摘要:
Deposition of a hard film of Ti-Si-N composite material on a substrate is carried out by using a source of evaporation possessing a composition of Ti.sub.a Si.sub.b (wherein "a" and "b" stand for atomic percentages respectively falling in the ranges of 75 at % .ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.25 at %, providing a+b=100 at %). Deposition is effected by a sputtering process or ion plating process in an atmosphere of an inert gas containing a nitrogen-containing reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of nitrogen is kept constant or varied continuously or stepwise. By this method there can be obtained a film having fine TiN crystalline particles uniformly dispersed in the matrix phase of Ti-Si amorphous metal or a film of functionally gradient structure in which the ratio of fine TiN crystalline particles dispersed in the matrix phase increases continuously or stepwise in the direction of thickness of the film.
摘要翻译:通过使用具有TiaSib组成的蒸发源(其中“a”和“b”表示分别落在75的范围内的原子百分比),将Ti-Si-N复合材料的硬膜沉积在基底上 at% = a = 85 at%和15 at% = b = 25 at%,提供+ b = 100 at%)。 在含有含氮反应气体的惰性气体的气氛中通过溅射法或离子镀法进行沉积,同时将反应气体的进料速率控制在室内,使得氮的分压保持恒定 或连续或逐步变化。 通过该方法可以获得均匀分散在Ti-Si非晶态金属的基体相中的细TiN结晶粒子的膜或其中分散在基体相中的细TiN结晶粒子的比例连续增加的功能梯度结构的膜,或 在膜的厚度方向上逐步地。
摘要:
A hard thin film having fine crystalline ceramic particles dispersed in a metallic matrix phase is disclosed. The production of the film is effected by first depositing a substantially amorphous film on a substrate and then heat-treating the deposited film. Deposition of the film on the substrate is carried out by using a source of evaporation having a composition represented by the general formula: Al.sub.a M.sub.b, wherein M stands for at least one element selected from the group consisting of Ti, Ta, V, Cr, Zr, Nb, Mo, Hf, W, Mn, Fe, Co, Ni, and Cu and "a" and "b" respectively stand for atomic % in the ranges of 60.ltoreq.a.ltoreq.98.5 and 1.5.ltoreq.b.ltoreq.40, providing a+b=100. Deposition is effected by a physical vapor deposition process in an atmosphere of an inert gas containing a reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of the react/on gas is kept constant or varied continuously or stepwise. By this method, there can be obtained a hard composite film having fine ceramic particles dispersed in a metallic matrix phase or a dense, hard, and composite film having a composition and structure obliquely varied from a substantially crystalline metallic phase to a crystalline ceramic phase in the direction of thickness of the film.
摘要翻译:公开了一种具有分散在金属基体相中的细晶体陶瓷颗粒的硬质薄膜。 通过首先在基板上沉积基本上非晶的膜然后对沉积的膜进行热处理来实现膜的制备。 通过使用具有由通式AlaMb表示的组成的蒸发源进行膜的沉积,其中M表示选自Ti,Ta,V,Cr,Zr中的至少一种元素 ,Nb,Mo,Hf,W,Mn,Fe,Co,Ni和Cu,“a”和“b”分别表示60≤a≤98.5的范围内的原子% b = 40,提供+ b = 100。 通过在包含反应气体的惰性气体的气氛中的物理气相沉积工艺进行沉积,同时将反应气体的进料速率控制在室内,使得反应/导入气体的分压保持恒定,或 连续或逐步变化。 通过该方法,可以获得具有分散在金属基体相中的细微陶瓷颗粒的硬质复合膜或致密的,硬的和复合的膜,其具有从基本上结晶的金属相到结晶陶瓷相倾斜变化的组成和结构 膜的厚度方向。
摘要:
A hard wear-resistant film is formed on a substrate in an atmosphere of an inert gas by using a target of a composition of Al.sub.a Ti.sub.b (wherein "a" and "b" stand for atomic percentages respectively in the ranges of 62 at %.ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.38 at %, providing a+b=100 at %) or Al.sub.c Ta.sub.d (wherein "c" and "d" stand for atomic percentages respectively in the ranges of 60 at %.ltoreq.c.ltoreq.80 at % and 20 at %.ltoreq.d.ltoreq.40 at %, providing c+d=100 at %) and by a sputtering process or ion plating process while varying continuously or stepwise the feed rate of a nitrogen-containing reaction gas into a chamber. The film consequently formed has a composition and structure thereof continuously or stepwise varied from a substantially amorphous metal of a part being in contact with the substrate to an (Al, Ti)N or (Al, Ta)N crystalline ceramic phase with the nitrogen content continuously or stepwise increased in the direction of the surface of the film.
摘要:
Deposition of a hard film of Ti--Si--N composite material on a substrate is carried out by using a source of evaporation possessing a composition of Ti.sub.a Si.sub.b (wherein "a" and "b" stand for atomic percentages respectively falling in the ranges of 75 at %.ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.25 at %, providing a+b=100 at %). Deposition is effected by a sputtering process or ion plating process in an atmosphere of an inert gas containing a nitrogen-containing reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of nitrogen is kept constant or varied continuously or stepwise. By this method, there can be obtained a film having fine TiN crystalline particles uniformly dispersed in the matrix phase of Ti--Si amorphous metal or a film of functionally gradient structure in which the ratio of fine TiN crystalline particles dispersed in the matrix phase increases continuously or stepwise in the direction of thickness of the film.
摘要翻译:通过使用具有TiaSib组成的蒸发源(其中“a”和“b”表示分别落在75的范围内的原子百分比),将Ti-Si-N复合材料的硬膜沉积在基板上 at% = a = 85 at%和15 at% = b = 25 at%,提供+ b = 100 at%)。 在含有含氮反应气体的惰性气体的气氛中通过溅射法或离子镀法进行沉积,同时将反应气体的进料速率控制在室内,使得氮的分压保持恒定 或连续或逐步变化。 通过该方法,可以得到均匀分散在Ti-Si非晶态金属的基体相中的细TiN结晶粒子的膜或功能梯度结构的膜,其中分散在基体相中的细TiN结晶粒子的比率连续增加 或者在薄膜的厚度方向上逐步。
摘要:
An aluminum-based alloy having the general formula Al.sub.x L.sub.y M.sub.z (wherein L is Mn or Cr; M is Ni, Co, and/or Cu; and x, y, and z, representing a composition ratio in atomic percentages, satisfy the relationships x+y+z=100, 75.ltoreq.x.ltoreq.95, 2.ltoreq.y.ltoreq.15, and 0.5.ltoreq.z.ltoreq.10) having a metallographic structure comprising a quasi-crystalline phase possesses high strength and high rigidity. In order to enhance the ductility and toughness of the aluminum-based alloy, the atomic percentage of M may be further limited to 0.5.ltoreq.z.ltoreq.4, and more preferably to 0.5.ltoreq.z.ltoreq.3. The aluminum-based alloy is useful as a structural material for aircraft, vehicles and ships, and for engine parts; as material for sashes, roofing materials, and exterior materials for use in construction; or as materials for use in marine equipment, nuclear reactors, and the like.
摘要:
Hard magnetic materials of the present invention contain at least one element of Fe, Co and Ni as a main component, at least one element M of Zr, Nb, Ta and Hf, at least one rare earth element R and B. The texture of the materials has at least 70% of fine crystalline phase having an average grain size of 100 nm or less, and the residue having an amorphous phase, the fine crystalline phase mainly composed of bcc-Fe or bcc-Fe compound, Fe--B compound and/or R.sub.2 Fe.sub.14 B.sub.1.
摘要:
An Fe-based soft magnetic alloy having a high saturated magnetic flux density and having a composition represented by formula (I) below: (Fe.sub.1-a Q.sub.a).sub.b B.sub.x T.sub.y T'.sub.z (I) wherein Q represents at least one element selected from the group consisting of Co and Ni; T represents at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Mo and W, with Zr and/or Hf being always included; T' represents at least one element selected from the group consisting of Cu, Ag, Au, Ni, Pd and Pt; a, b, x, y and z are real numbers satisfying relationships below: 0.ltoreq.a.ltoreq.0.05, 0.ltoreq.b.ltoreq.93 atomic %, 0.5.ltoreq.x.ltoreq.16 atomic %, 4.ltoreq.y.ltoreq.10 atomic %, 0.ltoreq.z.ltoreq.4.5 atomic % provided that when 0
摘要翻译:具有高饱和磁通密度且具有由下式(I)表示的组成的Fe基软磁合金:(Fe1-aQa)bBxTyT'z(I)其中Q表示选自以下的至少一种元素: Co和Ni; T表示选自Ti,Zr,Hf,V,Nb,Ta,Mo和W中的至少一种元素,其中始终包括Zr和/或Hf; T'表示选自Cu,Ag,Au,Ni,Pd和Pt中的至少一种元素; a,b,x,y和z是满足以下关系的实数:0 = a = 0.05,0
摘要:
A noise filter includes an annular magnetic core made of a soft magnetic alloy ribbon mainly made of Fe and containing B and at least one element selected from a group consisting of Ti, Zr, Hf, Nb, Ta, Mo and W, at least 50% of the soft magnetic alloy structure being composed of body-centered cubic structured fine grains having an average grain size of 30 nm or below, a casing for accommodating the magnetic core and having an insulating plate, a pair of coils separated from each other by the insulating plate, and an electronic circuit for connecting a core element made up of the magnetic core, the casing and the coils.
摘要:
The present invention relates to a method of stably manufacturing a Fe-base soft magnetic alloy having steps of subjecting an amorphous alloy mainly composed of Fe to heat treatment in which the amorphous alloy is heated to 400.degree. to 750.degree. C. at a heating rate of 1.0.degree. C./minute or higher so that at least 50% or more of the structure of the amorphous alloy is made of fine crystalline grains formed into a body-centered cubic structure and having an average grain size of crystal of 30 nm or smaller as to have a high magnetic permeability and saturation magnetic flux density.
摘要:
The present invention provides a sacrificial electrode material which consists of a single phase amorphous structure or a structure consisting of an amorphous phase and a crystalline solid solution phase and provides electrochemical corrosion protection to metallic articles exposed to an aqueous electrolytic solution. The electrode material is prepared by rapidly quenching a magnesium-based alloy material from the liquid phase or vapor phase thereof, the magnesium-based alloy material consisting the general formula: Mg.sub.bal X1.sub.a X2.sub.b or Mg.sub.bal X1.sub.a, wherein X1 is at least one element selected from the group consisting of Al, Zn, Ga, Ca and In; X2 is at least one element selected from the group consisting of Mm (misch metal), Y and rare earth metal elements; a and b are, in atomic percentages, 5.0.ltoreq.a.ltoreq.35.0 and 3.0.ltoreq.b.ltoreq.25.0, respectively. The magnesium-based alloy material may further contain one or more transition metal elements in their total contents not exceeding 1.0 atomic %.