Abstract:
NOVEL FLUOROPERHALODIAZOLEFINE ARE PREPARED BY REACTING A FLUOROPERHALOALKYLIDENE IMINE WITH A FLUOROPERHALOAZAOLEFIN IN AN APROTIC, POLAR LIQUID REACTION MEDIUM IN THE PRESENCE OF AN IONIZABLE FLUORIDE SALT. FOR EXAMPLE, PERFLUORO-2,4,4,6-TETRAMETHYL-3,5-DIAZA -25-HEPTADIENE IS PREPARED BY REACTING HEXAFLUOROISOPROYLIDENE IMINE WITH PERFLUORO-2,4-DIMETHYL-3-AZA-2-PENTENE IN ACETONITRILE IN THE PRESENCE OF POTASSIUM FLUORIDE. THE FLUOROPERHALODIAZAOLEFINS ARE USEFUL AS LIQUID DIELECTRICS AND AS INTERMEDIATES IN THE PREPARATION OF P OTHER FLUORINATED ORGANIC COMPOUNDS.
WHEREIN R IS AN ALKYLENE GROUP OF 1 TO 12 CARBON ATOMS, AN ALKYLENE GROUP OF 2 TO 12 CARBON ATOMS, OR A PHENYLENE GROUP, Q IS AN INTEGER FROM 1 TO 6, AND RF IS A RADICAL HAVING THE FORMULA
Y(CF2)5(CH2)T-
WHEREIN S IS AN INTEGER FROM 1 TO 16, T IS AN INTEGER NOT GREATER THAN S FROM 0 TO 8, WITH THE SUM OF S PLUS T BEING FROM 1 TO 20, AND Y IS SELECTED FROM THE GROUP CONSISTING OF F3C- AND RADICALS HAVING THE FORMULA
R1-CF(-R2)-CF(-O(-))-CF(-R1)-R2 NOVEL FLUOROCARBON AMIDES USEFUL AS OIL- AND WATERREPELLENT AGENTS HAVE THE FORMULA
WHEREIN R1 AND R2 ARE FLUORINE OR PERFLUOROALKYL GROUPS HAVING FROM 1 TO 9 CARBON ATOMS, WITH NOT MORE THAN THREE OF THE R1 AND R2 GROUPS BEING PERFLUOROALKYL GROUPS.
Abstract:
FLUOROPERHALOAZAOLEFINS ARE PREPARED BY REACTING A FLUOROPERHALOALKYL ISOCYANATE WITH A FLUOROPERHALOALKOXIIDE. FOR EXAMPLE, PERFLUORO-2,4-DIMETHYL-3-AZA-2-PENTENE IS PREPARED BY REACTING HEXAFLUOROISOPROPYL ISOCYANATE WITH POTASSIUM HEPTAFLUOROISOPROPOXIDE. THE FLUOROPERHALOAZAOLEFINS ARE USEFUL AS LIQUID DIELECTRICS AND AS INTERMEDIATES IN THE PREPARATION OF OTHER FLUORINATED ORGANIC COMPOUNDS.
Abstract:
Perfluoro-tertiary-alkanols of the formula
WHEREIN R is either fluorine or trifluoromethyl are outstanding fumigants against common penetrating pests such as those infecting soil, plants, grain, flour and carpets.
Abstract:
The soil and stain repellency of extruded filaments of a synthetic resin can be improved by incorporating in the resin a small amount, about 1 percent, of an amphipathic compound having from one to four fluoroalkyl groups pendent from an organic radical. The repellency is provided by the fluoroalkyl groups, which tend to be concentrated at the surface of the fiber.
Abstract:
Tertiary perfluoroalkyl cyanates are prepared by reacting the corresponding tertiary perfluoroalkoxide with cyanogen chloride or cyanogen bromide. The cyanates are novel compounds useful as intermediates in the preparation of low surface energy compounds useful as repellent coatings.
Abstract:
Novel fluorocarbon amides useful as oil- and water-repellant agents have the formula
WHEREIN R is an alkyl diradical of one to 12 carbon atoms, an alkylene diradical of two to 12 carbon atoms, or a phenyl diradical; q is an integer from 1 to 6; and Rf is a radical having the formula