公开(公告)号：US4713940A

公开(公告)日：1987-12-22

申请号：US927986

申请日：1986-11-07

Applicant: Gerhard Ranke ,  Friedrich Siegert

Inventor： Gerhard Ranke ,  Friedrich Siegert

IPC: C07C7/11 ,  F25J3/00

CPC classification number: C07C7/11

Abstract: A process is disclosed for obtaining C.sub.2+ or C.sub.3+ hydrocarbons from hydrocarbon-containing gaseous mixtures by pressure scrubbing with a physically acting solvent selective for C.sub.2+ and, respectively, C.sub.3+ hydrocarbons. The solvent, after loading, is regenerated and reused. In order to avoid impurities in the C.sub.2+ and, respectively, C.sub.3+ product in an economical and energy-saving way, the loaded solvent is subjected to expansion to a pressure lying below the critical pressure of the solvent-gas mixture, and to heating and partial evaporation in order to drive off concomitantly dissolved inert gases. The solvent, reduced in its content of inert gases, is then to be passed on to regeneration. The process is advantageous, in particular, in cases where crude gases are to be processed which exhibit a low concentration of components to be scrubbed out.

Abstract translation: 公开了一种用于通过用对C2 +和分别为C3 +烃选择性的物理作用溶剂的压力洗涤从含烃气体混合物中获得C2 +或C3 +烃的方法。 加载后的溶剂被再生并重复使用。 为了以经济和节能的方式避免C2 +和C3 +产品中的杂质，将负载的溶剂膨胀至低于溶剂 - 气体混合物的临界压力的压力，并加热和部分 蒸发以排除伴随溶解的惰性气体。 然后将其惰性气体含量降低的溶剂传递至再生。 该方法是有利的，特别是在粗制气体被处理的情况下，其表现出低浓度待洗涤的组分。

公开(公告)号：US4592766A

公开(公告)日：1986-06-03

申请号：US650016

申请日：1984-09-13

Applicant: Paul Kumman ,  Gerhard Ranke

Inventor： Paul Kumman ,  Gerhard Ranke

IPC: C07C7/04 ,  F25J3/02

CPC classification number: F25J3/0238 ,  C07C7/04 ,  F25J3/0209 ,  F25J3/0233 ,  F25J2200/02 ,  F25J2200/50 ,  F25J2200/70 ,  F25J2205/04 ,  F25J2210/02 ,  F25J2240/02 ,  F25J2245/02 ,  F25J2270/04 ,  F25J2270/90

Abstract: For the separation of ethane and higher hydrocarbons from a high pressure incoming gas containing hydrocarbons, the raw gas is cooled and expanded in several stages and the condensates that are produced are fed to a rectifying column to provide an overhead gaseous product essentially consisting of methane and a bottoms product consisting essentially of ethane and higher hydrocarbons. To save energy, the raw gas and/or the product streams are heat exchanged in parallel streams under different pressures, the cooled high-pressure gas is work-expanded and the condensates produced by cooling and expansion are fed separately to the rectifying column.

Abstract translation: 为了从含有烃的高压进入气体中分离乙烷和高级烃，将原料气体在几个阶段中冷却和膨胀，并将生产的冷凝物加入到精馏塔中以提供基本上由甲烷和 基本上由乙烷和高级烃组成的底部产物。 为了节省能源，原料气体和/或产物流在不同压力下以平行流进行热交换，冷却的高压气体被工作膨胀，并且通过冷却和膨胀产生的冷凝物分别供给到精馏塔。

公开(公告)号：US5133954A

公开(公告)日：1992-07-28

申请号：US679840

申请日：1991-04-01

Applicant: Gerhard Ranke ,  Gunter Weber

Inventor： Gerhard Ranke ,  Gunter Weber

IPC: B01D53/14 ,  C01B17/05

CPC classification number: C01B17/05 ,  B01D53/1425 ,  B01D53/1456

Abstract: For regenerating a scrubbing agent loaded with H.sub.2 S and/or COS, as well as optionally with other raw gas components to be recovered, the loaded scrubbing agent is mixed, preferably without prior heating, with an oxidatively acting solvent that is immiscible with the scrubbing agent, and the H.sub.2 S dissolved in the immiscible solvent is converted to elementary sulfur.

Abstract translation: 为了再生装载有H 2 S和/或COS的洗涤剂以及任选地与待回收的其它原料气体组分一起，将加载的洗涤剂优选不经过预先加热与与洗涤剂不混溶的氧化作用溶剂混合 ，溶解在不混溶溶剂中的H 2 S转化为元素硫。

公开(公告)号：US4810267A

公开(公告)日：1989-03-07

申请号：US871988

申请日：1986-06-09

Applicant: Heiner Landeck ,  Gerhard Ranke

Inventor： Heiner Landeck ,  Gerhard Ranke

IPC: C07C7/11 ,  C10G5/04 ,  B01D19/00

CPC classification number: C07C7/11

Abstract: For scrubbing C.sub.2+ or C.sub.3+ hydrocarbons from gaseous mixture containing hydrocarbons and/or inerts like H.sub.2 N.sub.2, CO and possibly acid gases, e.g. CO.sub.2 H.sub.2 S, COS e.g. natural gas and the like, the scrubbing medium consists essentially of compounds having one to two rings formed by 5 or 6 carbon atoms, wherein the compounds comprise, in total, at least 9 and at most 17 carbon atoms, and the rings are saturated unsaturated or partially saturated especially alkylated ring compounds of 9 or 10 carbon atoms, e.g. isomeric forms of trimethylbenzene, propylbenzene, propylcyclohexane, tetrahydronaphthalene, decahydronaphthalene.

公开(公告)号：US4668488A

公开(公告)日：1987-05-26

申请号：US791128

申请日：1985-10-24

Applicant: Gerhard Ranke ,  Heinz Karwat

Inventor： Gerhard Ranke ,  Heinz Karwat

IPC: B01D53/00 ,  C01B25/027 ,  B01D47/00 ,  B01D51/00 ,  B01J8/00 ,  F25J3/00

CPC classification number: C01B25/027 ,  B01D53/002 ,  Y10S62/92

Abstract: Process for the treatment of CO-rich gases incurred in the manufacture of phosphorus, which gases contain impurities like water, and compounds of sulfur, nitrogen and phosphorus. The gas is passed through regenerators for the purpose of removing impurities. In this manner, a product gas is obtained from which impurities have been condensed or frozen.

Abstract translation: 用于处理在制造磷中产生的富含CO的气体的方法，其中气体含有杂质如水，以及硫，氮和磷的化合物。 为了除去杂质，气体通过再生器。 以这种方式，获得产物气体，其中杂质已被冷凝或冷冻。

公开(公告)号：US3975172A

公开(公告)日：1976-08-17

申请号：US451044

申请日：1974-03-14

Applicant: Gerhard Ranke

Inventor： Gerhard Ranke

IPC: B01D53/14 ,  C07C1/00 ,  C07C7/11 ,  C07C11/24 ,  C07C67/00 ,  C10K1/16 ,  B01D47/06

CPC classification number: B01D53/14 ,  B01D53/1418 ,  B01D53/1425 ,  Y02C10/06

Abstract: Process for the recovery of one or more components of a raw gas, absorbed by the scrubbing liquid during a physical gas scrubbing step, by expanding the laden scrubbing liquid, characterized in that the expanded, laden scrubbing liquid is stripped, before its final regeneration, with a gas consisting exclusively of one or more components of the raw gas and essentially free of the components to be recovered and to be scrubbed out.

Abstract translation: 用于在物理气体洗涤步骤期间通过膨胀装载的洗涤液体来回收原料气体的一种或多种组分被洗涤液体吸收的方法，其特征在于，在其最终再生之前剥离膨胀的载满洗涤液体， 其中气体仅由原料气体的一种或多种组分组成，并且基本上不含待回收的组分并被洗涤出来。

公开(公告)号：US5413627A

公开(公告)日：1995-05-09

申请号：US34798

申请日：1993-03-01

Applicant: Heiner Landeck ,  Gerhard Ranke

Inventor： Heiner Landeck ,  Gerhard Ranke

IPC: B01D53/14 ,  B01D53/48 ,  B01D53/52 ,  C10K1/14 ,  C01B17/00

CPC classification number: B01D53/14 ,  B01D53/1425 ,  B01D53/1493 ,  C10K1/14

Abstract: For the selective removal of sulfur from gases, a physical scrubbing agent is used, comprising a heterocycle having five or more ring atoms, which contains two heteroatoms, one of which is nitrogen and the other of which is oxygen or nitrogen; and the heteroatoms in the rings of even member number of atoms occupy; one of the positions from 1,2 to 1,n/2 and, in the rings of uneven member number of atoms occupy one of the positions from 1,2 up to 1, (n-1)/2. Further, the nitrogen heteroatom(s) present in the ring is/are either double bonded or single bonded but, if single bonded, the nitrogen is organo-substituted.

Abstract translation: 为了从气体中选择性除去硫，使用物理洗涤剂，其包含具有五个或更多个环原子的杂环，其含有两个杂原子，其中一个是氮，另一个是氧或氮; 并且偶数个原子的环中的杂原子占据; 位置从1,2到1，n / 2之一，并且在不均匀成员数原子的环中占据从1,2到1，（n-1）/ 2的位置之一。 此外，存在于环中的氮杂原子是双键或单键的，但如果单键键合，则氮被有机取代。

公开(公告)号：US4797140A

公开(公告)日：1989-01-10

申请号：US896371

申请日：1986-08-14

Applicant: Heiner Landeck ,  Gerhard Ranke

Inventor： Heiner Landeck ,  Gerhard Ranke

IPC: C07C7/11 ,  C10G5/04 ,  B01D47/00

CPC classification number: C07C7/11

Abstract: For scrubbing C.sub.2+ or C.sub.3+ hydrocarbons from gaseous mixture containing hydrocarbons and/or inerts like H.sub.2' N.sub.2, CO and possibly acid gases, e.g. CO.sub.2 H.sub.2 S, COS e.g., natural gas and the like, the scrubbing medium consists essentially of compounds having one to two rings formed by 5 or 6 carbon atoms, wherein the compounds comprise, in total, at least 9 and at most 17 carbon atoms, and the rings are saturated unsaturated or partially saturated especially alkylated ring compounds of 9 or 10 carbon atoms, e.g. isomeric forms of trimethylbenzene, propylbenzene, propylcyclohexane, tetrahydronaphthalene, decahydronaphthalene.

Abstract translation: 用于从含有碳氢化合物和/或惰性气体的气体混合物（如H2'N2，CO）和可能的酸性气体（例如酸性气体）中洗涤C2 +或C3 +烃。 CO 2 H 2 S，COS例如天然气等，洗涤介质基本上由具有一个或两个由5或6个碳原子形成的环的化合物组成，其中化合物总共包含至少9个且至多17个碳原子，以及 环是饱和的不饱和或部分饱和的，尤其是9或10个碳原子的烷基化环化合物，例如 三甲基苯，丙基苯，丙基环己烷，四氢萘，十氢萘的异构体形式。

公开(公告)号：US4690812A

公开(公告)日：1987-09-01

申请号：US692563

申请日：1985-01-18

Applicant: Gerhard Ranke ,  Ulrich Schrader

Inventor： Gerhard Ranke ,  Ulrich Schrader

IPC: C01B3/34 ,  C01C1/04 ,  C07C67/00 ,  C07C239/00 ,  C07C273/10

CPC classification number: C07C273/10

Abstract: The combined production of ammonia and urea by the reaction of gases containing hydrocarbons with steam is conducted by using a steam reformer, downstream secondary reformer, and shift converter. The ammonia synthesis gas (hydrogen, nitrogen and carbon dioxide) is subjected to a high pressure scrubbing step with a physical solvent, to remove the acid impurities, especially CO.sub.2. The pressure on the loaded solvent is reduced to a first intermediate pressure for degasing of the coabsorbed inerts and then to a second intermediate pressure for removal of the bulk of the absorbed CO.sub.2, which is then used for urea synthesis. To remove residual CO.sub.2, the solvent is stripped with air and the resultant air stream containing the stripped residual CO.sub.2 is fed to the secondary reformer.

Abstract translation: 通过使用蒸汽重整器，下游次级重整器和换档转换器，通过含有烃与气体的气体的反应将氨和尿素合并生产。 将氨合成气（氢气，氮气和二氧化碳）用物理溶剂进行高压洗涤，除去酸性杂质，特别是二氧化碳。 负载溶剂上的压力降低到第一中间压力，用于对吸附的惰性气体进行脱气，然后降低到第二中间压力，以除去大部分吸收的CO 2，然后将其用于尿素合成。 为了除去残留的CO 2，用空气汽提溶剂，将含有汽提残余CO 2的所得空气流送入二次重整器。

公开(公告)号：US4533373A

公开(公告)日：1985-08-06

申请号：US500697

申请日：1983-06-03

Applicant: Peter Butz ,  Gerhard Ranke ,  Tran A. Tvan

Inventor： Peter Butz ,  Gerhard Ranke ,  Tran A. Tvan

IPC: B01D53/14 ,  C07C7/11 ,  F25J3/02

CPC classification number: C07C7/11 ,  B01D53/1406 ,  B01D53/1431 ,  B01D53/1456 ,  Y02C10/06 ,  Y02P20/152 ,  Y10S62/922 ,  Y10S62/931

Abstract: For the purification of hydrocarbon-containing, e.g., methane raw gases containing H.sub.2 S and CO.sub.2, the raw gas is dried, and separated by rectification into a hydrocarbon-rich overhead fraction containing some H.sub.2 S and CO.sub.2 and into a bottom fraction consisting essentially of H.sub.2 S and CO.sub.2. The overhead product is freed, in a first scrubbing column, of the acidic components with a physical acting scrubbing medium selective for H.sub.2 S and COS as against CO.sub.2, e.g., polyethylene glycol ether or toluene. The bottom product from the rectification step is vaporized and selectively desulfurized in a second scrubbing column with the same scrubbing medium, and the scrubbed gas from the second scrubbing column is discharged as CO.sub.2 under pressure.

Abstract translation: 为了纯化含烃，例如含有H 2 S和CO 2的甲烷原料气体，干燥原料气体，并通过精馏分离成含有一些H 2 S和CO 2的富含烃的塔顶馏分，并进入基本上由H 2 S组成的塔底馏分和 二氧化碳。 在第一个洗涤塔中，塔顶产物在第一个洗涤塔中释放出酸性成分，其中物理作用的洗涤介质可以选择性地用于H2S和COS，例如聚乙二醇醚或甲苯。 来自精馏步骤的底部产物在具有相同洗涤介质的第二洗涤塔中蒸发并选择性脱硫，并且来自第二洗涤塔的洗涤气体在压力下作为CO 2排出。