公开(公告)号：US20220098343A1

公开(公告)日：2022-03-31

申请号：US17414444

申请日：2019-12-16

Applicant: Arkema France ,  UNIVERSITE DE BORDEAUX ,  INSTITUT POLYTECHNIQUE DE BORDEAUX ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

Inventor： Georges HADZIIOANNOU ,  Eric CLOUTET ,  Cyril BROCHON ,  Konstantinos KALLITSIS ,  Fabrice DOMINGUES DOS SANTOS ,  Thibaut SOULESTIN

IPC: C08F214/22 ,  C08F8/06 ,  C08J5/18 ,  C08L27/16

Abstract: A copolymer including units derived from fluoro monomers of formula (I): CX1X2═CX3X4  (I) in which each of the X1, X2, X3 and X4 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated, the H and/or F atoms of the fluoro monomers being partially replaced with photoactive groups of formula —Y—Ar—R in the copolymer; Y representing an oxygen atom or an NH group or a sulfur atom, Ar representing an aryl group, preferably a phenyl group, and R being a monodentate or bidentate group including from 1 to 30 carbon atoms. The fluoro monomers of formula (I) of the copolymer include vinylidene fluoride and trifluoroethylene. Also, a process for preparing this copolymer, a composition including this copolymer, and a film obtained from the copolymer.

公开(公告)号：US20200157365A1

公开(公告)日：2020-05-21

申请号：US16633297

申请日：2018-07-17

Applicant: ARKEMA FRANCE ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  Universite De Montpellier ,  ECOLE NATIONALE SUPERIEURE DE CHIMIE DE MONTPELLIER

Inventor： Thierry LANNUZEL ,  Fabrice DOMINGUES DOS SANTOS ,  Thibaut SOULESTIN ,  Vincent LADMIRAL ,  Bruno AMEDURI

IPC: C09D11/106 ,  C08L27/16 ,  C08K5/06 ,  C08F214/24 ,  C08K5/36 ,  C08L83/08 ,  C08K5/17 ,  C08L47/00 ,  C08K5/00 ,  C08K5/10 ,  C08K5/07 ,  C08K5/521 ,  C09D11/101

Abstract: A process for preparing a crosslinked fluoropolymer film, including the successive steps of: (1) formulating an ink containing: (a) the product of the reaction of triethylamine with at least one fluorinated copolymer obtained by radical copolymerization of monomers including: (i) vinylidene fluoride (VDF), (ii) trifluoroethylene (TrFE), (iii) at least one chlorinated monomer of formula —CXCl═CX1X2 where X, X1 and X2 independently denote H, F or CF3, wherein at most one of X, X1 and X2 denotes CF3; (b) at least one crosslinking agent; (c) at least one photoinitiator; and (d) at least one organic solvent; (2) applying said ink in film form to a substrate; and (3) UV-irradiating said film. Also, the film capable of being obtained according to this process, and also to the uses thereof, in particular in the manufacture of (opto)electronic devices and more particularly in the manufacture of a gate dielectric layer in a field-effect transistor.

公开(公告)号：US20240110054A1

公开(公告)日：2024-04-04

申请号：US18267757

申请日：2021-12-15

Applicant: ARKEMA FRANCE

Inventor： Fabrice DOMINGUES DOS SANTOS ,  Thibaut SOULESTIN ,  Gilles FRANCOIS ,  Pierre GERARD

IPC: C08L33/12 ,  B06B1/06 ,  H10N30/00 ,  H10N30/098 ,  H10N30/857

CPC classification number: C08L33/12 ,  B06B1/0688 ,  H10N30/098 ,  H10N30/1061 ,  H10N30/857 ,  C08L2203/20

Abstract: A composite article including at least one electronic system, integrated onto the surface or in the volume of a thermoplastic matrix. The electronic system includes at least one piezoelectric transducer and means for transmitting an electrical signal. The piezoelectric transducer includes a piezoelectric polymer essentially consisting of, or consisting of, repeating units derived from vinylidene fluoride (VDF) and vinylidene trifluoride (TrFE), the molar proportion of the unit derived from TrFE being from 15% to 50% relative to the total number of moles of the units derived from VDF and TrFE. Also, the use of the electronic system and to the use of the article.

公开(公告)号：US20220411550A1

公开(公告)日：2022-12-29

申请号：US17414721

申请日：2019-12-16

Applicant: ARKEMA FRANCE ,  UNIVERSITE DE BORDEAUX ,  INSTITUT POLYTECHNIQUE DE BORDEAUX ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

Inventor： Fabrice DOMINGUES DOS SANTOS ,  Thibaut SOULESTIN ,  Georges HADZIIOANNOU ,  Eric CLOUTET ,  Cyril BROCHON ,  Konstantinos KALLITSIS

IPC: C08F214/22 ,  C08F214/24 ,  C08F220/18 ,  G03F7/004 ,  G03F7/033 ,  G03F7/30

Abstract: A copolymer including fluorinated units of formula (I): —CX1X2—CX3X4—  (I) in which each of the X1, X2, X3 and X4 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated; and fluorinated units of formula (II): —CX5X6—CX7Z—  (II) in which each of the X5, X6 and X7 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated, and in which Z is a photoactive group of formula —Y—Ar—R, Y representing an oxygen atom or an NH group or a sulfur atom, Ar representing an aryl group, and R being a monodentate or bidentate group including from 1 to 30 carbon atoms. Also, a process for preparing this copolymer, a composition including this copolymer, and a film obtained from this copolymer.

公开(公告)号：US20180312618A1

公开(公告)日：2018-11-01

申请号：US15769275

申请日：2016-10-18

Applicant: Arkema France ,  Centre National de la Recherche Scientifique ,  Universite de Montpellier ,  Ecole Nationale Superieure de Chimie de Montpellier

Inventor： Thierry T. Lannuzel ,  Fabrice DOMINGUES DOS SANTOS ,  Thibaut SOULESTIN ,  Vincent LADMIRAL ,  Bruno AMEDURI

IPC: C08F214/22 ,  C09D127/24 ,  C09D127/16 ,  C08F8/22 ,  C08F8/40 ,  C09D127/22 ,  C08F8/30

CPC classification number: C08F214/227 ,  C08F8/22 ,  C08F8/30 ,  C08F8/40 ,  C08F214/22 ,  C08F216/1408 ,  C08F2800/10 ,  C09D127/16 ,  C09D127/22 ,  C09D127/24 ,  C08F214/247

Abstract: “The invention relates to a fluorinated copolymers which are particularly based on vinylidene fluoride (VDF) or trifluoroethylene (TrFE) and particularly functionalized by functional and/or functionizable vinyl ethers. The invention also relates to methods for producing said copolymers, and to the applications thereof.”

公开(公告)号：US20200235283A1

公开(公告)日：2020-07-23

申请号：US16637311

申请日：2018-07-19

Applicant: ARKEMA FRANCE

Inventor： Fabrice DOMINGUES DOS SANTOS ,  Seung Tae CHOI ,  Hung Viet TRAN

IPC: H01L41/193 ,  C08L27/16 ,  C08J5/18 ,  H01L41/09 ,  H01L41/317

Abstract: The present invention relates to compositions obtained by mixing specific electroactive fluoro-terpolymers and specific electroactive fluorinated copolymers. The invention also concerns liquid formulations (inks) that can be used through conventional processing technologies for printed electronics and microelectronics in a safe environment, based on these compositions. Another aspect of this invention are the films manufactured using these formulations, and the devices comprising at least one layer of these films.

公开(公告)号：US20200157334A1

公开(公告)日：2020-05-21

申请号：US16631882

申请日：2018-07-16

Applicant: Arkema France ,  UNIVERSITE DE BORDEAUX ,  INSTITUT POLYTECHNIQUE DE BORDEAUX ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

Inventor： Georges HADZIIOANNOU ,  Eric CLOUTET ,  Cyril BROCHON ,  Damien THUAU ,  Konstantinos KALLITSIS ,  Fabrice DOMINGUES DOS SANTOS ,  Thibaut SOULESTIN

IPC: C08L27/16 ,  C08F214/16 ,  C08F214/04 ,  C08F8/30 ,  C08F214/24 ,  C08F214/22

Abstract: The invention relates to a copolymer comprising units derived from monomers of vinylidene fluoride and/or trifluoroethylene, as well as fluorinated monomers X comprising a double bond and a leaving group selected from among chlorine, bromine and iodine atoms, the leaving groups being partially replaced by azide groups in the copolymer.

公开(公告)号：US20160141534A1

公开(公告)日：2016-05-19

申请号：US14904331

申请日：2014-07-10

Applicant: ARKEMA FRANCE ,  UNIVERSITY DE BORDEAUX ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  INSTITUT POLYTECHNIQUE DE BORDEAUX

Inventor： Christophe NAVARRO ,  Guillaume FLEURY ,  Georges HADZIIOANNOU ,  Carine LACROIX ,  Eleni PAVLOPOULOU ,  Fabrice DOMINGUES DOS SANTOS

IPC: H01L51/42 ,  H01L51/00

CPC classification number: H01L51/42 ,  H01L51/0003 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/4253 ,  Y02E10/549 ,  Y02P70/521 ,  C09D127/16 ,  C08L65/02

Abstract: The present invention relates to the field of organic electronics for photovoltaic energy, i.e. conversion of light energy into electricity. More particularly, this invention relates to a method of fabrication of an active layer capable of emitting an electric current under light irradiation combining a ferroelectric polymer material and a semiconducting polymer for converting light energy into electricity.

Abstract translation: 本发明涉及用于光伏能量的有机电子学领域，即将光能转换成电能。 更具体地说，本发明涉及一种制造有源层的方法，该有源层能够在结合铁电聚合物材料和用于将光能转换成电的半导体聚合物的光照射下发射电流。

公开(公告)号：US20230022870A1

公开(公告)日：2023-01-26

申请号：US17784438

申请日：2020-12-11

Applicant: Arkema France ,  UNIVERSITE DE BORDEAUX ,  INSTITUT POLYTECHNIQUE DE BORDEAUX ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

Inventor： Fabrice DOMINGUES DOS SANTOS ,  Thibaut SOULESTIN ,  Florian LE GOUPIL ,  Konstantinos KALLITSIS ,  Georges HADZIIOANNOU

IPC: C09K5/14

Abstract: A polymer including VDF-based units having an electrocaloric effect under the effect of a variable electric field. The polymer includes 0.1 to 10.0 mol % double bonds, which are substantially non-conjugated. Also, a corresponding composition including the polymer, a corresponding film including the polymer, and to various uses of the polymer.

公开(公告)号：US20220073663A1

公开(公告)日：2022-03-10

申请号：US17414459

申请日：2019-12-16

Applicant: ARKEMA FRANCE ,  UNIVERSITE DE BORDEAUX ,  INSTITUT POLYTECHNIQUE DE BORDEAUX ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

Inventor： Fabrice DOMINGUES DOS SANTOS ,  Thibaut SOULESTIN ,  Georges HADZIIOANNOU ,  Eric CLOUTET ,  Cyril BROCHON ,  Konstantinos KALLITSIS

IPC: C08F214/22 ,  C09D127/16 ,  C09D5/24 ,  H01L51/00 ,  C09D11/106 ,  C09D11/52 ,  H01L41/193

Abstract: A copolymer including fluorinated units of formula (I): —CX1X2—CX3X4—  (I) in which each of the X1, X2, X3 and X4 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated; and units of formula (III): —CXAXB—CXCZ—  (III) in which each of the XA, XB and XC is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated, and Z being a polarizable group of formula —Y—Ar—R; Y representing an O atom or an S atom or an NH group, Ar representing an aryl group, and R being a monodentate or bidentate group including from 1 to 30 carbon atoms; and the copolymer having a heat of fusion of greater than or equal to 5 J/g. Also a process, a composition, an ink and a film.