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    Alcohol substituted amides as chain extenders for polyurethanes
    1.
    发明授权
    Alcohol substituted amides as chain extenders for polyurethanes 失效
    醇取代的酰胺作为聚氨酯的增链剂

    公开(公告)号：US4448905A

    公开(公告)日：1984-05-15

    申请号：US430573

    申请日：1982-09-30

    申请人： I. Sioun Lin ,  Stanley J. Gromelski, Jr. ,  Eugene V. Hort ,  Lowell R. Anderson ,  Earl P. Williams

    发明人： I. Sioun Lin ,  Stanley J. Gromelski, Jr. ,  Eugene V. Hort ,  Lowell R. Anderson ,  Earl P. Williams

    IPC分类号： C08G18/00 ,  C07C67/00 ,  C07C231/00 ,  C07C231/10 ,  C07C235/08 ,  C07C235/10 ,  C08G18/10 ,  C08G18/65 ,  C08G18/72

    CPC分类号： C08G18/10

    摘要： This invention relates to the reaction products of butyrolactone and an aliphatic amine utilizable as a chain extender and curing agent for castable polyurethanes and to the process employing said products in preparing castable polyurethane elastomers and to the process for preparing the butyrolactone amine adducts. The aliphatic amine reactants employed in preparing the butyrolactoneamine adducts are defined by the formula: ##STR1## wherein X is amino (--NH.sub.2) or hydroxy (--OH); R is hydrogen (--H) or methyl (--CH.sub.3) and n has a value of 1 to 2, which amines are reacted with butyrolactone in a mole ratio of between about 1:1 and about 1:3 to provide a curing agent having superior mechanical properties and having the formula: ##STR2## wherein R is hydrogen or methyl, R' is a hydroxy group or ##STR3## and n has a value of 1 or 2.

    摘要翻译： 本发明涉及可用作扩链剂的丁内酯和脂族胺的反应产物和用于可浇注聚氨酯的固化剂以及使用所述产品制备可浇注聚氨酯弹性体的方法以及制备丁内酯胺加合物的方法。 用于制备丁内酯加合物的脂族胺反应物由下式定义：其中X是氨基（-NH 2）或羟基（-OH）; R为氢（-H）或甲基（-CH 3），n为1至2，胺与丁内酯的摩尔比在约1:1至约1:3之间进行反应以提供具有 优异的机械性能并具有下式：其中R是氢或甲基，R'是羟基或者“IMAGE”，n的值是1或2。

    Diamine/diol chain extender blends for rim process
    2.
    发明授权
    Diamine/diol chain extender blends for rim process 失效
    用于轮辋加工的二胺/二醇增链剂共混物

    公开(公告)号：US4549007A

    公开(公告)日：1985-10-22

    申请号：US672211

    申请日：1984-11-16

    申请人： I. Sioun Lin ,  Stanley J. Gromelski, Jr. ,  Jesse Werner ,  Michael J. Brown ,  Paritosh M. Chakrabarti

    发明人： I. Sioun Lin ,  Stanley J. Gromelski, Jr. ,  Jesse Werner ,  Michael J. Brown ,  Paritosh M. Chakrabarti

    IPC分类号： C08G18/32 ,  C08G18/38 ,  C08G18/65 ,  C08G18/14

    CPC分类号： C08G18/3814 ,  C08G18/32 ,  C08G18/3821 ,  C08G18/3838 ,  C08G18/384 ,  C08G18/6529

    摘要： A chain extending agent for reaction injection molding (RIM) comprising a normally liquid blend of butanediol and a toluene diamine mono-substituted with an electron withdrawing group and having the formula ##STR1## wherein X is vicinal to an amino radical and is selected from the group of halogen, CN, NO.sub.2, acyl, carboxylate and isomeric mixtures thereof, and wherein the butanediol and diamine are combined in a critical mole ratio of from 4:1 to about 19:1. The above blend is particularly useful in the preparation of large moldings of polyurethane-polyurea elastomer by the RIM or RRIM (reinforced reaction injection molding) process wherein instant preformed blend is added to a mixture of polyol reactant and catalyst before polymerization in the mold with isocyanate to produce a urethane/urea polymer product of improved properties. Accordingly, the invention also concerns an enhanced RIM or RRIM process and improved product by the use of a mixture of the present chain extender blend and polyol reactant maintainable in the liquid state at ambient temperature.

    摘要翻译： 一种用于反应注射成型的链增长剂（RIM），其包含丁二醇的正常液体共混物和用吸电子基团单取代的具有式“IMAGE”的甲苯二胺，其中X与氨基相邻，并且选自 卤素，CN，NO 2，酰基，羧酸酯和其异构体混合物，其中丁二醇和二胺以4:1至约19:1的临界摩尔比组合。 上述共混物特别可用于通过RIM或RRIM（增强反应注射成型）方法制备聚氨酯 - 聚脲弹性体的大型模制品，其中在模具中与异氰酸酯聚合之前将即时预制混合物加入到多元醇反应物和催化剂的混合物中 以产生具有改进性能的氨基甲酸酯/脲聚合物产品。 因此，本发明还涉及通过使用本发明的增链剂共混物和在环境温度下保持液态的多元醇反应物的混合物来增强RIM或RRIM方法和改进的产品。

    Diamine/diol chain extender blends for rim process
    4.
    发明授权
    Diamine/diol chain extender blends for rim process 失效
    用于轮辋加工的二胺/二醇增链剂共混物

    公开(公告)号：US4523004A

    公开(公告)日：1985-06-11

    申请号：US506250

    申请日：1983-06-23

    申请人： I. Sioun Lin ,  Stanley J. Gromelski, Jr. ,  Jesse Werner ,  Michael J. Brown ,  Paritosh M. Chakrabarti

    发明人： I. Sioun Lin ,  Stanley J. Gromelski, Jr. ,  Jesse Werner ,  Michael J. Brown ,  Paritosh M. Chakrabarti

    IPC分类号： C08G18/32 ,  C08G18/38 ,  C08G18/65 ,  B29H7/20 ,  C08G18/14

    CPC分类号： C08G18/3814 ,  C08G18/32 ,  C08G18/3821 ,  C08G18/3838 ,  C08G18/384 ,  C08G18/6529

    摘要： A chain extending agent for reaction injection molding (RIM) comprising a normally liquid blend of butanediol and a toluene diamine mono-substituted with an electron withdrawing group and having the formula ##STR1## wherein X is vicinal to an amino radical and is selected from the group of halogen, CN, NO.sub.2, acyl, carboxylate and isomeric mixtures thereof, and wherein the butanediol and diamine are combined in a critical mole ratio of from 4:1 to about 19:1. The above blend is particularly useful in the preparation of large moldings of polyurethane-polyurea elastomer by the RIM or RRIM (reinforced reaction injection molding) process wherein instant preformed blend is added to a mixture of polyol reactant and catalyst before polymerization in the mold with isocyanate to produce a urethane/urea polymer product of improved properties. Accordingly, the intention also concerns an enhanced RIM or RRIM process and improved product by the use of a mixture of the present chain extender blend and polyol reactant maintainable in the liquid state at ambient temperature.

    摘要翻译： 一种用于反应注射成型的链增长剂（RIM），其包含丁二醇的正常液体共混物和用吸电子基团单取代的具有式“IMAGE”的甲苯二胺，其中X与氨基相邻，并且选自 卤素，CN，NO 2，酰基，羧酸酯和其异构体混合物，其中丁二醇和二胺以约4:1至约19:1的临界摩尔比组合。 上述共混物特别可用于通过RIM或RRIM（增强反应注射成型）方法制备聚氨酯 - 聚脲弹性体的大型模制品，其中在模具中与异氰酸酯聚合之前将即时预制混合物加入到多元醇反应物和催化剂的混合物中 以产生具有改进性能的氨基甲酸酯/脲聚合物产品。 因此，该意图还涉及通过使用在环境温度下保持液态的本发明扩链剂混合物和多元醇反应物的混合物来增强RIM或RRIM方法和改进的产物。

    Low molecular weight hair spray
    5.
    发明授权
    Low molecular weight hair spray 失效
    低分子量发胶

    公开(公告)号：US4567035A

    公开(公告)日：1986-01-28

    申请号：US525357

    申请日：1983-08-22

    申请人： Burton H. Waxman ,  I. Sioun Lin

    发明人： Burton H. Waxman ,  I. Sioun Lin

    IPC分类号： C08F22/00 ,  A61K8/04 ,  A61K8/81 ,  A61Q5/06 ,  C08F22/10 ,  C08F218/00 ,  C08F218/02 ,  C08F218/04 ,  C08F222/10 ,  A61K7/11 ,  A61K31/74

    CPC分类号： A61Q5/06 ,  A61K8/046 ,  A61K8/8164 ,  Y10S424/01

    摘要： A low molecular weight hair spray resin containing a vinyl monomer having a ##STR1## electron withdrawing group and consisting essentially of alternating units of vinyl ester and an alkyl half ester maleate derived from an alternating vinyl ester/maleic anhydride copolymer. The resins of this invention are defined by the structure: ##STR2## wherein R and R.sub.1 are each independently alkyl having from 1 to 6 carbon atoms and n has a value between about 40 and 250, preferably 60 to 220.

    摘要翻译： 含有具有吸电子基团的乙烯基单体并且基本上由乙烯基酯和由交替的乙烯基酯/马来酸酐共聚物衍生的马来酸烷基酯的交替单元组成的低分子量发胶树脂。 本发明的树脂由以下结构定义：其中R和R 1各自独立地为具有1至6个碳原子的烷基，n具有约40至250，优选60至220的值。