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公开(公告)号：US4315869A
公开(公告)日：1982-02-16
申请号：US143446
申请日：1980-04-24
IPC分类号： C07C255/34 , C07C120/10
CPC分类号： C07C255/00
摘要： .alpha.,.beta.-Unsaturated nitriles are prepared by reacting an aldehyde with formamide in the presence of an acid and the presence or absence of a non-aromatic solvent to give an N-alkenyl-formamide, which is then passed, in the gas phase, over a dehydration catalyst at an elevated temperature.The nitriles obtainable by the process of the invention are valuable starting materials for the preparation of dyes, crop protection agents, plasticizers and drugs.
摘要翻译： α，β-不饱和腈通过使醛与甲酰胺在酸的存在下和存在或不存在非芳族溶剂下反应制备，得到N-烯基 - 甲酰胺，然后在气相中通过， 在高温下脱水催化剂。 通过本发明的方法可获得的腈是用于制备染料，作物保护剂，增塑剂和药物的有价值的起始材料。
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公开(公告)号：US4766237A
公开(公告)日：1988-08-23
申请号：US7578
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz J. Broecker , Franz Merger , Rolf Fischer , Uwe Vagt , Heinz-Walter Schneider , Wolfgang Richter , Wolfgang Harder , Claus-Ulrich Priester
发明人： Hans-Martin Hutmacher , Franz J. Broecker , Franz Merger , Rolf Fischer , Uwe Vagt , Heinz-Walter Schneider , Wolfgang Richter , Wolfgang Harder , Claus-Ulrich Priester
IPC分类号： C07B61/00 , B01J21/16 , B01J23/00 , B01J23/74 , B01J23/755 , B01J25/02 , C07C67/00 , C07C227/00 , C07C227/04 , C07C227/08 , C07C229/08 , C07C67/30
CPC分类号： C07C227/08
摘要： In an improved process for the preparation of 6-aminocaproates by reacting a 5-formylvalerate with ammonia and hydrogen using an alkanol as a solvent in the presence of a hydrogenation catalyst at elevated temperatures and under superatmospheric pressure, the improvement comprises carrying out the reaction at from 40.degree. to 95.degree. C.
摘要翻译： 在氢化催化剂存在下，在升高的温度和超大气压下，通过使用烷醇作为溶剂使5-甲酰基戊酸与氨和氢反应制备6-氨基己酸酯的改进方法，其改进包括在 从40℃到95℃
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公开(公告)号：US4459236A
公开(公告)日：1984-07-10
申请号：US329126
申请日：1981-12-09
IPC分类号： C07C265/06 , C07C67/00 , C07C241/00 , C07C263/04 , C07C269/06 , C07C125/06 , C07C118/04
CPC分类号： C07C263/04 , Y02P20/582
摘要： 1-Alkenyl isocyanates are prepared by reacting aldehydes with carbamates to give N-(1-alkenyl)-carbamates and splitting these compounds at elevated temperatures. The 1,2-unsaturated isocyanates obtained are valuable starting materials for the preparation of pest control agents, dyes, drugs, textile water repellents, detergents, plastics, bleaches and adhesives, since they possess an activated double bond or an activated .alpha.-carbon atom, in addition to a reactive isocyanate group.
摘要翻译： 通过使醛与氨基甲酸酯反应制备1-烯基异氰酸酯，得到N-（1-链烯基） - 氨基甲酸酯，并在升高的温度下分裂这些化合物。 获得的1,2-不饱和异氰酸酯是制备害虫控制剂，染料，药物，纺织品防水剂，洗涤剂，塑料，漂白剂和粘合剂的有价值的起始原料，因为它们具有活化的双键或活化的α-碳原子 ，除了活性异氰酸酯基团外。
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公开(公告)号：US4950429A
公开(公告)日：1990-08-21
申请号：US327432
申请日：1989-03-23
申请人： Uwe Vagt , Rolf Fischer , Franz Merger , Hans-Martin Hutmacher
发明人： Uwe Vagt , Rolf Fischer , Franz Merger , Hans-Martin Hutmacher
IPC分类号： C07C51/09 , C07C67/00 , C07C227/00 , C07C227/08 , C07C229/08 , C07C227/04
CPC分类号： C07C227/08 , C07C51/09
摘要： 6-Aminocaproic acid is prepared by(a) reacting a 5-formylvaleric acid ester with water in the presence of an acid agent at 30.degree.-200.degree. C. and(b) reacting the 5-formylvaleric acid thus obtained with excess ammonia and hydrogen in the presence of a hydrogenation catalyst and of a solvent which is inert under the reaction conditions at 50.degree.-150.degree. C. under superatmospheric pressure.
摘要翻译： 6-氨基己酸的制备方法是：（a）在酸性试剂存在下，在30℃-200℃下使5-甲酰基戊酸酯与水反应，和（b）使所得到的5-甲酰基戊酸与过量的氨和 在氢化催化剂存在下，在50〜150℃的反应条件下，在超大气压下进行惰性的溶剂。
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公开(公告)号：US4777265A
公开(公告)日：1988-10-11
申请号：US22110
申请日：1987-03-05
申请人： Franz Merger , Hans-Martin Hutmacher , Wolfgang Schwarz , Gerhard Nestler , Maria G. Szucsanyi , Rudolf Mueller-Mall
发明人： Franz Merger , Hans-Martin Hutmacher , Wolfgang Schwarz , Gerhard Nestler , Maria G. Szucsanyi , Rudolf Mueller-Mall
IPC分类号： B01J31/00 , B01J31/02 , B01J31/20 , B01J31/22 , C07B61/00 , C07D233/32 , C07D239/10 , C07D239/36 , C07D243/04 , C07D245/02
CPC分类号： C07D239/10 , C07D233/32 , C07D243/04 , C07D245/02
摘要： Acrylates or methacrylates I ##STR1## (A and B=C.sub.2 -C.sub.5 -alkylene, R.sup.1 =H, CH.sub.3) are prepared by reacting an acrylate or methacrylate II ##STR2## (R.sup.2 =C.sub.1 -C.sub.4 -alkyl) with a heterocycle III ##STR3## in the presence of titanium alcoholates chelate compounds of the metals titanium, zirconium, iron and zinc with 1,3-dicarbonyl compounds.
摘要翻译： 丙烯酸酯或甲基丙烯酸酯I（A和B = C 2 -C 5亚烷基，R 1 = H，CH 3）是通过使丙烯酸酯或甲基丙烯酸酯II（R2 = C1-C4-烷基）与杂环 在钛醇化物存在下，III，III，Ⅲ族金属螯合钛，锆，铁和锌与1,3-二羰基化合物的化合物。
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公开(公告)号：US4730040A
公开(公告)日：1988-03-08
申请号：US7788
申请日：1987-01-28
申请人： Uwe Vagt , Rolf Fischer , Franz Merger , Hans-Martin Hutmacher
发明人： Uwe Vagt , Rolf Fischer , Franz Merger , Hans-Martin Hutmacher
IPC分类号： C07D223/04 , C07D201/08
CPC分类号： C07D201/08
摘要： .epsilon.-caprolactam is prepared by a process in which(a) a 5-formylvalerate is reacted with water in the presence of an acidic agent at from 30.degree. to 200.degree. C.,(b) the 5-formylvaleric acid thus obtained is reacted with excess ammonia and hydrogen in the presence of a hydrogenation catalyst and of a solvent which is inert under the reaction conditions, at from 50.degree. to 150.degree. C. under superatmospheric pressure, and(c) after the ammonia has been separated off, the resulting solution of 6-aminocaproic acid is heated to 150.degree.-370.degree. C. and the caprolactam formed is isolated.
摘要翻译： ε-己内酰胺通过以下方法制备：（a）在30℃至200℃下，在酸性试剂存在下，使5-甲酰基戊酸酯与水反应，（b）将所得的5-甲酰基戊酸反应 在氢化催化剂和在反应条件下为惰性的溶剂中，在超大气压下，在50-150℃下，过量的氨和氢，和（c）氨分离后， 将得到的6-氨基己酸溶液加热至150-370℃，形成己内酰胺。
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公开(公告)号：US4731445A
公开(公告)日：1988-03-15
申请号：US007585
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester
发明人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester
CPC分类号： C07D201/08 , Y02P20/52
摘要： Caprolactam is prepared by a process in which(a) the 5-formylvalerate is reacted with excess ammonia and hydrogen in the presence of an alkanol as the solvent and in the presence of a hydrogenation catalyst under superatmospheric pressure in the liquid phase at from 40.degree. to 130.degree. C.,(b) excess ammonia and hydrogen are separated off from the reaction mixture,(c) the resulting reaction mixture is reacted with water at elevated temperatures with simultaneous removal of alkanols, and(d) the reaction mixture thus obtained is heated to 150.degree.-370.degree. C. and .epsilon.-caprolactam is obtained.
摘要翻译： 己内酰胺通过以下方法制备：其中（a）5-烷基戊酸酯与过量的氨和氢在作为溶剂的链烷醇存在下和氢化催化剂存在下，在超大气压下在40℃的液相中反应 （b）从反应混合物中分离出过量的氨和氢，（c）将所得的反应混合物在高温下与水反应，同时除去链烷醇，和（d）由此得到的反应混合物 加热至150-370℃，得到ε-己内酰胺。
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公开(公告)号：US4730041A
公开(公告)日：1988-03-08
申请号：US7789
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester , Heinz-Walter Schneider , Wolfgang Richter
发明人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester , Heinz-Walter Schneider , Wolfgang Richter
IPC分类号： B01J23/74 , B01J23/78 , B01J25/00 , C07B61/00 , C07D201/08
CPC分类号： C07D201/08 , Y02P20/52
摘要： Caprolactam is prepared by a process in which(a) a 5-formylvalerate is reacted with excess ammonia and hydrogen in the presence of an alkanol as a solvent and in the presence of a hydrogenation catalyst under superatmospheric pressure in the liquid phase at from 40.degree. to 130.degree. C.,(b) excess ammonia and hydrogen are separated off from the reaction mixture and(c) the reaction mixture thus obtained is heated to 150.degree.-250.degree. C. and .epsilon.-caprolactam is obtained.
摘要翻译： 己内酰胺通过以下方法制备：其中（a）5-烷基戊酸酯与过量的氨和氢在烷醇作为溶剂的存在下和氢化催化剂的存在下在超大气压下在40℃的液相中反应 至130℃，（b）从反应混合物中分离出过量的氨和氢，（c）将所得反应混合物加热至150-250℃，得到ε-己内酰胺。
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公开(公告)号：US4709072A
公开(公告)日：1987-11-24
申请号：US872967
申请日：1986-06-11
IPC分类号： C07C253/00 , C07C67/00 , C07C253/30 , C07C255/12 , C07C255/13 , C07C255/45 , C07C121/34 , C07C121/46 , C07C121/75
CPC分类号： C07C255/00
摘要： Ethylene cyanohydrin (Ia) and its ethersR--O--CH.sub.2 --CH.sub.2 --CN Ib(where R is an organic radical) are prepared jointly by reacting an alcohol R--OH (II) with 2,2'-dicyanodiethyl ether (III) in the presence of a base.
摘要翻译： 通过使醇R-OH（II）与2,2'-二氰基二乙醚（III）反应制备乙烯氰醇（Ia）及其醚RO-CH2-CH2-CN Ib（其中R是有机基团） 存在基地
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公开(公告)号：US5689010A
公开(公告)日：1997-11-18
申请号：US638592
申请日：1996-04-29
IPC分类号： B01J31/22 , C07B61/00 , C07C45/50 , C07C45/62 , C07C45/73 , C07C45/74 , C07C47/02 , C07C47/21 , C07C45/49
摘要： Aldehydes with a higher number of carbon atoms and high selection are prepared by reacting olefins, in particular from petrochemical refinery products, by a hydroformylation with aldol condensation using a mixed catalyst of rhodium-carbonyl-phosphines and Mannich catalyst.
摘要翻译： 通过使用铑 - 羰基膦和Mannich催化剂的混合催化剂通过使醛醇缩合的加氢甲酰化反应，使烯烃，特别是石油化学品炼油产物反应，制备具有较高碳原子数和高选择性的醛。
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