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公开(公告)号：US4014831A
公开(公告)日：1977-03-29
申请号：US579496
申请日：1975-05-21
申请人： Jan Bock , Neville G. Thame , Lowell Westerman
发明人： Jan Bock , Neville G. Thame , Lowell Westerman
IPC分类号： C08L23/00 , C08F8/00 , C08F8/44 , C08K3/00 , C08K3/22 , C08K5/00 , C08K5/05 , C08K5/09 , C08K5/17 , C08K5/19 , C08L23/26 , C08L25/00 , C08L101/00 , C08L101/02 , C08F8/42
CPC分类号： C08F8/44
摘要： The instant invention relates to a method for making processable ionic polymer compositions which are characterized as being processable at high temperatures, for example, 200.degree. C, while retaining adequate physical properties at both room temperatures and elevated temperatures which are below the processing temperature, for example, up to 100.degree. C and more. In this method, an ionic polymer comprising an elastomeric or plastic backbone and pendant acid groups is combined with a first neutralizing agent having two components. One component of said neutralizing agent is a metal or ammonium type moiety which combines with the pendant acid groups as a metal or ammonium salt thereof; the other component of neutralizing agent takes up the hydrogen ion present in the pendant acid groups and is converted into a preferential plasticizer for said ionomer. The preferential plasticizer acts to disrupt the ionic association of the metal or ammonium salt groups, thus allowing the ionic polymer to act as a noncrosslinked material. When the composition is in this state, it can be compounded with oils, fillers, etc. An ionic composition in this state is also characterized as having poor physical properties, for example, tensile strength, and excellent processing characteristics, e.g., low viscosity at elevated temperatures. This neutralized composition is then contacted with a second neutralizing agent which acts to substantially convert said preferential plasticizer to a higher melting species, for example, a salt. The composition, after the second neutralizing step, is then characterized as having the desired properties, for example, excellent physical properties at room temperature and up to 100.degree. C and more than adequate processability at temperatures of from 200.degree. C and above. Preferably, the ionic polymer is an ionic elastomer having from 0.2 to 25 mole % pendant acid groups, for example, carboxylic, phosphonic and sulfonic acid groups. Preferably, the pendant acid groups are sulfonic acid groups.The first neutralizing agent is preferably selected from the group consisting of metal salts of fatty acids wherein said metal is selected from Groups IA, IIA, IIB, IIA, Al and Pb of the Periodic Table of the Elements or ammonium salts of fatty acids said ammonium moiety has the general formula R.sub.4 N wherein R is selected from the group consisting of hydrogen and lower alkyl, e.g., methyl and ethyl, more preferably hydrogen radicals.The second neutralizing agent is preferably selected from the group consisting of Group IA, IIA and IIB derivatives of lower organic acids, for example, from 1 to 4 carbon atoms and their hydroxides. Preferably, the first neutralizing agent is combined with said ionic polymer at from 0.5 equivalents/equivalent of acid to 5 equivalents/equivalent acid and more preferably from 1 equivalent/equivalent acid to 3 equivalents/equivalent acid and said second neutralizing agent is combined with said ionic polymer preferably at from 0.25 equivalent/equivalent acid to 3 equivalents/equivalent acid, and more preferably between 0.75 equivalent/equivalent acid and 3 equivalents/equivalent acid.
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公开(公告)号：US4220573A
公开(公告)日：1980-09-02
申请号：US2787
申请日：1979-01-11
申请人： Jan Bock , Neville G. Thame , Lowell Westerman
发明人： Jan Bock , Neville G. Thame , Lowell Westerman
CPC分类号： C08K5/09
摘要： The instant invention relates to unique and novel ionic polymer compositions which are characterized as being processable at high temperatures, for example, 200.degree. C., while retaining adequate physical properties at both room temperature and elevated temperatures which are below the processing temperature. The ionic polymer compositions include a metal neutralized sulfonated polymer which is plasticized with a preferential plasticizer, at a concentration level of about at least 7 parts by weight per 100 parts of the metal neutralized sulfonated polymer. The preferential plasticizer acts to disrupt the ionic association of the metal or ammonium salt groups of the neutralized sulfonated polymer, thus allowing the ionic polymer to act as a noncrosslinked material at the processing temperature. When the composition is in this state, it can be compounded with oils, fillers, etc. The plasticized metal neutralized sulfonated polymer has excellent physical properties at room temperature and up to 100.degree. C. and more than adequate processability at temperatures of from 200.degree. C. and above thereby providing a proper balance of rheological and physical properties. Preferably, the ionic polymer is an ionic elastomer having from 0.2 to 25 mole % pendant acid groups, for example, carboxylic, phosphonic and sulfonic acid groups. Preferably, the pendant acid groups are sulfonic acid groups.
摘要翻译： 本发明涉及独特和新颖的离子聚合物组合物，其特征在于可在高温例如200℃下加工，同时在室温和高于处理温度的高温下保持足够的物理性能。 离子聚合物组合物包括用优选增塑剂增塑的金属中和磺化聚合物，其浓度水平为每100份金属中和磺化聚合物约至少7重量份。 优选的增塑剂用于破坏中和的磺化聚合物的金属或铵盐基团的离子缔合，从而允许离子聚合物在加工温度下用作非交联材料。 当组合物处于这种状态时，它可以与油，填料等混合。塑化金属中和的磺化聚合物在室温和高达100℃下具有优异的物理性能，并且在200℃的温度下具有足够的加工性能 C.以上，从而提供流变学和物理性质的适当平衡。 优选地，离子聚合物是具有0.2至25摩尔％侧基酸基团的离子弹性体，例如羧酸，膦酸和磺酸基团。 优选地，侧基酸基团是磺酸基团。
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公开(公告)号：US3974241A
公开(公告)日：1976-08-10
申请号：US524512
申请日：1974-11-18
CPC分类号： C08L23/32
摘要： This invention relates to blends of sulfonated elastomers with crystalline polyolefins. The sulfonated elastomer comprises from about 0.2 to about 20 mole percent sulfonate groups, at least 95% of which are combined with metal counter ions selected from the group consisting of Groups I and II of the Periodic Table of the Elements, aluminum, and lead; organic amines; and mixtures thereof. The crystalline polyolefin is preferably selected from the group consisting of polyethylene, including high and low density polyethylenes, and polypropylene. The crystalline polyolefin comprises a minor portion of said blends.
摘要翻译： 本发明涉及磺化弹性体与结晶聚烯烃的共混物。 磺化弹性体包含约0.2至约20摩尔％的磺酸盐基团，其中至少95％与选自元素周期表第I和II族的金属抗衡离子，铝和铅组合; 有机胺; 及其混合物。 结晶聚烯烃优选选自包括高密度和低密度聚乙烯的聚乙烯和聚丙烯。 结晶聚烯烃包含少部分所述共混物。
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公开(公告)号：US4014847A
公开(公告)日：1977-03-29
申请号：US487467
申请日：1974-07-11
IPC分类号： C08K5/00 , C08K5/04 , C08K5/05 , C08L7/00 , C08L21/00 , C08L23/00 , C08L25/00 , C08L101/00 , C08K5/20 , C08K5/43 , C08K5/49
CPC分类号： C08K5/0016
摘要： Ionically crosslinked polymers are plasticized by blending the ionic compositions with a plasticizer which is normally liquid and non-volatile, the plasticizer compounds having a solubility parameter of at least 9.0. The plasticizers are preferential plasticizers for their ionic domains and do not ordinarily plasticize the polymeric backbone.
摘要翻译： 离子交联聚合物通过将离子组合物与通常为液体和非挥发性的增塑剂共混而增塑，增塑剂化合物的溶解度参数为至少9.0。 增塑剂是其离子结构域的优选增塑剂，通常不会使聚合物主链增塑。
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