公开(公告)号：US20200377450A1

公开(公告)日：2020-12-03

申请号：US16859274

申请日：2020-04-27

Applicant: ExxonMobil Research and Engineering Company

Inventor： Abhimanyu O. Patil ,  Satish Bodige ,  Aruna Mohan ,  Arben Jusufi ,  Kanmi Mao

IPC: C07C309/42 ,  C10M135/10

Abstract: The present disclosure relates to surfactants formed from sulfonation of aromatic ethers. The example surfactant composition may include a sulfonated aromatic ether. The sulfonated aromatic ether may include an aromatic ring with substituents comprising an ether group and a sulfonic acid group or a salt of the sulfonic acid group. The ether group may be represented by the following formula: wherein R1 is a linear or branched alkyl group having from 1 carbon atom to 20 carbon atoms; wherein each R2 is individually a hydrogen or an alkyl group having from 1 carbon atom to 4 carbon atoms; and wherein n is a value from 0 to 8.

公开(公告)号：US10227539B2

公开(公告)日：2019-03-12

申请号：US15198346

申请日：2016-06-30

Applicant: ExxonMobil Research and Engineering Company

Inventor： Michael P. Lanci ,  Stuart L. Soled ,  Javier Guzman ,  Sabato Miseo ,  Thomas E. Green ,  Joseph E. Baumgartner ,  Lei Zhang ,  Christine E. Kliewer ,  Lukasz Koziol ,  Kanmi Mao ,  Tracie L. Owens ,  Gary P. Schleicher

IPC: C10G45/00 ,  C10M101/02 ,  B01J23/42 ,  B01J23/44 ,  B01J31/02 ,  B01J31/28 ,  B01J37/02 ,  C10G45/34 ,  C10G45/46 ,  C10G45/52 ,  C10G65/12 ,  B01J37/08 ,  B01J35/00 ,  B01J37/00 ,  B01J21/12 ,  B01J23/46

Abstract: Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.

公开(公告)号：US10227535B2

公开(公告)日：2019-03-12

申请号：US15198397

申请日：2016-06-30

Applicant: ExxonMobil Research and Engineering Company

Inventor： Michael P. Lanci ,  Stuart L. Soled ,  Javier Guzman ,  Sabato Miseo ,  Thomas E. Green ,  Joseph E. Baumgartner ,  Lei Zhang ,  Christine E. Kliewer ,  Lukasz Koziol ,  Kanmi Mao ,  Tracie L. Owens ,  Gary P. Schleicher ,  Xiaochun Xu

IPC: C10G45/52 ,  C10G45/00 ,  B01J23/42 ,  B01J23/44 ,  B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J23/46 ,  B01J31/02 ,  B01J31/28 ,  B01J37/02 ,  C10G45/34 ,  C10G45/46 ,  C10G65/08

Abstract: Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.

公开(公告)号：US20210380425A1

公开(公告)日：2021-12-09

申请号：US17285546

申请日：2019-11-01

Applicant: ExxonMobil Research and Engineering Company

Inventor： Joseph M. Falkowski ,  Hilda Bouza Vroman ,  Allen W. Burton ,  Eugene Terefenko ,  Kanmi Mao ,  Karl G. Strohmaier

IPC: C01B39/48 ,  B01D53/047 ,  B01J20/18

Abstract: A composition can include a Rho zeolite with a RHO topology having a Si to B ratio or a Si to A1 ratio greater than or equal to 8. Making such a composition can include heating an aqueous reaction mixture having a molar ratio of atomic Si to atomic B of about 4 to about 50 or a molar ratio of atomic Si to atomic Al of about 4 to about 50 in the presence of a C4-C6 diquat of N,2-dimethylbenzimidazole structure directing agent to a temperature of at least 75° C. to produce a Rho zeolite.

公开(公告)号：US20210188749A1

公开(公告)日：2021-06-24

申请号：US17124905

申请日：2020-12-17

Applicant: ExxonMobil Research and Engineering Company

Inventor： Ross Mabon ,  Shane Deighton ,  Arben Jusufi ,  Kanmi Mao

IPC: C07C31/125 ,  C07C43/13 ,  C07C29/147 ,  C07C41/18

Abstract: Provided herein are novel extended branched alcohols having a lower branching number and improved biodegradability when compared to other branched alcohols. Also provided are novel extended branched ethoxylates having surfactant properties which can be more efficient in reducing surface tension when compared to the ethoxylated form of other branched alcohols. Further provided are novel syntheses of making extended branched alcohols and extended branched ethoxylates.

公开(公告)号：US20200109058A1

公开(公告)日：2020-04-09

申请号：US16558659

申请日：2019-09-03

Applicant: ExxonMobil Research and Engineering Company

Inventor： Allen W. Burton ,  Hilda B. Vroman ,  Joseph M. Falkowski ,  Eugene Terefenko ,  Kanmi Mao

IPC: C01B39/48 ,  C01B39/08 ,  C01B39/12

Abstract: The zeolite UTD-1 may be formed under hydrothermal synthesis conditions using a directing agent that does not include a metal atom therein. Methods for synthesizing the zeolite UTD-1 may comprise: combining at least a silicon atom source and a directing agent having a structure of in an aqueous medium; forming the zeolite in the aqueous medium under hydrothermal synthesis conditions, such that the zeolite has a framework silicate with a cationic portion of the directing agent occluded within pores or channels of the framework silicate; and isolating the zeolite from the aqueous medium. The zeolite has a powder x-ray diffraction pattern with at least the following 2θscattering angles: 6.0±0.12, 7.6±0.1, 14.66±0.15, 19.7±0.15, 21.27±0.15, 22.13±0.15, 22.61±0.15, and 24.42±0.10 for a borosilicate form zeolite, or 6.0±0.12, 7.6±0.15, 14.55±0.15, 19.64±0.15, 21.01±0.20, 21.90±0.20, 22.34±0.20, and 24.38 ±0.20 for an aluminosilicate form zeolite.

公开(公告)号：US20160367962A1

公开(公告)日：2016-12-22

申请号：US15175071

申请日：2016-06-07

Applicant: ExxonMobil Research and Engineering Company

Inventor： Yi Du ,  Kanmi Mao ,  Bradley Wooler ,  Arun K. Sharma ,  Doug F. Colmyer ,  Frank C. Wang ,  Simon C. Weston

IPC: B01J20/18 ,  B01J20/26 ,  C12P7/06 ,  C10L1/02 ,  C12P7/16 ,  C12P5/02 ,  C07C29/76 ,  C07C7/13

CPC classification number: B01J20/18 ,  B01D15/00 ,  B01J20/226 ,  B01J20/267 ,  B01J2220/44 ,  C07C7/13 ,  C07C29/76 ,  C10L1/02 ,  C10L2290/12 ,  C10L2290/26 ,  C10L2290/542 ,  C12P5/02 ,  C12P7/06 ,  C12P7/16 ,  Y02E50/17 ,  Y02E50/343

Abstract: Adsorbent materials comprising a ZIF material and cross-linked polymer are provided herein. Methods of separating organic compounds from an aqueous solution or a non-aqueous solution and biofuel production processes using the adsorbent material are also provided herein.

Abstract translation: 本文提供了包含ZIF材料和交联聚合物的吸附材料。 本文还提供了使用吸附剂材料从水溶液或非水溶液中分离有机化合物的方法和生物燃料生产方法。

公开(公告)号：US11292756B2

公开(公告)日：2022-04-05

申请号：US17124905

申请日：2020-12-17

Applicant: ExxonMobil Research and Engineering Company

Inventor： Ross Mabon ,  Shane Deighton ,  Arben Jusufi ,  Kanmi Mao

IPC: C07C31/125 ,  C07C41/18 ,  C07C43/13 ,  C07C29/147 ,  C07C67/08

Abstract: Provided herein are novel extended branched alcohols having a lower branching number and improved biodegradability when compared to other branched alcohols. Also provided are novel extended branched ethoxylates having surfactant properties which can be more efficient in reducing surface tension when compared to the ethoxylated form of other branched alcohols. Further provided are novel syntheses of making extended branched alcohols and extended branched ethoxylates.

公开(公告)号：US10807875B2

公开(公告)日：2020-10-20

申请号：US16558659

申请日：2019-09-03

Applicant: ExxonMobil Research and Engineering Company

Inventor： Allen W. Burton ,  Hilda B. Vroman ,  Joseph M. Falkowski ,  Eugene Terefenko ,  Kanmi Mao

IPC: C01B39/48 ,  C01B39/08 ,  C01B39/12 ,  B01J20/18 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  B01J20/10

Abstract: The zeolite UTD-1 may be formed under hydrothermal synthesis conditions using a directing agent that does not include a metal atom therein. Methods for synthesizing the zeolite UTD-1 may comprise: combining at least a silicon atom source and a directing agent having a structure of in an aqueous medium; forming the zeolite in the aqueous medium under hydrothermal synthesis conditions, such that the zeolite has a framework silicate with a cationic portion of the directing agent occluded within pores or channels of the framework silicate; and isolating the zeolite from the aqueous medium. The zeolite has a powder x-ray diffraction pattern with at least the following 2θscattering angles: 6.0±0.12, 7.6±0.1, 14.66±0.15, 19.7±0.15, 21.27±0.15, 22.13±0.15, 22.61±0.15, and 24.42±0.10 for a borosilicate form zeolite, or 6.0±0.12, 7.6±0.15, 14.55±0.15, 19.64±0.15, 21.01±0.20, 21.90±0.20, 22.34±0.20, and 24.38±0.20 for an aluminosilicate form zeolite.

公开(公告)号：US09919288B2

公开(公告)日：2018-03-20

申请号：US15175071

申请日：2016-06-07

Applicant: ExxonMobil Research and Engineering Company

Inventor： Yi Du ,  Kanmi Mao ,  Bradley Wooler ,  Arun K. Sharma ,  Doug F. Colmyer ,  Frank C. Wang ,  Simon C. Weston

IPC: B01J20/18 ,  B01D15/00 ,  B01J20/22 ,  B01J20/26 ,  C07C7/13 ,  C07C29/76 ,  C10L1/02 ,  C12P5/02 ,  C12P7/06 ,  C12P7/16

CPC classification number: B01J20/18 ,  B01D15/00 ,  B01J20/226 ,  B01J20/267 ,  B01J2220/44 ,  C07C7/13 ,  C07C29/76 ,  C10L1/02 ,  C10L2290/12 ,  C10L2290/26 ,  C10L2290/542 ,  C12P5/02 ,  C12P7/06 ,  C12P7/16 ,  Y02E50/17 ,  Y02E50/343

Abstract: Adsorbent materials comprising a ZIF material and cross-linked polymer are provided herein. Methods of separating organic compounds from an aqueous solution or a non-aqueous solution and biofuel production processes using the adsorbent material are also provided herein.