US11104107B2

公开(公告)日：2021-08-31

申请号：US16571888

申请日：2019-09-16

Applicant: AGC Inc.

Inventor： Shigeru Aida ,  Toru Sasaki

IPC: B32B27/08 ,  B32B27/28 ,  B32B27/32 ,  B32B27/30 ,  C08F214/26

Abstract: To provide a fluororesin laminate in which a layer of a fluorinated copolymer and a layer of a propylene polymer excellent in heat resistance are strongly attached.
A laminate comprising a layer which contains a fluorinated copolymer having an adhesive functional group and having monomer unit based on tetrafluoroethylene and monomer units based on ethylene, and a layer which contains a propylene polymer having an adhesive functional group.

公开(公告)号：US10729018B2

公开(公告)日：2020-07-28

申请号：US16125265

申请日：2018-09-07

Applicant: AGC Inc.

Inventor： Toru Sasaki ,  Wataru Kasai

IPC: C23F1/00 ,  H05K3/46 ,  B32B27/30 ,  B29C65/00 ,  H05K1/03 ,  B32B37/00 ,  B29C65/18 ,  B29C65/48 ,  B29C65/50 ,  B29C65/78 ,  H05K3/06

Abstract: To stably produce a laminate wherein heat resistant resin layers are laminated on both surfaces of a fluorinated resin layer, by thermal lamination.A process for producing a laminate, which comprises a preliminary heating step of heating, while conveying by a metal roll 33 for heating and a metal roll 32 for thermal lamination without pressing in the thickness direction, a temporary laminate wherein heat resistant resin films 2 and 2 are laminated on both surfaces of a fluorinated resin film 1 containing a melt-moldable fluorinated resin (A) having at least one type of functional groups selected from the group consisting of a carbonyl group-containing group, a hydroxyl group, an epoxy group and an isocyanate group and after the preliminary heating step, a thermal lamination step of pressing the temporary laminate in the thickness direction, while heating it by metal rolls 31 and 32 for thermal lamination at a thermal lamination temperature of at least the melting point of the fluorinated resin (A) ant at most 420° C., for bonding.

公开(公告)号：US10716203B2

公开(公告)日：2020-07-14

申请号：US15140912

申请日：2016-04-28

Applicant: AGC Inc.

Inventor： Tomoya Hosoda ,  Eiichi Nishi ,  Toru Sasaki ,  Yasuhiko Matsuoka ,  Wataru Kasai

IPC: H05K1/02 ,  B32B15/08 ,  C09J7/30 ,  C09J127/18 ,  B32B7/12 ,  C09J7/22 ,  H01P11/00 ,  H05K3/38 ,  B32B27/28 ,  C09J179/08 ,  H01P3/08 ,  H05K1/03 ,  H05K3/06 ,  H05K3/22 ,  H05K3/46

Abstract: To provide an adhesive film comprising a polyimide film and a fluorinated resin layer directly laminated, in which blisters (foaming) in an atmosphere corresponding to reflow soldering at high temperature are suppressed, and a flexible metal laminate.An adhesive film having a fluorinated resin layer containing a fluorinated copolymer (A) directly laminated on one side or both sides of a polyimide film, wherein the fluorinated copolymer (A) has a melting point of at least 280° C. and at most 320° C., is melt-moldable, and has at least one type of functional groups selected from the group consisting of a carbonyl group-containing group, a hydroxy group, an epoxy group and an isocyanate group, and the fluorinated resin layer has a thickness of from 1 to 20 μm.

公开(公告)号：US10304583B2

公开(公告)日：2019-05-28

申请号：US14944657

申请日：2015-11-18

Applicant: AGC Inc.

Inventor： Tomoya Hosoda ,  Yasuhiko Matsuoka ,  Toru Sasaki ,  Wataru Kasai

IPC: H01B3/30 ,  B32B27/08 ,  H01B3/44 ,  C08F214/26 ,  C08J5/12 ,  B32B27/28 ,  B29C65/02 ,  B29C65/00 ,  H01B13/08 ,  B32B27/18 ,  B32B27/20 ,  B32B27/30 ,  B32B27/32 ,  B29K627/18 ,  B29K679/00 ,  B29L9/00 ,  B29L31/34 ,  B29C63/00 ,  B29C63/02

Abstract: To provide an insulating tape for covering, in which a polyimide film and a fluorinated resin film are laminated with excellent adhesion, and a method for producing a structure, which comprises covering a conductor with such an insulating tape for covering, followed by thermal treatment. The insulating tape for covering, comprises a polyimide film and a fluorinated resin film directly laminated on one or both surfaces of the polyimide film, wherein the fluorinated resin film contains a fluorinated copolymer (A) which has a melting point of from 220 to 320° C. and can be melt-molded and which has at least one type of functional groups selected from the group consisting of carbonyl group-containing groups, hydroxy groups, epoxy groups and isocyanate groups.

公开(公告)号：US20180371228A1

公开(公告)日：2018-12-27

申请号：US16047548

申请日：2018-07-27

Applicant: AGC Inc.

Inventor： Satoko Yasuda ,  Hiroki Nagai ,  Eiichi Nishi ,  Toru Sasaki

IPC: C08L27/18 ,  H01B7/02 ,  H01B3/44 ,  C08J3/20

Abstract: To provide a fluororesin composition which is excellent in flexibility and oil resistance, is less susceptible to heat discoloration and is excellent in moldability. The fluororesin composition is made of a melt-kneaded product comprising a fluorinated elastomer having a storage shear modulus G′ of at least 100 and a melt-moldable fluororesin having a melting point of at least 150° C., wherein the fluorinated elastomer is dispersed in the fluororesin, the content of the fluorinated elastomer is from 10 to 65 mass % to the total of the fluorinated elastomer and the fluororesin, and the total amount of the fluorinated elastomer and the fluororesin is at least 90 mass % to the fluororesin composition, and the storage modulus E′ of the fluororesin composition at a temperature higher by 25° C. than the melting point of the fluororesin is at most 250 kPa.