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    Alkyl ether carboxylic acid taurides
    4.
    发明授权
    Alkyl ether carboxylic acid taurides 失效
    烷基醚羧酸

    公开(公告)号：US5231224A

    公开(公告)日：1993-07-27

    申请号：US833999

    申请日：1992-02-11

    申请人： Thomas Gerdau ,  Alwin Reng ,  Walter Kunz

    发明人： Thomas Gerdau ,  Alwin Reng ,  Walter Kunz

    IPC分类号： C07C303/22 ,  A61K8/46 ,  A61Q5/02 ,  C07C303/32 ,  C07C309/15 ,  C11D1/18 ,  C11D1/28

    CPC分类号： A61Q5/02 ,  A61K8/466 ,  C07C309/15 ,  C11D1/28

    摘要： The invention relates to alkyl ether carboxylic acid taurides of the formulaR.sup.2 --(OC.sub.2 H.sub.4).sub.n --O--CH.sub.2 --CO--NR.sup.1 --C.sub.2 H.sub.4 --SO.sub.3 M,in which n is greater than 0, R.sup.1 =H or C.sub.1 -C.sub.4 alkyl, R.sup.2 =C.sub.5 -C.sub.22 alkyl and M=H, Na, K, Ca/2 or Mg/2.Processes for their preparation and their use as surface-active substances, especially as mild cleaning agents for cosmetic purposes, are also described.

    摘要翻译： 本发明涉及式R2-（OC2H4）nO-CH2-CO-NR1-C2H4-SO3M的烷基醚羧酸牛磺酸盐，其中n大于0，R1 = H或C1-C4烷基，R2 = C5- C22烷基，M = H，Na，K，Ca / 2或Mg / 2。 还描述了其制备方法及其作为表面活性物质的用途，特别是作为用于化妆品目的的温和清洁剂。

    N-p-propargyloxyphenethyl-thioacetic acid amides
    5.
    发明授权
    N-p-propargyloxyphenethyl-thioacetic acid amides 失效
    N-对 - 丙酰氧基苯乙基 - 硫代乙酰胺

    公开(公告)号：US07105545B2

    公开(公告)日：2006-09-12

    申请号：US10472577

    申请日：2002-04-02

    申请人： Walter Kunz ,  Clemens Lamberth ,  Fredrik Cederbaum ,  Martin Zeller

    发明人： Walter Kunz ,  Clemens Lamberth ,  Fredrik Cederbaum ,  Martin Zeller

    IPC分类号： A01N43/40 ,  A01N43/06 ,  A01N43/08 ,  A01N37/44 ,  A01N37/18

    CPC分类号： C07C327/44 ,  A01N37/36 ,  A01N43/08 ,  A01N43/10 ,  A01N43/12 ,  A01N43/30 ,  A01N43/32 ,  A01N43/40 ,  A01N43/54

    摘要： The invention relates to N-propargyloxy-phenethyl thioacetic acid amide derivatives of the general formula (I) including the optical isomers thereof and mixtures of such isomers, wherein R1 is hydrogen, alkyl, cycloalkyl or optionally substituted aryl, R2 and R3 are each independently hydrogen or alkyl, R4 is alkyl, alkenyl or alkynyl, R5, R6, R7 and R8 are each independently hydrogen or alkyl, R9 is hydrogen, optionally substituted alkyl, optionally substituted alkenyl or optionally substituted alkynyl, R10 is optionally substituted aryl or optionally substituted heteroaryl, and Z is hydroxy, optionally substituted aryloxy, optionally substituted alkoxy, optionally substituted alkynyloxy, optionally substituted arylthio, optionally substituted alkylthio, optionally substituted alkynylthio, optionally substituted alkylsulfinyl, optionally substituted alkenysulfinyl, optionally substituted alkynylsulfinyl, optionally substituted alkylsulfonyl, optionally substituted alkenylsulfonyl, optionally substituted alkynylsulfonyl or a group —O—CO—R11, —O—CO—O—R11 or —O—CO—CO—O—R11 wherein R11 is hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted aryl or optionally substituted heteroaryl. These compounds possess useful plant protecting properties and may advantageously be employed in agricultural practice for controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi

    摘要翻译： 本发明涉及通式（I）的N-炔丙氧基 - 苯乙基硫代乙酰胺衍生物，其包括其旋光异构体和这些异构体的混合物，其中R 1是氢，烷基，环烷基或任选取代的 芳基，R 2和R 3各自独立地是氢或烷基，R 4是烷基，烯基或炔基，R 5， R 6，R 7，R 8和R 8各自独立地为氢或烷基，R 9为 氢，任选取代的烷基，任选取代的烯基或任选取代的炔基，R 10是任选取代的芳基或任选取代的杂芳基，Z是羟基，任选取代的芳氧基，任选取代的烷氧基，任选取代的炔氧基，任选地 取代的芳硫基，任选取代的烷硫基，任选取代的炔硫基，任选取代的烷基亚磺酰基，任选取代的烯基亚磺酰基，任选的 取代的炔基亚磺酰基，任选取代的烷基磺酰基，任选取代的链烯基磺酰基，任选取代的炔基磺酰基或基团-O-CO-R 11，-O-CO-OR 11或-O- 其中R 11是氢，任选取代的烷基，任选取代的环烷基，任选取代的芳基或任选取代的杂芳基。 这些化合物具有有用的植物保护性质，并且可有利地用于农业实践中以控制或防止由植物病原微生物特别是真菌侵染植物

    Treatment of tobacco and tobacco smoke with chelating agents to remove Pb-210 and Po-210
    6.
    发明申请
    Treatment of tobacco and tobacco smoke with chelating agents to remove Pb-210 and Po-210 审中-公开
    用螯合剂处理烟草和烟草烟雾以去除Pb-210和Po-210

    公开(公告)号：US20050034737A1

    公开(公告)日：2005-02-17

    申请号：US10639130

    申请日：2003-08-13

    申请人： Charles Kunz ,  Walter Kunz

    发明人： Charles Kunz ,  Walter Kunz

    IPC分类号： A24B15/28 ,  A24D3/16 ,  A24B3/10 ,  A24B15/00

    CPC分类号： A24B15/287 ,  A24B15/28 ,  A24D3/16

    摘要： This invention relates to the treatment of tobacco and tobacco smoke with chelating agents to reduce the concentration of Pb-210 and Po-210. Chelating formulations such as the tetrasodium salt of ethylenediaminetetraacetic acid in aqueous solution with a wetting agent are sprayed onto the tobacco during growth and/or the chelating formulations are used to soak or wash the tobacco after harvest but before curing the tobacco. Pb-210, Po-210 and other metals are removed from tobacco smoke by applying chelating agents to the surface of the tobacco and/or the filter material.

    摘要翻译： 本发明涉及用螯合剂处理烟草烟草烟雾以降低Pb-210和Po-210的浓度。 螯合配方如乙二胺四乙酸的四钠盐在水溶液中与润湿剂在生长期间喷洒到烟草上，和/或螯合制剂用于在收获后但在固化烟草之前浸泡或洗涤烟草。 通过将螯合剂施用到烟草和/或过滤材料的表面，从烟草烟雾中除去Pb-210，Po-210和其它金属。

    3-amino-2-mercaptobenzoic acid derivatives and processes for their preparation
    8.
    发明授权
    3-amino-2-mercaptobenzoic acid derivatives and processes for their preparation 失效
    3-氨基-2-巯基苯甲酸衍生物及其制备方法

    公开(公告)号：US5770758A

    公开(公告)日：1998-06-23

    申请号：US770353

    申请日：1996-12-20

    申请人： Walter Kunz ,  Beat Jau

    发明人： Walter Kunz ,  Beat Jau

    IPC分类号： C07C323/62 ,  C07C20060101 ,  C07C319/02 ,  C07C319/12 ,  C07C323/33 ,  C07C323/34 ,  C07C323/47 ,  C07C323/49 ,  C07C323/63 ,  C07C323/64 ,  C07C327/26 ,  C07C335/16 ,  C07C335/22 ,  C07D20060101 ,  C07D277/82 ,  C07D285/00 ,  C07D285/01 ,  C07D285/06 ,  C07D285/14 ,  C07D417/04 ,  C07C255/07 ,  C07C321/08 ,  C07C327/16

    CPC分类号： C07D285/14 ,  C07C319/02 ,  C07C319/12 ,  C07C323/63 ,  C07C327/26 ,  C07C335/22 ,  C07D277/82

    摘要： Compounds of the formula I ##STR1## and disulfides thereof and salts thereof are important intermediate products for the preparation of compounds having a microbicidal and plant-immunizing action, of the formula III ##STR2## In the compounds of the formulae I and III: X is halogen, n is 0,1,2 or 3; Z is CN, CO-A or CS-A, A is hydrogen, halogen, OR.sub.1, SR.sub.2 and N(R.sub.3)R.sub.4 ; R.sub.1 to R .sub.4 are hydrogen, a substituted or unsubstituted, open-chain, saturated or unsaturated hydrocarbon radical containing not more than 8 carbon atoms, a substituted or unsubstituted cyclic, saturated or unsaturated hydrocarbon radical containing not more than 10 carbon atoms, substituted or unsubstituted benzyl or phenethyl, a substituted or unsubstituted alkanoyl group containing not more than 8 carbon atoms, a substituted or unsubstituted benzoyl group or a substituted or unsubstituted heterocyclyl radical; or R.sub.3 and R.sub.4, together with the nitrogen atom to which they are bonded, are a 5- or 6-membered, substituted or unsubstituted heterocyclic radical having 1-3 heteroatoms O,S and/or N. Processes for the preparation of compounds of the formula I are described.

    摘要翻译： 式I的化合物及其二硫化物及其盐是制备具有式III的杀微生物和植物免疫作用的化合物的重要的中间产物。在式I和III的化合物中 X为卤素，n为0,1,2或3; Z是CN，CO-A或CS-A，A是氢，卤素，OR1，SR2和N（R3）R4; R 1至R 4为氢，取代或未取代的含有不超过8个碳原子的开链，饱和或不饱和烃基，取代或未取代的含有不多于10个碳原子的环状，饱和或不饱和烃基，取代或未取代的 未取代的苄基或苯乙基，取代或未取代的不超过8个碳原子的烷酰基，取代或未取代的苯甲酰基或取代或未取代的杂环基; 或R 3和R 4与它们所键合的氮原子一起是具有1-3个杂原子O，S和/或N的5或6元取代或未取代的杂环基。用于制备 描述了式I。

    Method for the protection of plants against diseases
    9.
    发明授权
    Method for the protection of plants against diseases 失效
    保护植物免受疾病的方法

    公开(公告)号：US5049569A

    公开(公告)日：1991-09-17

    申请号：US325848

    申请日：1989-03-20

    申请人： Walter Kunz

    发明人： Walter Kunz

    IPC分类号： A01N47/32 ,  A01N47/34 ,  A01N47/36 ,  A01N47/38 ,  A01N53/04 ,  C07D213/81 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12

    CPC分类号： C07D213/81 ,  A01N47/34 ,  A01N47/36 ,  A01N47/38 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12

    摘要： Novel acylated urea derivatives of the general formula ##STR1## in which: X is hydrogen or halogen; Y is halogen; R.sub.1, R.sub.2 independently of one another are hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkyl which is substituted by halogen, cyano, C.sub.1 -C.sub.4 alkoxy or COO-C.sub.1 -C.sub.3 alkyl, or is C.sub.3 -C.sub.5 alkenyl or C.sub.3 -C.sub.5 alkenyl which is substituted by halogen, or is C.sub.3 -C.sub.5 alkynyl or C.sub.3 -C.sub.5 alkynyl which is substituted by halogen, or is C.sub.3 -C.sub.7 cycloalkyl or C.sub.3 -C.sub.7 cycloalkyl which is substituted by C.sub.1 -C.sub.2 alkyl, halogen, cyano or COO-C.sub.1 -C.sub.3 alkyl, or is phenyl, benzyl or phenyl or benzyl which are substituted by C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or halogen; and R.sub.1 can furthermore also be the radical Q or Q which is substituted by C.sub.1 -C.sub.3 alkyl, C.sub.3 -C.sub.7 cycloalkyl, C.sub.1 -C.sub.3 alkoxy or halogen, where Q can be bonded to the N atom via a C.sub.1 -C.sub.2 alkyl; or where R.sub.1 and R.sub.2 together with the adjacent N atom from a 3- to 7-membered heterocycle which can additionally contain 1 or 2 further hetero atoms such as O, N or S, and a carbonyl group and can be substituted by C.sub.1 -C.sub.3 alkyl, halogen or COO-C.sub.1 -C.sub.3 alkyl; Q is furan-2-yl, thiophen-2-yl, isoxazol-3-yl, isoxazol-3-yl, thiazol-2-yl, 1,2,4-thiadiazol-3-yl, 1,3,4-thiadiazol-2-yl, 2-, 3- or 4-pyridyl radicals or 2-, 3- or 4-pyridyl radicals which are substituted by C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio or halogen; 2-, 4- or 5-pyrimidyl radicals or 2-, 4- or 5-pyrimidyl radicals which are substituted by C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio, halogen or cyclopropyl.The novel active substances have plant-protecting properties and are suitable in particular for the preventive protection of plants against infection with phytopathogenic microorganisms, such as fungi, bacteria and viruses.

    摘要翻译： 新型通式为“IMAGE”的酰化脲衍生物，其中：X为氢或卤素; Y为卤素; R 1，R 2彼此独立地是氢，C 1 -C 6烷基或被卤素，氰基，C 1 -C 4烷氧基或COO-C 1 -C 3烷基取代的C 1 -C 6烷基，或被被卤素取代的C 3 -C 5烯基或C 3 -C 5链烯基， 或被被卤素取代的C3-C5炔基或C3-C5炔基，或是被C1-C2烷基，卤素，氰基或COO-C1-C3烷基取代的C3-C7环烷基或C3-C7环烷基，或是苯基，苄基或苯基或 被C 1 -C 3烷基，C 1 -C 3烷氧基或卤素取代的苄基; 并且R 1还可以是被C 1 -C 3烷基，C 3 -C 7环烷基，C 1 -C 3烷氧基或卤素取代的基团Q或Q，其中Q可以通过C 1 -C 2烷基与N原子键合; 或者其中R 1和R 2与相邻的N原子一起形成3至7元杂环，其可另外含有1或2个另外的杂原子如O，N或S和羰基，并且可以被C 1 -C 3烷基 ，卤素或COO-C 1 -C 3烷基; Q是呋喃-2-基，噻吩-2-基，异恶唑-3-基，异恶唑-3-基，噻唑-2-基，1,2,4-噻二唑-3-基， C 1 -C 3烷氧基，C 1 -C 3烷硫基或卤素取代的噻唑烷-2-基，2-，3-或4-吡啶基或2-，3-或4-吡啶基; 被C 1 -C 3烷基，C 1 -C 3烷氧基，C 1 -C 3烷硫基，卤素或环丙基取代的2-，4-或5-嘧啶基或2-，4-或5-嘧啶基。 新型活性物质具有植物保护性质，特别适用于植物防止植物病原微生物如真菌，细菌和病毒感染的预防性保护。

    1,3-Dioxolan-5-one derivatives
    10.
    发明授权
    1,3-Dioxolan-5-one derivatives 失效
    1,3-二氧戊环-5-酮衍生物

    公开(公告)号：US4447625A

    公开(公告)日：1984-05-08

    申请号：US422314

    申请日：1982-09-23

    申请人： Walter Kunz

    发明人： Walter Kunz

    IPC分类号： A01N43/50 ,  A01N43/653 ,  C07C51/295 ,  C07D317/34 ,  C07D317/72 ,  C07D405/06 ,  C07D521/00

    CPC分类号： C07D317/72 ,  A01N43/50 ,  A01N43/653 ,  C07C51/295 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D317/34

    摘要： The invention relates to novel 4-(1H-azolylmethyl)-1,3-dioxolan-5-one derivatives of the formula I ##STR1## and to the production and use of these compounds. In formula I, R.sub.1 and R.sub.2 are unsubstituted or substituted alkyl or phenyl, or together form a 3- to 7-membered carbocyclic ring which is unsubstituted or substituted, A is an unsubstituted or substituted phenyl radical, and X is --CH.dbd. or --N.dbd.. The compounds of the formula I can be used in the form of appropriate compositions for regulating plant growth and/or for controlling and/or protecting plants from attack by phytopathogenic microorganisms.

    摘要翻译： 本发明涉及式I（I）的新型4-（1H-吡唑甲基）-1,3-二氧戊环-5-酮衍生物以及这些化合物的生产和使用。 在式Ⅰ中，R 1和R 2为未取代或取代的烷基或苯基，或一起形成未取代或取代的3-至7-元碳环，A为未取代或取代的苯基，X为-CH =或 - N =。 式I的化合物可以以用于调节植物生长和/或控制和/或保护植物免受植物病原微生物攻击的适当组合物的形式使用。