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公开(公告)号：US10774208B2
公开(公告)日：2020-09-15
申请号：US15557147
申请日：2016-03-10
Applicant: Arkema Inc.
Inventor： Saeid Zerafati , Ramin Amin-Sanayei , James J. Henry , Gregory S. O'Brien
IPC: C08L27/12 , C08L83/04 , C08L27/16 , C09D127/16 , C08F283/12 , C08L51/08
Abstract: The invention relates to blends containing polymers of vinylidene fluoride, having low ductile-brittle transition temperatures and having excellent low temperature impact properties while maintaining the positive aspects of unmodified vinylidene fluoride-containing polymers. The blends of this invention are produced by adding a core-shell impact modifier (CSIM) comprised of a polysiloxane core and a shell compatible with vinylidene fluoride-containing polymer. The blends are further characterized by the presence of a heterogeneous copolymer composition comprised of two or more distinct phases and/or at least one flame and smoke suppressant. The preparation of these new blends can be done by conventional thermoplastic compounding techniques such as twin screw compounding; alternatively, the CSIM can be introduced earlier, such as in the latex. The unique properties of the new blends make them useful in end-use applications where those properties provide performance advantages, such as in wires & cables and in oil and gas applications.
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公开(公告)号：US20190299190A1
公开(公告)日：2019-10-03
申请号：US16444214
申请日：2019-06-18
Applicant: ARKEMA INC.
Inventor： Sean M. Stabler , Azaz A. Vahora , Denis Kato De Almeida , Florence Mehlmann , Ramin Amin-Sanayei
Abstract: The invention relates to the use of a high performance thermoplastic polymer binder material for immobilizing adsorptive materials, such as activated carbon, in gas storage devices. The use of these binders, especially polyamide binders, polytetrafluoroethylene binders, or polyvinylidene fluoride binders such as Kyblock® resin, provides for high sorbent packing density, low fouling solid structure that maximizes the volume of gas to the volume of the storage space.
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公开(公告)号：US09839881B2
公开(公告)日：2017-12-12
申请号：US14410644
申请日：2013-10-01
Applicant: Arkema Inc.
Inventor： Sean M. Stabler , Thomas F. Roland , David A. Seiler , Ramin Amin-Sanayei , Walter Kosar
CPC classification number: B01D69/12 , B01D39/1623 , B01D39/163 , B01D39/2048 , B01D39/2062 , B01D41/04 , B01D53/228 , B01D61/246 , B01D69/06 , B01D71/021 , B01D71/34 , B01D2239/086 , B01D2239/1216 , B01D2325/12 , C02F1/44
Abstract: The invention relates to a porous separation article having a fluoropolymer or polyamide binder interconnecting one or more types of interactive powdery materials or fibers. The interconnectivity is such that the binder connects the powdery materials or fibers in discrete spots rather than as a complete coating, allowing the materials or fibers to be in direct contact with, and interact with a fluid. The resulting article is a formed multicomponent, interconnected web, with porosity. The separation article is useful in water purification, as well as in the separation of dissolved or suspended materials in both aqueous and non-aqueous systems in industrial uses. The separation article can function at ambient temperature, as well as at elevated temperatures.
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公开(公告)号：US20160086742A1
公开(公告)日：2016-03-24
申请号：US14953757
申请日：2015-11-30
Applicant: Arkema Inc.
Inventor： Ramin Amin-Sanayei , Ravi R. Gupta
IPC: H01G11/48 , H01M2/16 , H01M4/62 , H01M10/052 , H01M4/136 , H01M4/86 , H01M8/10 , H01G11/52 , H01M4/131
CPC classification number: H01G11/48 , H01G11/52 , H01M2/1673 , H01M4/0404 , H01M4/131 , H01M4/136 , H01M4/139 , H01M4/1391 , H01M4/1393 , H01M4/1397 , H01M4/621 , H01M4/623 , H01M4/8668 , H01M8/1004 , H01M10/052 , H01M10/0525 , H01M2008/1095 , Y02E60/122 , Y02E60/13 , Y02P70/54
Abstract: The invention relates to an aqueous fluoropolymer, and preferably polyvinylidene fluoride (PVDF), composition for manufacturing electrodes for use in non-aqueous-type electrochemical devices, such as batteries and electric double layer capacitors. The composition contains aqueous PVDF binder, and one or more powdery electrode-forming materials. In one embodiment, the composition is free of fluorinated surfactant In another embodiment, one or more fugitive adhesion promoters are added. The electrode formed from the composition of the invention exhibits interconnectivity and irreversibility that is achieved from the use of aqueous PVDF binder.
Abstract translation: 本发明涉及含氟聚合物，优选聚偏二氟乙烯（PVDF），用于制造用于非水型电化学装置的电极组合物，例如电池和双电层电容器。 该组合物含有PVDF粘合剂水溶液和一种或多种粉状电极形成材料。 在一个实施方案中，组合物不含氟化表面活性剂。在另一个实施方案中，加入一种或多种短效粘合促进剂。 由本发明组合物形成的电极表现出相互连接性和不可逆性，其通过使用PVDF粘合剂水溶液实现。
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公开(公告)号：US09239051B1
公开(公告)日：2016-01-19
申请号：US14929710
申请日：2015-11-02
Applicant: Arkema Inc.
Inventor： Ramin Amin-Sanayei , Scott R. Gaboury
CPC classification number: H01M10/0525 , C08K5/1565 , C09D127/16 , F04C15/0096 , H01G11/26 , H01G11/30 , H01G11/38 , H01G11/48 , H01G11/52 , H01M2/1686 , H01M4/0404 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/62 , H01M4/623 , Y02E60/13 , Y10T428/3154
Abstract: This invention relates to a waterborne fluoropolymer composition useful for the fabrication of Li-Ion-Battery (LIB) electrodes. The fluoropolymer composition contains an organic carbonate compound, which is more environmentally friendly than other fugitive adhesion promoters currently used in waterborne fluoropolymer binders. An especially useful organic carbonate compound is ethylene carbonate (EC) and vinylene carbonate (VC), which are solids at room temperature, and other carbonates which are liquid at room temperature such as propylene carbonate, methyl carbonate and ethyl carbonate. The composition of the invention is low cost, environmentally friendly, safer, and has enhanced performance compared to current compositions.
Abstract translation: 本发明涉及可用于制造锂离子电池（LIB）电极的水性氟聚合物组合物。 氟聚合物组合物含有有机碳酸酯化合物，其比目前在水性氟聚合物粘合剂中使用的其它短效粘合促进剂更环保。 特别有用的有机碳酸酯化合物是在室温下为固体的碳酸亚乙酯（EC）和碳酸亚乙烯酯（VC），以及其它在室温下为液体的碳酸酯，例如碳酸亚丙酯，碳酸甲酯和碳酸乙酯。 本发明的组合物低成本，环保，更安全，并且与现有组合物相比具有增强的性能。
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Patent Agency Ranking
公开(公告)号：US20150030906A1
公开(公告)日：2015-01-29
申请号：US14379540
申请日：2013-02-21
Applicant: Arkema Inc.
Inventor： Ramin Amin-Sanayei , Scott R. Gaboury
Abstract: The invention relates to a separator for non-aqueous-type electrochemical device that has been coated with an aqueous fluoropolymer coating. The fluoropolymer is preferably polyvinylidene fluoride (PVDF), and more preferably a copolymer of polyvinylidene fluoride. The fluoropolymer coating provides a porous coating on porous substrate separator used in non-aqueous-type electrochemical devices, such as batteries and electric double layer capacitors. The fluoropolymer coating improves the thermal resistance and mechanical integrity, and lowers the interfacial electrical impedance of the porous separator. The fluoropolymer composition optionally contains powdery particles that are held together on the separator by the fluoropolymer binder. In one embodiment, the starting fluoropolymer dispersion is free of fluorinated surfactant. In another embodiment, one or more fugitive adhesion promoters are added.
Abstract translation: 本发明涉及一种已经涂覆含氟聚合物水性涂料的非水型电化学装置用隔膜。 氟聚合物优选为聚偏氟乙烯（PVDF），更优选为聚偏二氟乙烯的共聚物。 氟聚合物涂层在用于非水型电化学装置（例如电池和双电层电容器）中的多孔基材分离器上提供多孔涂层。 含氟聚合物涂层改善了热阻和机械完整性，并降低了多孔隔板的界面电阻抗。 含氟聚合物组合物任选地含有通过氟聚合物粘合剂在隔膜上保持在一起的粉末状颗粒。 在一个实施方案中，起始含氟聚合物分散体不含氟化表面活性剂。 在另一个实施方案中，加入一种或多种短效粘合促进剂。
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公开(公告)号：US11133562B2
公开(公告)日：2021-09-28
申请号：US14410674
申请日：2013-11-01
Applicant: Arkema Inc.
Inventor： John Schmidhauser , Scott R. Gaboury , Ramin Amin-Sanayei , Christophe Roger , Wensheng He , Rosemary Heinze
IPC: H01M50/46 , H01G11/52 , H01M50/403 , H01M50/411 , H01M50/449 , H01M50/446
Abstract: The invention relates to integrated electrode separators (IES), and their use in lithium ion batteries as replacements for free standing separators. The IES results from coating an electrode with a fluoropolymer aqueous-based emulsion or suspension, and drying the coating to produce a tough, porous separator layer on the electrodes. The aqueous fluoropolymer coating may optionally contain dispersed inorganic particles and other additives to improve electrode performance such as higher ionic conduction or higher temperature use. The IES provides several advantages, including a thinner, more uniform separator layer, and the elimination of a separate battery component (separator membrane) for a simpler and cost-saving manufacturing process. The aqueous separator coating can be used in combination with a solvent cast electrode as well as an aqueous cast electrode either in two separate process steps, or in a one-step process.
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公开(公告)号：US10892490B2
公开(公告)日：2021-01-12
申请号：US15549736
申请日：2016-02-05
Applicant: Arkema Inc.
Inventor： Sean M. Stabler , Ramin Amin-Sanayei
IPC: H01M4/62 , H01M4/131 , H01M2/16 , H01M10/052 , H01J37/256
Abstract: The invention relates to a dry free-flowing composite of a sub-micron polymer binder particles and interactive materials, and articles formed therefrom. The polymer particles are formed from a dilute latex polymer and blended with interactive materials, then the blend is spray-dried, to form a dry blend in which less than 10% of all polymer particles are in an agglomerated form. The polymer is preferably a polyvinylidene fluoride, such as Kyblock® PVDF from Arkema. The dry blend will be used to form articles and coatings by many means, for example forming a three dimensional article by heat and pressure, it can be redispersed into an aqueous coating composition, or can be electro-coated onto a substrate.
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公开(公告)号：US10570231B2
公开(公告)日：2020-02-25
申请号：US15987049
申请日：2018-05-23
Applicant: Arkema Inc.
Inventor： Ramin Amin-Sanayei
IPC: C08F14/22 , C08F14/24 , C08F14/26 , C08F14/28 , C08F2/00 , C08F214/22 , C08F214/18 , H01M4/62
Abstract: The invention relates to novel linear, semi-crystalline fluoropolymers containing 0.5 to 25 mole percent of at least one vinyl ester monomer unit. At least 40 mole percent of the vinyl ester monomer units are present in the copolymer as single monomer units (not diads or triads or greater) between two fluoromonomer units. The invention also relates to a process for forming the fluoromonomers/vinyl ester copolymer. The fluoropolymer of the invention may be used in applications benefiting from a functional fluoropolymers including as a binder or coating in batteries, or for use in forming hydrophilic membranes and hollow fibers.
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公开(公告)号：US10434478B2
公开(公告)日：2019-10-08
申请号：US15837160
申请日：2017-12-11
Applicant: Arkema Inc.
Inventor： Sean M. Stabler , Thomas F. Roland , David A. Seiler , Ramin Amin-Sanayei , Walter P. Kosar
IPC: B01D69/12 , C02F1/44 , B01J20/20 , C02F1/28 , B01J20/28 , B01D67/00 , B01D69/14 , B01D71/02 , B01D71/34 , C02F1/00
Abstract: The invention relates to a porous separation article having a fluoropolymer, polyamide, PEEK, or PEKK binder interconnecting one or more types of interactive powdery materials or fibers. The interconnectivity is such that the binder connects the powdery materials or fibers in discrete spots rather than as a complete coating, allowing the materials or fibers to be in direct contact with, and interact with a fluid. The resulting article is a formed multicomponent, interconnected web, with porosity. The separation article is useful in water purification, as well as in the separation of dissolved or suspended materials in both aqueous and non-aqueous systems in industrial uses. The separation article can function at ambient temperature, as well as at elevated temperatures.
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