公开(公告)号：US5747594A

公开(公告)日：1998-05-05

申请号：US788981

申请日：1997-01-27

申请人： Jacquelyn A. deGroot ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Seema V. Karande ,  Laura K. Mergenhagen ,  Dan G. Moldovan ,  Kenneth B. Stewart ,  Nicole F. Whiteman

发明人： Jacquelyn A. deGroot ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Seema V. Karande ,  Laura K. Mergenhagen ,  Dan G. Moldovan ,  Kenneth B. Stewart ,  Nicole F. Whiteman

IPC分类号： B65D81/34 ,  B29C47/00 ,  B29K23/00 ,  B29L9/00 ,  B32B27/32 ,  B65D1/00 ,  B65D65/40 ,  C08F110/02 ,  C08F210/08 ,  C08F210/16 ,  C08J5/18 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08L23/16 ,  C09J123/08

CPC分类号： C08L23/06 ,  B29C47/0004 ,  B29C47/0021 ,  B29C47/0026 ,  B32B27/32 ,  B32B27/322 ,  C08J5/18 ,  C08L23/0815 ,  C09J123/0815 ,  C08F110/02 ,  C08F210/16 ,  C08J2323/04 ,  C08J2323/08 ,  C08L2205/02 ,  C08L2314/06 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/1393 ,  Y10T428/1397 ,  Y10T428/24992 ,  Y10T428/2826 ,  Y10T428/31913

摘要： The subject invention provides a polymer mixture having high heat resistivity, low hexane extractive and controllably lower or higher modulus. The mixture is comprised of at least one first substantially linear ethylene polymer, Component (A), and at least one second ethylene polymer which is a homogeneously branched polymer, heterogeneously branched linear polymer or a non-short chain branched linear polymer. When fabricated into film, the mixture is characterized by a heat seal initiation temperature which is substantially lower than its Vicat softening point as well as a high ultimate hot tack strength. When fabricated as a molded article, the mixture is characterized by high microwave warp distortion while maintaining a lower modulus. The polymer mixture is particularly well-suited for use in multilayer film structures as a sealant layer for such applications as cook-in packages, hot-fill packages, and barrier shrink films. In molding applications, the mixture is well-suited as freezer-to-microwave food storage containers and lids which maintain good flexibility at low temperature to allow easy openability of such containers.

公开(公告)号：US5792534A

公开(公告)日：1998-08-11

申请号：US475953

申请日：1995-06-07

申请人： Jacquelyn A. deGroot ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Seema V. Karande ,  Laura K. Mergenhagen ,  Dan G. Moldovan ,  Kenneth B. Stewart ,  Nicole F. Whiteman

发明人： Jacquelyn A. deGroot ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Seema V. Karande ,  Laura K. Mergenhagen ,  Dan G. Moldovan ,  Kenneth B. Stewart ,  Nicole F. Whiteman

IPC分类号： B65D81/34 ,  B29C47/00 ,  B29K23/00 ,  B29L9/00 ,  B32B27/32 ,  B65D1/00 ,  B65D65/40 ,  C08F110/02 ,  C08F210/08 ,  C08F210/16 ,  C08J5/18 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08L23/16 ,  C09J123/08

CPC分类号： C08L23/06 ,  B29C47/0004 ,  B29C47/0021 ,  B29C47/0026 ,  B32B27/32 ,  B32B27/322 ,  C08J5/18 ,  C08L23/0815 ,  C09J123/0815 ,  C08F110/02 ,  C08F210/16 ,  C08J2323/04 ,  C08J2323/08 ,  C08L2205/02 ,  C08L2314/06 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/1393 ,  Y10T428/1397 ,  Y10T428/24992 ,  Y10T428/2826 ,  Y10T428/31913

摘要： The subject invention provides a polymer mixture having high heat resistivity, low hexane extractive and controllably lower or higher modulus. The mixture is comprised of at least one first substantially linear ethylene polymer, Component (A), and at least one second ethylene polymer which is a homogeneously branched polymer, heterogeneously branched linear polymer or a non-short chain branched linear polymer. When fabricated into film, the mixture is characterized by a heat seal initiation temperature which is substantially lower than its Vicat softening point as well as a high ultimate hot tack strength. When fabricated as a molded article, the mixture is characterized by high microwave warp distortion while maintaining a lower modulus. The polymer mixture is particularly well-suited for use in multilayer film structures as a sealant layer for such applications as cook-in packages, hot-fill packages, and barrier shrink films. In molding applications, the mixture is well-suited as freezer-to-microwave food storage containers and lids which maintain good flexibility at low temperature to allow easy openability of such containers.

摘要翻译： 本发明提供了具有高耐热性，低己烷萃取和可控地更低或更高模量的聚合物混合物。 该混合物由至少一种第一基本上线性的乙烯聚合物，组分（A）和至少一种第二乙烯聚合物组成，其是均匀支化的聚合物，非均匀支化的线性聚合物或非短链支化的线型聚合物。 当制成膜时，混合物的特征在于热封起始温度明显低于其维卡软化点以及高极限热粘性强度。 当制造成模制品时，混合物的特征在于高的微波翘曲变形，同时保持较低的模量。 聚合物混合物特别适合用于多层膜结构，作为诸如煮熟包装，热填充包装和阻挡收缩膜之类的应用的密封剂层。 在成型应用中，该混合物非常适合作为冷冻至微波食品储存容器和盖子，其在低温下保持良好的柔韧性，以允许这种容器容易打开。

公开(公告)号：US5773106A

公开(公告)日：1998-06-30

申请号：US487819

申请日：1995-06-07

申请人： Jacquelyn A. deGroot ,  Pradeep Jain ,  Lonnie G. Hazlitt ,  Seema V. Karande ,  Laura K. Mergenhagen ,  Dan G. Moldovan ,  Kenneth B. Stewart ,  Nicole F. Whiteman

发明人： Jacquelyn A. deGroot ,  Pradeep Jain ,  Lonnie G. Hazlitt ,  Seema V. Karande ,  Laura K. Mergenhagen ,  Dan G. Moldovan ,  Kenneth B. Stewart ,  Nicole F. Whiteman

IPC分类号： B65D81/34 ,  B29C47/00 ,  B29K23/00 ,  B29L9/00 ,  B32B27/32 ,  B65D1/00 ,  B65D65/40 ,  C08F110/02 ,  C08F210/08 ,  C08F210/16 ,  C08J5/18 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08L23/16 ,  C09J123/08 ,  B29D31/00

CPC分类号： C08L23/06 ,  B29C47/0004 ,  B29C47/0021 ,  B29C47/0026 ,  B32B27/32 ,  B32B27/322 ,  C08J5/18 ,  C08L23/0815 ,  C09J123/0815 ,  C08F110/02 ,  C08F210/16 ,  C08J2323/04 ,  C08J2323/08 ,  C08L2205/02 ,  C08L2314/06 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/1393 ,  Y10T428/1397 ,  Y10T428/24992 ,  Y10T428/2826 ,  Y10T428/31913

摘要： The subject invention provides a polymer mixture having high heat resistivity, low hexane extractive and controllably lower or higher modulus. The mixture is comprised of at least one first substantially linear ethylene polymer, Component (A), and at least one second ethylene polymer which is a homogeneously branched polymer, heterogeneously branched linear polymer or a non-short chain branched linear polymer. When fabricated into film, the mixture is characterized by a heat seal initiation temperature which is substantially lower than its Vicat softening point as well as a high ultimate hot tack strength. When fabricated as a molded article, the mixture is characterized by high microwave warp distortion while maintaining a lower modulus. The polymer mixture is particularly well-suited for use in multilayer film structures as a sealant layer for such applications as cook-in packages, hot-fill packages, and barrier shrink films. In molding applications, the mixture is well-suited as freezer-to-microwave food storage containers and lids which maintain good flexibility at low temperature to allow easy openability of such containers.

摘要翻译： 本发明提供了具有高耐热性，低己烷萃取和可控地更低或更高模量的聚合物混合物。 该混合物由至少一种第一基本上线性的乙烯聚合物，组分（A）和至少一种第二乙烯聚合物组成，其是均匀支化的聚合物，非均匀支化的线性聚合物或非短链支化的线型聚合物。 当制成膜时，混合物的特征在于热封起始温度明显低于其维卡软化点以及高极限热粘性强度。 当制造成模制品时，混合物的特征在于高的微波翘曲变形，同时保持较低的模量。 聚合物混合物特别适合用于多层膜结构，作为诸如煮熟包装，热填充包装和阻挡收缩膜之类的应用的密封剂层。 在成型应用中，该混合物非常适合作为冷冻至微波食品储存容器和盖子，其在低温下保持良好的柔韧性，以允许这种容器容易打开。

公开(公告)号：US06982311B2

公开(公告)日：2006-01-03

申请号：US10210139

申请日：2002-07-31

申请人： Seema V. Karande ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kaelyn Koch ,  Shih-Yaw Lai ,  Li-Min Tau

发明人： Seema V. Karande ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kaelyn Koch ,  Shih-Yaw Lai ,  Li-Min Tau

IPC分类号： C08F210/16

CPC分类号： B32B27/32 ,  B32B2323/046 ,  B32B2323/10 ,  B32B2369/00 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L101/00 ,  C08L2314/06 ,  Y10T428/24 ,  Y10T428/269 ,  C08L2666/04

摘要： The subject invention provides a film having at least one layer comprising an interpolymer of ethylene and at least on comonomer selected from the group consisting of C3-C20 α-olefins, dienes, and cycloalkenes, wherein the interpolymer is characterized as having a high degree of processability, good optical performance, and good mechanical properties. The subject invention further provides film fabrication processes and polymer compositions which are useful in preparing the subject films.

摘要翻译： 本发明提供一种膜，其具有至少一层，其包含乙烯和至少一种选自C 3 -C 20α-烯烃的共聚单体的互聚物， 二烯和环烯烃，其中互聚物的特征在于具有高加工性，良好的光学性能和良好的机械性能。 本发明还提供了可用于制备本发明膜的膜制造方法和聚合物组合物。

公开(公告)号：US06486284B1

公开(公告)日：2002-11-26

申请号：US09485801

申请日：2000-05-08

申请人： Seema V. Karande ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kaelyn Koch ,  Shih-Yaw Lai ,  Li-Min Tau

发明人： Seema V. Karande ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kaelyn Koch ,  Shih-Yaw Lai ,  Li-Min Tau

IPC分类号： C08F21016

CPC分类号： B32B27/32 ,  B32B2323/046 ,  B32B2323/10 ,  B32B2369/00 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L101/00 ,  C08L2314/06 ,  Y10T428/24 ,  Y10T428/269 ,  C08L2666/04

摘要： The subject invention provides a film having at least one layer comprising an interpolymer of ethylene and at least one comonomer selected from the group consisting of C3-C20 &agr;-olefins, dienes, and cycloalkenes, wherein the interpolymer is characteried as having a high degree of processability good optical performance, and good mechanical properties. The subject invention further provides film fabrication processes and polymer compositions which are useful in preparing the subject films.

摘要翻译： 本发明提供了一种膜，其具有包含乙烯和至少一种选自C 3 -C 20α-烯烃，二烯和环烯烃的共聚单体的互聚物的至少一层，其中所述互聚物的特征在于具有高度 加工性好的光学性能，以及良好的机械性能。 本发明还提供了可用于制备本发明膜的膜制造方法和聚合物组合物。

公开(公告)号：US06469103B1

公开(公告)日：2002-10-22

申请号：US09156948

申请日：1998-09-18

申请人： Pradeep Jain ,  Lonnie G. Hazlitt ,  Jacquelyn A. deGroot ,  Kenneth W. Anderson

发明人： Pradeep Jain ,  Lonnie G. Hazlitt ,  Jacquelyn A. deGroot ,  Kenneth W. Anderson

IPC分类号： C08L2306

CPC分类号： C08L23/0815 ,  C08F210/16 ,  C08L2205/02 ,  C08L2308/00 ,  C08L2314/06 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/26 ,  C08F2/001

摘要： The present invention pertains to an ethylene interpolymer composition characterized as having a narrow molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a composition and a fabricated article made from such composition. The novel composition is characterized as having at least two polymer components, the first component having an ATREF peak temperature, Tpeak1 and a viscosity average molecular weight, Mv1, and the second component having an ATREF peak temperature, Tpeak2, and a viscosity average molecular, Mv2, wherein the temperature differential between Tpeak2 and Tpeak1 decreases with increased composition density and Mv1/Mv2 is less than or equal to 1.2. The novel composition is further characterized as having a Mw/Mn of less than or equal to 3.3 as determined by gel permeation chromatography, an I10/I2>6.6, and a composition density less than 0.945 gram/cubic centimeter. The novel composition exhibits high, balanced toughness properties, good processibility and surprisingly improved optical properties and is particularly well-suited for use in applications such as lamination films trash can liners and heavy duty shipping bags, especially as a blown film.

摘要翻译： 本发明涉及具有窄分子量分布（MWD）和优化组合均匀性的乙烯互聚物组合物，制备这种组合物的方法和由这种组合物制成的制造制品。 该新型组合物的特征在于具有至少两种聚合物组分，第一组分具有ATREF峰温度，Tpeak1和粘均分子量Mv1，第二组分具有ATREF峰温度Tpeak2和粘均分子， Mv2，其中Tpeak2和Tpeak1之间的温差随着组成密度的增加而降低，Mv1 / Mv2小于或等于1.2。 该新型组合物的特征还在于通过凝胶渗透色谱法测定的Mw / Mn小于或等于3.3，I10 / I2> 6.6，组成密度小于0.945克/立方厘米。 该新型组合物显示出高的平衡的韧性，良好的加工性和令人惊奇的改进的光学性能，特别适用于诸如层压膜垃圾桶衬里和重型运输袋，特别是作为吹塑薄膜的应用。

公开(公告)号：US06908968B2

公开(公告)日：2005-06-21

申请号：US10764776

申请日：2004-01-26

申请人： Pradeep Jain ,  Lonnie G. Hazlitt ,  Jacquelyn A. deGroot ,  Kenneth W. Anderson

发明人： Pradeep Jain ,  Lonnie G. Hazlitt ,  Jacquelyn A. deGroot ,  Kenneth W. Anderson

IPC分类号： B65D30/02 ,  B32B27/32 ,  C08F2/00 ,  C08F2/01 ,  C08F4/60 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/70 ,  C08F210/02 ,  C08F210/16 ,  C08J5/18 ,  C08L23/08 ,  C08L23/06 ,  C08F4/44 ,  C08F110/02

CPC分类号： C08L23/0815 ,  C08F210/16 ,  C08L2205/02 ,  C08L2308/00 ,  C08L2314/06 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/26 ,  C08F2/001

摘要： A polymer composition comprises at least two polymer components, the first component having an ATREF peak temperature, Tpeak1, and a viscosity average molecular weight, Mv1, and the second component having an ATREF peak temperature, Tpeak2, and a viscosity average molecular weight, Mv2, wherein the temperature differential between Tpeak2 and Tpeak1 decreases with increased composition density and Mv1/Mv2 is less than or equal to 1.2. the composition is further characterized as having a Mw/Mn of less than or equal to 3.3, an I10/I2>6.6, and a composition density less than 0.945 gram/cubic centimeter.

摘要翻译： 聚合物组合物包含至少两种聚合物组分，第一组分具有ATREF峰温度T max 1和粘度平均分子量M 1 v 1，并且第二组分 具有ATREF峰值温度T 2峰2和粘度平均分子量M 2 V 2，其中T 2峰2和T 2之间的温差， SUB> peak1 随着组成密度的增加而降低，并且M 1/2 / M 2 V 2小于或等于1.2。 该组合物进一步被表征为具有小于或等于3.3的M

公开(公告)号：US06683149B2

公开(公告)日：2004-01-27

申请号：US10247025

申请日：2002-09-19

申请人： Pradeep Jain ,  Lonnie G. Hazlitt ,  Jacquelyn A. deGroot ,  Kenneth W. Anderson

发明人： Pradeep Jain ,  Lonnie G. Hazlitt ,  Jacquelyn A. deGroot ,  Kenneth W. Anderson

IPC分类号： C08F11002

CPC分类号： C08L23/0815 ,  C08F210/16 ,  C08L2205/02 ,  C08L2308/00 ,  C08L2314/06 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/26 ,  C08F2/001

摘要： The present invention pertains to an ethylene interpolymer composition characterized as having a narrow molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a composition and a fabricated article made from such composition. The novel composition is characterized as having at least two polymer components, the first component having an ATREF peak temperature, Tpeak1 and a viscosity average molecular weight, Mv1, and the second component having an ATREF peak temperature, Tpeak2, and a viscosity average molecular, Mv2, wherein the temperature differential between Tpeak2 and Tpeak1 decreases with iincreased composition density and Mv1/Mv2 is less than or equal to 1.2. The novel composition exhibits high, balanced toughness properties, good processibility and surprisingly improved optical properties and is particularly well-suited for use in applications such as lamination films trash can liners and heavy duty shipping bags, especially as a blown film.

摘要翻译： 本发明涉及具有窄分子量分布（MWD）和优化组合均匀性的乙烯互聚物组合物，制备这种组合物的方法和由这种组合物制成的制造制品。 该新型组合物的特征在于具有至少两种聚合物组分，第一组分具有ATREF峰温度，Tpeak1和粘均分子量Mv1，第二组分具有ATREF峰温度Tpeak2和粘均分子， Mv2，其中Tpeak2和Tpeak1之间的温差随着组合物浓度的增加而降低，Mv1 / Mv2小于或等于1.2。 该新型组合物显示出高的平衡的韧性，良好的加工性和令人惊奇的改进的光学性能，特别适用于诸如层压膜垃圾桶衬里和重型运输袋，特别是作为吹塑薄膜的应用。

公开(公告)号：US06451916B1

公开(公告)日：2002-09-17

申请号：US09943853

申请日：2001-08-31

申请人： Kenneth W. Anderson ,  Pak-Wing S. Chum ,  David A. Eversdyk ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kalyan Sehanobish ,  Li-Min Tau

发明人： Kenneth W. Anderson ,  Pak-Wing S. Chum ,  David A. Eversdyk ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kalyan Sehanobish ,  Li-Min Tau

IPC分类号： C08F800

CPC分类号： B01J8/0015 ,  B01J19/2435 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/04 ,  C08L2205/02 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08F2/001 ,  C08L2666/04 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F210/14

摘要： The present invention pertains to a continuous process and polymerization system characterized by separate injection of catalyst and make-up feed, an ethylene interpolymer composition characterized as having broad molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a composition and a fabricated article made from such composition. The novel composition is characterized as having a melt flow ratio, I10/I2, from 8 to 30, a Mw/Mn of greater than 4 as determined by gel permeation chromatography, a melt index, I2, from 0.01 to 1000 grams/10 minutes, preferably greater that 0.1 to 10 grams/10 minutes, and a density less than 0.945 g/cm3. The novel composition exhibits good processibility and improved toughness properties, especially excellent film tear and impact resistance, and is particularly well-suited for use in applications such as high performance trash can liners and heavy duty shipping bags.

摘要翻译： 本发明涉及连续工艺和聚合体系，其特征在于分别注入催化剂和补充进料，特征在于具有宽分子量分布（MWD）和优化的组成均匀性的乙烯互聚物组合物，制备这种组合物的方法和 由这种组合物制成的制成品。 该新型组合物的特征在于具有通过凝胶渗透色谱法测定的熔体流动比I10 / I2，8至30，Mw / Mn大于4，熔体指数I 2为0.01至1000克/ 10分钟 ，优选为0.1〜10克/ 10分钟，密度小于0.945g / cm 3。 该新型组合物显示出良好的加工性和改进的韧性，特别优异的膜撕裂和抗冲击性，并且特别适合用于高性能垃圾桶衬里和重型运输袋等应用中。

公开(公告)号：US06319989B1

公开(公告)日：2001-11-20

申请号：US09463207

申请日：2000-01-20

申请人： Kenneth W. Anderson ,  Pak-Wing S. Chum ,  David A. Eversdyk ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kalyan Sehanobish ,  Li-Min Tau

发明人： Kenneth W. Anderson ,  Pak-Wing S. Chum ,  David A. Eversdyk ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kalyan Sehanobish ,  Li-Min Tau

IPC分类号： C08F800

CPC分类号： C08J5/18 ,  B01J8/0015 ,  B01J19/2435 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08J2323/08 ,  C08L23/04 ,  C08L2205/02 ,  C08F2/001 ,  C08L2666/04 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F210/14

摘要： The present invention pertains to a continuous process and polymerization system characterized by separate injection of catalyst and make-up feed, an ethylene interpolymer composition characterized as having broad molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a compostion and a fabricated article made from such composition. The novel composition is characterized as having a melt flow ratio, I10/I2, from 8 to 30, a Mw/Mn of greater than 4 as determined by gel permeation chromatography, a melt index, I2, from 0.01 to 1000 grams/10 minutes, preferably greater that 0.1 to 10 grams/10 minutes, and a density less than 0.945 g/cm3. The novel composition exhibits good processibility and improved toughness properties, especially excellent film tear and impact resistance, and is particularly well-suited for use in applications such as high performance trash can liners and heavy duty shipping bags.

摘要翻译： 本发明涉及连续工艺和聚合体系，其特征在于分别注入催化剂和补充进料，特征在于具有宽分子量分布（MWD）和优化的组成均匀性的乙烯互聚物组合物，制备这种组合物的方法和 由这种组合物制成的制成品。 该新型组合物的特征在于具有通过凝胶渗透色谱法测定的熔体流动比I10 / I2，8至30，Mw / Mn大于4，熔体指数I 2为0.01至1000克/ 10分钟 ，优选为0.1〜10克/ 10分钟，密度小于0.945g / cm 3。 该新型组合物显示出良好的加工性和改进的韧性，特别优异的膜撕裂和抗冲击性，并且特别适合用于高性能垃圾桶衬里和重型运输袋等应用中。