公开(公告)号：US09211769B2

公开(公告)日：2015-12-15

申请号：US14360693

申请日：2012-12-26

Applicant: BRIDGESTONE CORPORATION

Inventor： Tetsuo Amamoto ,  Koji Masaki

IPC: B60C11/14 ,  C08L7/00 ,  B60C1/00 ,  C08L21/00 ,  C09D123/08

CPC classification number: B60C11/14 ,  B60C1/00 ,  B60C1/0016 ,  B60C2011/145 ,  C08K3/04 ,  C08K3/06 ,  C08K3/22 ,  C08K5/09 ,  C08K5/3467 ,  C08K5/548 ,  C08K7/02 ,  C08K9/08 ,  C08L7/00 ,  C08L9/00 ,  C08L21/00 ,  C09D123/0853 ,  D01F8/04 ,  D01F8/06

Abstract: The present invention relates to a rubber composition capable of sustaining improved on-ice performance of a tire over a long period of time. Specifically, the present invention provides a rubber composition having a rubber component (A) and a composite fiber (B), wherein the composite fiber (B) comprises: a fiber (B1) made of a hydrophilic resin; a covering layer (B2) made of a resin having an affinity for a rubber component and provided to cover at least a portion of the fiber; and a bonding layer (B3) present at least in a portion of an interface between the fiber (B1) and the covering layer (B2) and having affinities for both the hydrophilic resin and the resin having an affinity for the rubber component.

Abstract translation: 橡胶组合物技术领域本发明涉及能够长时间保持轮胎的改进的冰上性能的橡胶组合物。 具体而言，本发明提供具有橡胶成分（A）和复合纤维（B）的橡胶组合物，其中复合纤维（B）包括：由亲水性树脂制成的纤维（B1） 由对橡胶部件具有亲和力的树脂制成的覆盖层（B2），其设置成覆盖至少一部分纤维; 和至少在纤维（B1）和被覆层（B2）之间的界面的一部分中存在并且对亲水性树脂和对橡胶组分具有亲和性的树脂具有亲和性的粘结层（B3）。

公开(公告)号：US09574073B2

公开(公告)日：2017-02-21

申请号：US14361324

申请日：2012-12-26

Applicant: BRIDGESTONE CORPORATION

Inventor： Tetsuo Amamoto ,  Koji Masaki

IPC: C08J3/24 ,  C08L7/00 ,  B60C1/00 ,  C08J9/10

CPC classification number: C08L7/00 ,  B60C1/00 ,  B60C1/0016 ,  C08J3/24 ,  C08J9/10 ,  C08J2203/04 ,  C08J2321/00 ,  C08K3/04 ,  C08K3/06 ,  C08K5/3477 ,  C08K5/47 ,  C08K2003/0893 ,  C08K2201/003 ,  C08K2201/005 ,  C08L9/00 ,  C08L23/0861 ,  C08L2205/16

Abstract: The present invention provides a vulcanized rubber capable of improving ice performance of the tire, in particular a vulcanized rubber which is made by vulcanizing a rubber component and has cells with an aspect ratio of 1-30 of which at least a part of a wall surface is hydrophilic.

Abstract translation: 本发明提供一种能够改善轮胎的冰特性的硫化橡胶，特别是通过硫化橡胶组分制成的硫化橡胶，并且具有纵横比为1-30的细胞，其中壁表面的至少一部分 是亲水的。

公开(公告)号：US20140326376A1

公开(公告)日：2014-11-06

申请号：US14360693

申请日：2012-12-26

Applicant: BRIDGESTONE CORPORATION

Inventor： Tetsuo Amamoto ,  Koji Masaki

IPC: B60C11/14 ,  C08L7/00 ,  B60C1/00

CPC classification number: B60C11/14 ,  B60C1/00 ,  B60C1/0016 ,  B60C2011/145 ,  C08K3/04 ,  C08K3/06 ,  C08K3/22 ,  C08K5/09 ,  C08K5/3467 ,  C08K5/548 ,  C08K7/02 ,  C08K9/08 ,  C08L7/00 ,  C08L9/00 ,  C08L21/00 ,  C09D123/0853 ,  D01F8/04 ,  D01F8/06

Abstract: The present invention relates to a rubber composition capable of sustaining improved on-ice performance of a tire over a long period of time. Specifically, the present invention provides a rubber composition having a rubber component (A) and a composite fiber (B), wherein the composite fiber (B) comprises: a fiber (B1) made of a hydrophilic resin; a covering layer (B2) made of a resin having an affinity for a rubber component and provided to cover at least a portion of the fiber; and a bonding layer (B3) present at least in a portion of an interface between the fiber (B1) and the covering layer (B2) and having affinities for both the hydrophilic resin and the resin having an affinity for the rubber component.

Abstract translation: 橡胶组合物技术领域本发明涉及能够长时间保持轮胎的改进的冰上性能的橡胶组合物。 具体而言，本发明提供具有橡胶成分（A）和复合纤维（B）的橡胶组合物，其中复合纤维（B）包括：由亲水性树脂制成的纤维（B1） 由对橡胶部件具有亲和力的树脂制成的覆盖层（B2），其设置成覆盖至少一部分纤维; 和至少在纤维（B1）和被覆层（B2）之间的界面的一部分中存在并且对亲水性树脂和对橡胶组分具有亲和性的树脂具有亲和性的粘结层（B3）。

公开(公告)号：US20140316023A1

公开(公告)日：2014-10-23

申请号：US14361324

申请日：2012-12-26

Applicant: BRIDGESTONE CORPORATION

Inventor： Tetsuo Amamoto ,  Koji Masaki

IPC: C08L7/00 ,  C08J3/24

CPC classification number: C08L7/00 ,  B60C1/00 ,  B60C1/0016 ,  C08J3/24 ,  C08J9/10 ,  C08J2203/04 ,  C08J2321/00 ,  C08K3/04 ,  C08K3/06 ,  C08K5/3477 ,  C08K5/47 ,  C08K2003/0893 ,  C08K2201/003 ,  C08K2201/005 ,  C08L9/00 ,  C08L23/0861 ,  C08L2205/16

Abstract: The present invention provides a vulcanized rubber capable of improving ice performance of the tire, in particular a vulcanized rubber which is made by vulcanizing a rubber component and has cells with an aspect ratio of 1-30 of which at least a part of a wall surface is hydrophilic.

Abstract translation: 本发明提供一种能够改善轮胎的冰特性的硫化橡胶，特别是通过硫化橡胶组分制成的硫化橡胶，并且具有纵横比为1-30的细胞，其中壁表面的至少一部分 是亲水的。

公开(公告)号：US09644052B2

公开(公告)日：2017-05-09

申请号：US14665607

申请日：2015-03-23

Applicant: BRIDGESTONE CORPORATION ,  JSR CORPORATION

Inventor： Yoichi Ozawa ,  H. Jerrold Miller ,  Koji Masaki ,  Koichi Morita ,  Tatsuo Fujimaki ,  Tetsuya Omura ,  Takuo Sone ,  Iwakazu Hattori

IPC: C08K5/13 ,  C08F136/14 ,  C08C19/00 ,  C08C19/44 ,  C08F36/04 ,  C08C19/22 ,  C08F136/06 ,  C08K3/04 ,  C08K3/36

CPC classification number: C08F136/14 ,  C08C19/00 ,  C08C19/22 ,  C08C19/44 ,  C08F36/04 ,  C08F136/06 ,  C08K3/04 ,  C08K3/045 ,  C08K3/36 ,  C08L21/00 ,  C08L91/00 ,  C08F4/545 ,  C08L15/00

Abstract: In general the present invention provides a functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with a functionalizing agent defined by the formula (I) A-R1—Z   (I) where R1 is a divalent bond or divalent organic group comprising from 0 to about 20 carbon atoms, A is a substituent that will undergo an addition reaction with a pseudo-living polymer, and Z is a substituent that will react or interact with silica or carbon black reinforcing fillers, with the proviso that A, R1, and Z are substituents that will not protonate a pseudo-living polymer.

公开(公告)号：US08987362B2

公开(公告)日：2015-03-24

申请号：US14101820

申请日：2013-12-10

Applicant: Bridgestone Corporation ,  JSR Corporation

Inventor： Yoichi Ozawa ,  H. Jerrold Miller ,  Koji Masaki ,  Koichi Morita ,  Tatsuo Fujimaki ,  Tetsuyo Omura ,  Takuo Sone ,  Iwakazu Hattori

IPC: C08K5/13 ,  C08F36/06 ,  C08F136/06 ,  C08C19/00 ,  C08C19/44 ,  C08F36/04 ,  C08C19/22

CPC classification number: C08F136/14 ,  C08C19/00 ,  C08C19/22 ,  C08C19/44 ,  C08F36/04 ,  C08F136/06 ,  C08K3/04 ,  C08K3/045 ,  C08K3/36 ,  C08L21/00 ,  C08L91/00 ,  C08F4/545 ,  C08L15/00

Abstract: In general the present invention provides a functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with a functionalizing agent defined by the formula (I) A-R1—Z  (I) where R1 is a divalent bond or divalent organic group comprising from 0 to about 20 carbon atoms, A is a substituent that will undergo an addition reaction with a pseudo-living polymer, and Z is a substituent that will react or interact with silica or carbon black reinforcing fillers, with the proviso that A, R1, and Z are substituents that will not protonate a pseudo-living polymer.

Abstract translation: 通常本发明提供一种官能化聚合物，该方法包括以下步骤：通过使共轭单体与镧系元素类催化剂聚合制备假活性聚合物，并使假活性聚合物与由式（ I）A-R1-Z（I）其中R1是包含0至约20个碳原子的二价键或二价有机基团，A是将与假活性聚合物进行加成反应的取代基，Z是 将与二氧化硅或炭黑增强填料反应或相互作用的取代基，条件是A，R1和Z是不会使假活性聚合物质子化的取代基。