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公开(公告)号：US4471152A
公开(公告)日：1984-09-11
申请号：US492174
申请日：1983-05-06
申请人： Gerald Doyle , Roy L. Pruett , David W. Savage , W. S. W. Ho
发明人： Gerald Doyle , Roy L. Pruett , David W. Savage , W. S. W. Ho
CPC分类号： C07C7/152
摘要： A process for separating a gaseous alkene mixture into components thereof which comprises contacting the gaseous alkene mixture with a cuprous complex of the formula [Cu(facac)].sub.x L.sub.y where facac is a fluorinated acetylacetonate and L is a stabilizing agent in an organic solvent wherein L is displaced by alkene. Cuprous complexes containing alkene can then be separated provided that the separation factor between alkene complex to be separated and other alkene complexes is at least about 1.05.
摘要翻译： 一种将气态烯烃混合物分离成其组分的方法，其包括使气态烯烃混合物与式[Cu（facac）] xLy的亚铜络合物接触，其中facac为氟化乙酰丙酮化物，L为在有机溶剂中的稳定剂，其中L 被烯烃置换。 然后可以分离含有烯烃的亚铜络合物，只要待分离的烯烃络合物与其它烯烃络合物之间的分离因子为至少约1.05。
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公开(公告)号：US4508694A
公开(公告)日：1985-04-02
申请号：US492173
申请日：1983-05-06
申请人： Gerald Doyle , Roy L. Pruett , David W. Savage
发明人： Gerald Doyle , Roy L. Pruett , David W. Savage
CPC分类号： C07C7/152
摘要： Carbon monoxide is removed from feedstreams by a process which comprises contacting the feedstream with a solution of a cuprous fluorinated acetylacetonate in an organic solvent containing a stabilizing agent to remove CO by forming a first cuprous complex, decomposing the first cuprous complex whereby the stabilizing agent which replaces CO in the first cuprous complex to form a second cuprous complex, and separating the displaced CO. The formation of the second cuprous complex avoids any deposition of copper metal upon heating.
摘要翻译： 从进料流中除去一氧化碳，该方法包括使进料流与含有稳定剂的有机溶剂中的含氟乙酰丙酮化合物的溶液接触，通过形成第一种亚铜络合物除去CO，分解第一种亚铜络合物，由此稳定剂 替代第一个亚铜络合物中的CO以形成第二个亚铜络合物，并分离置换的CO。第二亚铜络合物的形成避免了加热时铜金属的任何沉积。
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3.发明授权
公开(公告)号：US4434317A
公开(公告)日：1984-02-28
申请号：US492225
申请日：1983-05-06
申请人： Gerald Doyle , Roy L. Pruett , David W. Savage
发明人： Gerald Doyle , Roy L. Pruett , David W. Savage
CPC分类号： C07C7/152
摘要： Alkenes, alkynes or mixtures thereof are removed from feedstreams by a process which comprises contacting the feedstream with a solution of a cuprous fluorinated acetylacetone in an organic solvent containing stabilizing agent to remove alkene, alkyne or mixture thereof by forming a first cuprous complex, decomposing the first cuprous complex whereby stabilizing agent replaces alkene or alkyne in the first cuprous complex to form a second cuprous complex, and separating the displaced component. The formation of the second cuprous complex avoids any deposition of copper metal upon heating.
摘要翻译： 烯烃，炔烃或其混合物通过一种方法从进料流中除去，该方法包括使进料流与含氟的含氟乙酰丙酮的有机溶剂中的溶液接触，以除去烯烃，炔烃或其混合物，形成第一个亚铜络合物，分解 第一亚铜络合物，由此稳定剂代替第一亚铜络合物中的烯烃或炔烃以形成第二亚铜络合物，并分离置换的组分。 第二种亚铜络合物的形成避免了加热时铜金属的任何沉积。
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公开(公告)号：US20090152168A1
公开(公告)日：2009-06-18
申请号：US12287744
申请日：2008-10-14
IPC分类号： C10G19/00
摘要： The present invention relates to a process for desulfurizing bitumen and other heavy oils such as low API gravity, high viscosity crudes, tar sands bitumen, or shale oils with alkali metal compounds under conditions to promote in-situ regeneration of the alkali metal compounds. The present invention employs the use of superheated water and hydrogen under conditions to improve the desulfurization and alkali metal hydroxide regeneration kinetics at sub-critical temperatures.
摘要翻译： 本发明涉及一种在碱性金属化合物的原位再生条件下使沥青和其它重油如API重力低，高粘度原油，焦油砂沥青或页岩油脱硫的方法。 本发明使用过热水和氢气条件来改善亚临界温度下的脱硫和碱金属氢氧化物再生动力学。
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公开(公告)号：US5292990A
公开(公告)日：1994-03-08
申请号：US625337
申请日：1990-12-10
CPC分类号： B01J29/40 , C10G25/03 , B01J2229/26 , B01J2229/42
摘要： Basically, the present invention is predicated on the discovery that zeolites that have a high silica to alumina ratio, e.g., a ratio of 20 and above, pore diameters of greater than about 5.0.ANG., and which have substantially no active acid sites, i.e., zeolites which are non-reactive toward olefin isomerization and oligomerization, are especially useful in substantially separating linear olefins and paraffins from hydrocarbon mixtures containing at least linear and branched aliphatic hydrocarbons and optionally containing aromatic and other hydrocarbons.
摘要翻译： 基本上，本发明基于以下发现：发现具有高二氧化硅与氧化铝比例的比例，例如20以上的孔径大于约5.0（Aangstroem），并且基本上没有活性酸性位点， 即对烯烃异构化和低聚不具有反应性的沸石特别可用于从至少含有直链和支链脂族烃并任选含有芳烃和其它烃的烃混合物中基本分离直链烯烃和链烷烃。
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6.发明授权Process for removing acidic gases from gaseous mixtures using aqueous scrubbing solutions containing heterocyclic nitrogen compounds 失效使用含有杂环氮化合物的含水洗涤溶液从气态混合物中除去酸性气体的方法
公开(公告)号：US4624838A
公开(公告)日：1986-11-25
申请号：US728410
申请日：1985-04-29
申请人： Yen-Chi Pan , David W. Savage
发明人： Yen-Chi Pan , David W. Savage
CPC分类号： C01B31/20 , B01D53/1456 , B01D53/1493 , Y02C10/06
摘要： Disclosed is a process for removing acid gases from gaseous streams by contacting the stream with an aqueous scrubbing solution containing a heterocyclic nitrogen compound comprised of either a five-- or six--membered ring having a pKa no greater than about 8. Imidazole is a preferred heterocyclic nitrogen compound.
摘要翻译： 公开了一种通过使该物流与含有由不超过约8的pKa的五元或六元环组成的杂环氮化合物的含水洗涤溶液接触而从气流中除去酸性气体的方法。咪唑是优选的杂环 氮化合物。
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7.发明授权Process for the selective removal of hydrogen sulfide from gaseous mixtures with severely sterically hindered secondary aminoether alcohols 失效从具有严格位阻的仲氨基醚醇的气态混合物中选择性除去硫化氢的方法
公开(公告)号：US4405585A
公开(公告)日：1983-09-20
申请号：US339891
申请日：1982-01-18
CPC分类号： B01D53/1493
摘要： The selective removal of H.sub.2 S gas from a normally gaseous mixture containing H.sub.2 S and CO.sub.2 is accomplished by contacting the gaseous mixture with an absorbent solution comprising a severely sterically hindered secondary aminoether alcohol having a cumulative .sup.- -E.sub.s value (Taft's steric hindrance constant) greater than about 1.75 whereby H.sub.2 S is selectively absorbed from the mixture.
摘要翻译： 通过将气体混合物与包含严重空间位阻的仲氨基醚醇的吸收剂溶液接触来实现H 2 S气体的选择性除去，该混合物的累积-E值（塔夫脱的空间位阻常数）大于约 从而从混合物中选择性地吸收H2S。
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8.发明授权Process for selective removal of H.sub.2 S from mixtures containing H.sub.2 .sub.2 using di-severely sterically hindered secondary aminoethers 失效使用二重立体位阻仲氨基醚从含有H 2 S和CO 2的混合物中选择性除去H 2 S的方法
公开(公告)号：US4405583A
公开(公告)日：1983-09-20
申请号：US339900
申请日：1982-01-18
IPC分类号： B01D53/14 , C07D295/088 , B01D53/34 , C09K3/00
CPC分类号： C07D295/088 , B01D53/1468 , B01D53/1493
摘要： The selective removal of H.sub.2 S gas from a normally gaseous mixture containing H.sub.2 S and CO.sub.2 is accomplished by contacting the gaseous mixture with an absorbent solution comprising a di-secondary aminoether wherein each amino group has a severely sterically hindered secondary amino moiety whereby H.sub.2 S is selectively absorbed from the mixture.
摘要翻译： 通过将气体混合物与包含二仲氨基醚的吸收剂溶液接触来实现从含有H 2 S和CO 2的常规气态混合物中选择性除去H 2 S气体，其中每个氨基具有严格位阻的仲氨基部分，由此H 2 S从 混合物。
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9.发明授权Process for selective removal of H.sub.2 S from mixtures containing H.sub.2 .sub.2 using diaminoether solutions 失效使用二氨基醚溶液从含有H 2 S和CO 2的混合物中选择性除去H 2 S的方法
公开(公告)号：US4405582A
公开(公告)日：1983-09-20
申请号：US339883
申请日：1982-01-18
IPC分类号： B01D53/52 , B01D53/14 , B01D53/77 , C07C67/00 , C07C213/00 , C07C217/08 , C07D207/06 , C07D295/08 , C07D295/088 , C10K1/14 , B01D53/34 , C09K3/00
CPC分类号： C07D295/088 , B01D53/1468 , B01D53/1493
摘要： The selective removal of H.sub.2 S gas from a normally gaseous mixture containing H.sub.2 S and CO.sub.2 is accomplished by contacting the gaseous mixture with an absorbent solution comprising a diaminoether wherein at least one amino group is a tertiary amine whereby H.sub.2 S is selectively absorbed from the mixture.
摘要翻译： 通过将气态混合物与包含二氨基醚的吸收剂溶液接触，其中至少一个氨基是叔胺，从而从混合物中选择性地吸收H 2 S，从而将H 2 S气体从含有H 2 S和CO 2的常规气态混合物中选择性地除去。
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10.发明授权Process and composition for removing carbon dioxide containing acidic gases from gaseous mixtures 失效用于从气体混合物中除去含有酸性气体的二氧化碳的方法和组合物
公开(公告)号：US4217236A
公开(公告)日：1980-08-12
申请号：US835773
申请日：1977-09-22
申请人： Guido Sartori , David W. Savage
发明人： Guido Sartori , David W. Savage
CPC分类号： B01D53/1493 , Y02C10/06
摘要： Carbon dioxide containing acidic gases are substantially removed from a normally gaseous mixture by a process comprising contacting the normally gaseous mixture with an aqueous amine solution, wherein the amine consists of at least about 50 mol % of a sterically hindered amino alcohol and at least about 10 mol % of a tertiary amino alcohol, wherein said sterically hindered amino alcohol contains at least one secondary amino group which is part of a ring and is attached to either a secondary or tertiary carbon atom or a primary amino group attached to a tertiary carbon atom. The coaction of the sterically hindered amino alcohol and the tertiary amino alcohol provide an increase in the amount of carbon dioxide containing acidic gases absorbed compared to the use of the sterically hindered amines alone and lowers the heat of reaction.
摘要翻译： 含有酸性气体的二氧化碳基本上通过包括使常规气态混合物与胺水溶液接触的方法从常规气态混合物除去，其中胺由至少约50mol％的空间位阻氨基醇和至少约10 mol％的叔氨基醇，其中所述空间位阻氨基醇含有至少一个仲氨基，其为环的一部分，并且连接于连接到叔碳原子的仲或叔碳原子或伯氨基。 与单独使用空间位阻胺相比，空间位阻氨基醇和叔氨基醇的共同作用增加了吸收的二氧化碳含量，降低了反应热。
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