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公开(公告)号:US20240166960A1
公开(公告)日:2024-05-23
申请号:US18264740
申请日:2021-02-09
Inventor: Samuel J. CADY , Xiaochun XU , Shifang LUO , Michael H. RING , Joseph E. GATT
IPC: C10G65/02
CPC classification number: C10G65/02 , C10G2300/1011 , C10G2300/304 , C10G2300/307 , C10G2400/04
Abstract: A method for producing renewable arctic diesel is provided herein. The method includes contacting a bio-derived feedstock with a hydrotreatment catalyst under effective hydrotreatment conditions to produce a hydrotreated feedstock and separating the hydrotreated feedstock into gas phase products and liquid phase products. The liquid phase products include an oxygen content of less than 0.4 wt % but greater than 10 ppm. The method also includes contacting the liquid phase products with a ZSM-48-based isomerization/dewaxing catalyst under effective isomerization/dewaxing conditions to produce an isomerized product stream including a change in cloud point (ΔCP) of 50 degrees ° C. or more. The method further includes separating the isomerized product stream into gas phase products and liquid phase products, as well as fractionating the liquid phase products to produce renewable naphtha and renewable arctic diesel with a cloud point of −20° C. or less and a yield of 80 wt % or more.
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公开(公告)号:US20230398528A1
公开(公告)日:2023-12-14
申请号:US18041519
申请日:2020-08-19
Inventor: Yi DU , Bradley D. WOOLER , Stuart L. SOLED , Sabato MISEO , Xiaochun XU
CPC classification number: B01J31/1805 , B01J27/02 , B01J37/04 , B01J37/20 , C07C5/02 , C07C2523/84 , B01J2531/845 , B01J2531/66 , B01J2531/64 , B01J2231/641 , B01J2531/0222
Abstract: Compositions can include compounds having a formula: CoyW1-xMx04 (I), wherein M is Mo, V, or Nb; 0.5≥x≥0; and 1
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公开(公告)号:US20240218264A1
公开(公告)日:2024-07-04
申请号:US18091127
申请日:2022-12-29
Inventor: Colin Lee BESWICK , Bing DU , Daniel J. GARCIA , Hyung Rae KIM , Prateek MEHTA , Arun K. SHARMA , Xiaochun XU , Masaaki SUGITA , William J. KNAEBLE , Zhiyan WANG
IPC: C10G11/18
CPC classification number: C10G11/182 , C10G11/187 , C10G2300/1011 , C10G2300/1074 , C10G2300/202 , C10G2300/4006 , C10G2300/4043 , C10G2300/708 , C10G2400/04
Abstract: Systems and methods are provided for expanding the operating envelope for an FCC reaction system while also reducing or minimizing the net environmental CO2 emissions associated with the FCC reaction system and/or the resulting FCC products. In some aspects, reducing or minimizing net environmental CO2 emissions can be achieved during processing of unconventional feeds, such as feeds that are traditionally viewed as having insufficient tendency to coke in order to maintain heat balance within an FCC reaction system. In other aspects, this can correspond to expanding the production of diesel within an FCC reaction system by modifying the reaction conditions in a manner that can cause a reaction system to fall out of heat balance (relative to the heat needed to maintain a target operating temperature) even when using conventional feeds
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公开(公告)号:US20240218259A1
公开(公告)日:2024-07-04
申请号:US18393152
申请日:2023-12-21
Inventor: Megan E. WITZKE , Randolph J. SMILEY , Chuansheng BAI , Scott J. WEIGEL , Xiaochun XU
IPC: C10G3/00 , B01J23/883 , B01J29/78
CPC classification number: C10G3/46 , B01J23/883 , B01J29/7861 , C10G3/50 , C10G2300/1011 , C10G2300/202 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/70 , C10G2400/04 , C10G2400/08
Abstract: Systems and methods are provided for reducing hydrogen consumption during deoxygenation of bio-derived (or at least partially bio-derived) feedstocks. The reduced hydrogen consumption is achieved by performing the deoxygenation in the presence of a bulk multimetallic catalyst and/or in the presence of a base metal dewaxing catalyst having reduced metal stack heights. Additionally, due in part to being able to reduce or minimize hydrogen consumption, the heat release during deoxygenation can also be reduced, thus allowing a smaller catalyst volume to perform deoxygenation.
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公开(公告)号:US20230416611A1
公开(公告)日:2023-12-28
申请号:US18243172
申请日:2023-09-07
Inventor: Xiaochun XU , Hyung Rae KIM , Chengrong WANG , Colin L. BESWICK
CPC classification number: C10G1/06 , C10G11/18 , C10L1/10 , C10G2300/80 , C10G2300/4075 , C10G2300/1011 , C10L1/143
Abstract: Systems and methods are provided for improving product yields and/or product quality during co-processing of fast pyrolysis oil in a fluid catalytic cracking (FCC) reaction environment. The systems and methods can allow for co-processing of an increased amount of fast pyrolysis oil while reducing or minimizing coke production for a feedstock including fast pyrolysis oil and a conventional FCC feed. The reducing or minimizing of coke production can be achieved in part by adding a low molecular weight, non-ionic surfactant to the mixture of fast pyrolysis oil and conventional FCC feed.
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公开(公告)号:US20230407191A1
公开(公告)日:2023-12-21
申请号:US18210878
申请日:2023-06-16
Inventor: Xiaochun XU , Gordon B. MCGARVEY , Vincent A. BRUNET
CPC classification number: C10G47/20 , C10G67/00 , C10G2300/1014 , C10G2300/30
Abstract: This application relates to production of renewable fuels, including a method of producing renewable fuels. The method comprises hydrotreating a biofeedstock by contacting reactants comprising a combined feedstock and hydrogen with a hydrotreating catalyst to produce normal paraffins. The combined feedstock comprises a biofeedstock and an additional feedstock. The biofeedstock has about 10% or more of each of metals, phosphorous, and chlorophyll than the additional feedstock. The biofeedstock comprises the metals in an amount of about 300 parts per million (“ppm”) or less, the phosphorous in an amount of about 300 ppm or less, and the chlorophyll in an amount of about 50 ppm or less. The method further comprises isomerizing at least a portion of the normal paraffins to produce branched paraffins in an isomerization effluent.
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公开(公告)号:US20230257664A1
公开(公告)日:2023-08-17
申请号:US18166852
申请日:2023-02-09
Inventor: Aaron Sattler , Hyung Rae KIM , Theodore W. WALKER , Ethan G. DACOSTA , Xiaochun XU
IPC: C10G11/18
CPC classification number: C10G11/182 , C10G2300/1003 , C10G2300/1007 , C10G2300/1011 , C10G2300/1074
Abstract: The present disclosure provides methods and systems for co-processing a hydrocarbon feed in an FCC system with a second feed of a biomass-derived pyrolysis oil and a third feed of a plastic-derived pyrolysis oil and/or lubricant. A method of co-processing fluid catalytic cracking feeds, includes: introducing a hydrocarbon feed to a fluid catalytic cracking reactor, wherein the hydrocarbon feed comprises hydrocarbons; introducing a biomass feed to the fluid catalytic cracking reactor wherein the biomass feed comprises a biomass-derived pyrolysis oil; introducing a waste feed to the fluid catalytic cracking reactor, wherein the waste feed comprises a plastic, a plastic-derived pyrolysis oil, a lubricant, or a combination thereof; and reacting at least the hydrocarbon feed, the biomass feed, and the waste feed in the presence of one or more fluid catalytic cracking catalysts in the fluid catalytic cracking reactor to produce cracked products.
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公开(公告)号:US20250092317A1
公开(公告)日:2025-03-20
申请号:US18965321
申请日:2024-12-02
Inventor: Hyung Rae KIM , Jihad M. DAKKA , Xiaochun XU
IPC: C10G3/00
Abstract: Systems and methods are provided for increasing the yield of products generated during co-processing of biomass oil in a fluid catalytic cracking (FCC) system. The systems and methods can allow for increased yield by reducing or minimizing formation of carbon oxides, gas phase products, and/or coke yields during the co-processing. This can be achieved by adding a hydrogen-rich co-feed to the co-processing environment. Examples of hydrogen-rich co-feeds include high hydrogen content vacuum gas oil co-feed, high hydrogen content distillate co-feed, and/or high hydrogen content naphtha co-feed. Additionally or alternately, various types of fractions that contain a sufficient amount of hydrogen donor compounds can be used to reduce or minimize carbon oxide formation.
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公开(公告)号:US20230416619A1
公开(公告)日:2023-12-28
申请号:US18165631
申请日:2023-02-07
Inventor: Xiaochun XU , Madelyn M. Evans
IPC: C10G65/08
CPC classification number: C10G65/08 , C10G2300/1011 , C10G2300/4025 , C10G2300/301 , C10G2400/08
Abstract: Systems and methods are provided for production of renewable jet fuel and/or jet fuel blending component fractions. The systems and methods provide for formation of jet boiling range fractions via hydrodeoxygenation and catalytic dewaxing of bio-derived feeds. The systems and methods for reducing or minimizing recycle and/or forming only a jet boiling range product and a lower boiling range product can be facilitated based on selection of a suitable feedstock and/or based on selection of suitable reaction conditions and catalyst for the catalytic dewaxing.
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公开(公告)号:US20240360367A1
公开(公告)日:2024-10-31
申请号:US18768222
申请日:2024-07-10
Inventor: Xiaochun XU , Dario CAMPANI , Hyung Rae KIM
CPC classification number: C10G3/42 , B01D3/14 , B01J8/1818 , B01J8/24 , B01J19/245 , C10L1/04 , C11C3/003 , B01J2219/0004 , C10G2300/1003 , C10G2300/1014 , C10G2300/202 , C10G2400/02 , C10L2200/0484
Abstract: A method may include: providing bio waste stream wherein the bio waste stream comprises at least one bio waste selected from the group consisting of palm oil mill effluent, soapstock, and combinations thereof; introducing the bio waste effluent stream into a fluidized catalytic cracking unit; contacting the bio waste with a catalyst in the fluidized catalytic cracking unit; and cracking at least a portion of the bio waste stream to form cracked products that comprise a cracked product stream.
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