公开(公告)号：US20100182689A1

公开(公告)日：2010-07-22

申请号：US12664167

申请日：2008-06-13

申请人： Hidetaka Nakanishi ,  Akio Naka

发明人： Hidetaka Nakanishi ,  Akio Naka

IPC分类号： G02B1/08 ,  C08L33/08 ,  C08K5/3492 ,  C08L37/00 ,  C08L39/00

CPC分类号： C08G18/12 ,  C08G18/0823 ,  C08G18/4286 ,  C08G18/664 ,  C08K5/3492 ,  C09J175/12 ,  G02B1/04 ,  G02B1/105 ,  G02B1/14 ,  G02B5/208 ,  G02B5/3033 ,  C08L33/08 ,  C08G18/3246 ,  C08G18/706 ,  C08L33/064

摘要： Provided is a resin composition containing a thermoplastic acrylic resin and an ultraviolet absorber (UVA). While this resin composition has excellent heat resistance because of its high glass transition temperature, foaming and bleed-out can be suppressed and the problems arising from the evaporation of the UVA can be reduced even during the molding of the resin composition at a high temperature. The resin composition is a thermoplastic resin composition containing a thermoplastic acrylic resin and an ultraviolet absorber having a molecular weight of 700 or more, and having a glass transition temperature of 110° C. or higher. It is preferable that the ultraviolet absorber has a hydroxyphenyltriazine skeleton. It is preferable that the acrylic resin has a ring structure in its main chain. The ring structure is, for example, at least one selected from a lactone ring structure, a glutaric anhydride structure, a glutarimide structure, an N-substituted maleimide structure, and a maleic anhydride structure.

摘要翻译： 提供含有热塑性丙烯酸树脂和紫外线吸收剂（UVA）的树脂组合物。 虽然该树脂组合物由于其玻璃化转变温度高而具有优异的耐热性，但是可以抑制发泡和渗出，并且即使在高温下在树脂组合物的成型期间也可以降低由UVA的蒸发引起的问题。 树脂组合物是含有热塑性丙烯酸树脂和分子量为700以上，玻璃化转变温度为110℃以上的紫外线吸收剂的热塑性树脂组合物。 紫外线吸收剂优选具有羟基苯基三嗪骨架。 优选丙烯酸树脂在其主链中具有环结构。 环结构例如为选自内酯环结构，戊二酸酐结构，戊二酰亚胺结构，N-取代马来酰亚胺结构和马来酸酐结构中的至少一种。

公开(公告)号：US20080033081A1

公开(公告)日：2008-02-07

申请号：US11888113

申请日：2007-07-31

申请人： Keiichi Fujise ,  Itsuko Hamaguchi ,  Akio Naka ,  Daijyo Tomihisa

发明人： Keiichi Fujise ,  Itsuko Hamaguchi ,  Akio Naka ,  Daijyo Tomihisa

IPC分类号： C08F26/10 ,  C08K5/3415

CPC分类号： C08K5/31 ,  C08K5/3415 ,  C08L39/06

摘要： Disclosed is a vinylpyrrolidone-based polymer composition which has improved storage stability and of which the reduction in the molecular weight (K value) under shear stress is small. The composition comprises a vinylpyrrolidone-based polymer and contains from 1 to 10000 ppm of at least one compound selected from a group consisting of biguanides and further contains from 1000 to 30000 ppm of 2-pyrrolidone and from 1 to 5000 ppm of ammonia.

摘要翻译： 公开了一种具有改善的储存稳定性并且其剪切应力下分子量（K值）降低小的乙烯基吡咯烷酮基聚合物组合物。 该组合物包含基于乙烯基吡咯烷酮的聚合物，并且含有1至10000ppm的至少一种选自双胍的化合物，并且还包含1000至30000ppm的2-吡咯烷酮和1至5000ppm的氨。

公开(公告)号：US08119739B2

公开(公告)日：2012-02-21

申请号：US12280789

申请日：2007-02-27

申请人： Hideo Asano ,  Akio Naka ,  Hirokazu Niwa ,  Tomoyuki Kuwamoto ,  Hiroyasu Watabe ,  Yoshiyuki Shiotani

发明人： Hideo Asano ,  Akio Naka ,  Hirokazu Niwa ,  Tomoyuki Kuwamoto ,  Hiroyasu Watabe ,  Yoshiyuki Shiotani

IPC分类号： C08F269/00 ,  C08F20/26 ,  G03C1/00 ,  G03C7/00

CPC分类号： G02B5/3083 ,  C08F220/26 ,  C08J5/18 ,  C08J2333/06

摘要： The invention provides a retardation film, composed primarily of an acrylic polymer, with transparency, heat resistance, and large retardation. The retardation film of the present invention is composed primarily of an acrylic polymer. The film has an in-plane retardation of from 130 nm to 500 nm, inclusive, per 100 μm thickness at a wavelength of 589 nm. The film has a total light transmittance of not less than 85%. The retardation film has a glass transition temperature of preferably from 110° C. to 200° C., inclusive. The acrylic polymer, which is the primary component, preferably has a lactone ring structure.

摘要翻译： 本发明提供一种延迟膜，其主要由丙烯酸类聚合物组成，具有透明性，耐热性和较大延迟。 本发明的延迟膜主要由丙烯酸类聚合物构成。 该薄膜在波长589nm处每100μm厚度具有130nm至500nm的面内延迟。 该膜具有不小于85％的总透光率。 延迟膜的玻璃化转变温度优选为110℃〜200℃。 作为主要成分的丙烯酸系聚合物优选具有内酯环结构。

公开(公告)号：US06498231B2

公开(公告)日：2002-12-24

申请号：US09998665

申请日：2001-12-03

申请人： Daijo Tomihisa ,  Toshiaki Kuriyama ,  Tomiyasu Ueta ,  Akio Naka ,  Hideyuki Nishibayashi ,  Yoshitomo Nakata

发明人： Daijo Tomihisa ,  Toshiaki Kuriyama ,  Tomiyasu Ueta ,  Akio Naka ,  Hideyuki Nishibayashi ,  Yoshitomo Nakata

IPC分类号： C08F600

CPC分类号： C08K5/005 ,  C08K5/13 ,  C08L39/06

摘要： The present invention provides: a vinylpyrrolidone polymer which exhibits good heat resistance and storage stability; a composition containing the vinylpyrrolidone polymer; a stabilization process for the vinylpyrrolidone polymer, and a preservation process for a vinylpyrrolidone polymer by which: even when the vinylpyrrolidone polymer is preserved for a long time or at high temperature, the physical properties such as molecular weight (K value) of the vinylpyrrolidone polymer can be prevented from changing, therefore the vinylpyrrolidone polymer can stably be preserved. To enhance the heat resistance and the storage stability, a vinylpyrrolidone polymer is mixed with a certain amount of antioxidant, and the oxygen concentration is suppressed to not higher than 50,000 ppm in a gas phase that contacts with the vinylpyrrolidone polymer when preserving.

公开(公告)号：US20100168340A1

公开(公告)日：2010-07-01

申请号：US12280162

申请日：2007-02-21

申请人： Kenichi Ueda ,  Shigeo Otome ,  Akio Naka

发明人： Kenichi Ueda ,  Shigeo Otome ,  Akio Naka

IPC分类号： C08L33/02

CPC分类号： C08L33/08 ,  C08F285/00 ,  C08J5/18 ,  C08J2333/12 ,  C08L25/12 ,  C08L33/14 ,  C08L35/06 ,  C08L51/003 ,  C08L2205/22 ,  Y10S524/902 ,  Y10T428/24612 ,  Y10T428/254 ,  C08L2666/04 ,  C08F212/08 ,  C08F220/44

摘要： To realize a resin composition which enables formation of a film having excellent film formability and bending resistance and having a small retardation. A resin composition of the present invention comprises: an acrylic resin as a main component; and organic fine particles whose average particle diameter ranges from 0.01 μm to 1 μm, wherein a glass transition temperature of the acrylic resin ranges from 110° C. to 200° C., and each of the organic fine particles has a structural unit of a vinyl cyanide monomer and a structural unit of an aromatic vinyl monomer.

摘要翻译： 实现能够形成具有优异的成膜性和耐弯曲性并且具有较小延迟的膜的树脂组合物。 本发明的树脂组合物包括：丙烯酸树脂作为主要成分; 平均粒径为0.01μm〜1μm的有机细颗粒，其中丙烯酸树脂的玻璃化转变温度为110℃至200℃，每个有机细颗粒的结构单元为 乙烯基氰单体和芳族乙烯基单体的结构单元。

公开(公告)号：US07700674B2

公开(公告)日：2010-04-20

申请号：US11888113

申请日：2007-07-31

申请人： Keiichi Fujise ,  Itsuko Hamaguchi ,  Akio Naka ,  Daijyo Tomihisa

发明人： Keiichi Fujise ,  Itsuko Hamaguchi ,  Akio Naka ,  Daijyo Tomihisa

IPC分类号： C08F26/10

CPC分类号： C08K5/31 ,  C08K5/3415 ,  C08L39/06

摘要： Disclosed is a vinylpyrrolidone-based polymer composition which has improved storage stability and of which the reduction in the molecular weight (K value) under shear stress is small. The composition comprises a vinylpyrrolidone-based polymer and contains from 1 to 10000 ppm of at least one compound selected from a group consisting of biguanides and further contains from 1000 to 30000 ppm of 2-pyrrolidone and from 1 to 5000 ppm of ammonia.

摘要翻译： 公开了一种具有改善的储存稳定性并且其剪切应力下分子量（K值）降低小的乙烯基吡咯烷酮基聚合物组合物。 该组合物包含基于乙烯基吡咯烷酮的聚合物，并且含有1至10000ppm的至少一种选自双胍的化合物，并且还包含1000至30000ppm的2-吡咯烷酮和1至5000ppm的氨。

公开(公告)号：US06235859B1

公开(公告)日：2001-05-22

申请号：US09323156

申请日：1999-06-01

申请人： Akio Naka ,  Yuuji Shimasaki

发明人： Akio Naka ,  Yuuji Shimasaki

IPC分类号： G08F1612

CPC分类号： C08F16/12 ,  B01J21/16

摘要： Provided are an industrially advantageous process for producing a polymer of polyvinyl ether at a temperature of not lower than a room temperature for short time, and a catalyst used for the process. The above process is characterized by using an acid clay mineral subjected to acid treatment as a catalyst to polymerize vinyl ether.

摘要翻译： 提供了在短时间内不低于室温的温度下生产聚乙烯醚聚合物的工业上有利的方法和用于该方法的催化剂。 上述方法的特征在于使用经酸处理的酸性粘土矿物作为聚合乙烯基醚的催化剂。

公开(公告)号：US07972680B2

公开(公告)日：2011-07-05

申请号：US12280162

申请日：2007-02-21

申请人： Kenichi Ueda ,  Shigeo Otome ,  Akio Naka

发明人： Kenichi Ueda ,  Shigeo Otome ,  Akio Naka

IPC分类号： B32B27/30 ,  C08L33/08 ,  C08L33/20 ,  C08L25/04

CPC分类号： C08L33/08 ,  C08F285/00 ,  C08J5/18 ,  C08J2333/12 ,  C08L25/12 ,  C08L33/14 ,  C08L35/06 ,  C08L51/003 ,  C08L2205/22 ,  Y10S524/902 ,  Y10T428/24612 ,  Y10T428/254 ,  C08L2666/04 ,  C08F212/08 ,  C08F220/44

摘要： To realize a resin composition which enables formation of a film having excellent film formability and bending resistance and having a small retardation. A resin composition of the present invention comprises: an acrylic resin as a main component; and organic fine particles whose average particle diameter ranges from 0.01 μm to 1 μm, wherein a glass transition temperature of the acrylic resin ranges from 110° C. to 200° C., and each of the organic fine particles has a structural unit of a vinyl cyanide monomer and a structural unit of an aromatic vinyl monomer.

摘要翻译： 实现能够形成具有优异的成膜性和耐弯曲性并且具有较小延迟的膜的树脂组合物。 本发明的树脂组合物包括：丙烯酸树脂作为主要成分; 平均粒径为0.01μm〜1μm的有机细颗粒，其中丙烯酸树脂的玻璃化转变温度为110℃至200℃，每个有机细颗粒的结构单元为 乙烯基氰单体和芳族乙烯基单体的结构单元。

公开(公告)号：US20090135483A1

公开(公告)日：2009-05-28

申请号：US12280789

申请日：2007-02-27

申请人： Hideo Asano ,  Akio Naka ,  Hirokazu Niwa ,  Tomoyuki Kuwamoto ,  Hiroyasu Watabe ,  Yoshiyuki Shiotani

发明人： Hideo Asano ,  Akio Naka ,  Hirokazu Niwa ,  Tomoyuki Kuwamoto ,  Hiroyasu Watabe ,  Yoshiyuki Shiotani

IPC分类号： G02B1/08

CPC分类号： G02B5/3083 ,  C08F220/26 ,  C08J5/18 ,  C08J2333/06

摘要： The invention provides a retardation film, composed primarily of an acrylic polymer, with transparency, heat resistance, and large retardation. The retardation film of the present invention is composed primarily of an acrylic polymer. The film has an in-plane retardation of from 130 nm to 500 nm, inclusive, per 100 μm thickness at a wavelength of 589 nm. The film has a total light transmittance of not less than 85%. The retardation film has a glass transition temperature of preferably from 110° C. to 200° C., inclusive. The acrylic polymer, which is the primary component, preferably has a lactone ring structure.

摘要翻译： 本发明提供一种延迟膜，其主要由丙烯酸类聚合物组成，具有透明性，耐热性和较大延迟。 本发明的延迟膜主要由丙烯酸类聚合物构成。 该膜在589nm的波长下，每100μm厚度具有从130nm到500nm（包括端面）的面内延迟。 该膜具有不小于85％的总透光率。 延迟膜的玻璃化转变温度优选为110℃〜200℃。 作为主要成分的丙烯酸系聚合物优选具有内酯环结构。

公开(公告)号：US20060216263A1

公开(公告)日：2006-09-28

申请号：US11377422

申请日：2006-03-17

申请人： Takashi Miyai ,  Mitsuru Nakajima ,  Akio Naka

发明人： Takashi Miyai ,  Mitsuru Nakajima ,  Akio Naka

IPC分类号： A61K8/81

CPC分类号： A61K8/8176 ,  A61K8/41 ,  A61Q19/00 ,  C09D139/08

摘要： A polyvinylpyrrolidone composition in a form of a solid preparation or an aqueous solution, the composition including polyvinylpyrrolidone, ammonia, and a secondary amine, and processes for producing the polyvinylpyrrolidone composition, the first process including heat drying a polyvinylpyrrolidone aqueous solution containing ammonia and a secondary amine to obtain the polyvinylpyrrolidone in a form of a solid preparation, the second process including adding a secondary amine to an aqueous solution containing polyvinylpyrrolidone and ammonia to obtain the polyvinylpyrrolidone composition in a form of an aqueous solution, and the third process including polymerizing N-vinyl-2-pyrrolidone using hydrogen peroxide as a polymerization initiator in a presence of a metal catalyst using ammonia as a promoter in an aqueous medium to obtain the polyvinylpyrrolidone composition in a form of an aqueous solution.

摘要翻译： 一种固体制剂或水溶液形式的聚乙烯吡咯烷酮组合物，该组合物包括聚乙烯吡咯烷酮，氨和仲胺，以及制备聚乙烯吡咯烷酮组合物的方法，第一种方法包括将含有氨的聚乙烯吡咯烷酮水溶液和二级 胺，以获得固体制剂形式的聚乙烯吡咯烷酮，第二种方法包括在含有聚乙烯吡咯烷酮和氨的水溶液中加入仲胺，得到水溶液形式的聚乙烯吡咯烷酮组合物，第三种方法包括聚合N- 乙烯基-2-吡咯烷酮，使用过氧化氢作为聚合引发剂，在金属催化剂存在下，使用氨作为促进剂在水性介质中，得到水溶液形式的聚乙烯吡咯烷酮组合物。