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1.发明授权Conversion of light paraffins to oxygenates or olefins using an imide promoter 失效使用酰亚胺助催化剂将轻链烷烃转化为含氧化合物或烯烃公开(公告)号：US06555715B1
公开(公告)日：2003-04-29
申请号：US09975371
申请日：2001-10-11
IPC分类号： C07C4528
CPC分类号： C07C1/24 , C07C11/02 , C07C29/145 , C07C45/28 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2527/054 , C07C2527/173 , C07C2529/04 , C07C49/08 , C07C49/10 , C07C31/10 , C07C31/12
摘要： A process has been developed for oxygenating linear C2 to C6 alkanes to ketones or aldehydes. The process involves reacting the alkanes with oxygen in the presence of a catalyst comprising an imide promoter and a metal co-catalyst. An example of the imide is N-hydroxyphthalimide and an example of the co-catalyst is Co (acetylacetonate). The process is preferably carried out using an inert solvent, an example of which is acetic acid. Optionally, the oxygenated product can be hydrogenated to give the corresponding alcohol which can optionally in turn be dehydrated to provide the corresponding olefin.
摘要翻译： 已经开发了将线性C2至C6烷烃氧化成酮或醛的方法。 该方法包括在包含酰亚胺助催化剂和金属助催化剂的催化剂存在下使烷烃与氧反应。 酰亚胺的实例是N-羟基邻苯二甲酰亚胺，助催化剂的实例是Co（乙酰丙酮化物）。 该方法优选使用惰性溶剂进行，惰性溶剂的实例是乙酸。 任选地，氧化产物可以被氢化得到相应的醇，其可以任选地依次脱水以提供相应的烯烃。
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公开(公告)号：US08884055B2
公开(公告)日：2014-11-11
申请号：US13155553
申请日：2011-06-08
申请人： Alakananda Bhattacharyya , Joseph A. Kocal , Joel T. Walenga , Nikolay Y. Adonin , Nina I. Kuznetsova , Bair S. Bal'zhinimaev
发明人： Alakananda Bhattacharyya , Joseph A. Kocal , Joel T. Walenga , Nikolay Y. Adonin , Nina I. Kuznetsova , Bair S. Bal'zhinimaev
IPC分类号： C07C51/16 , C07C51/265
CPC分类号： C07C51/265 , C07C51/42 , Y02P20/52 , Y02P20/542 , C07C63/26
摘要： A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid.
摘要翻译： 固体对苯二甲酸组合物和由对二甲苯生产对苯二甲酸的方法。 该方法包括形成包含对二甲苯，溶剂，溴源和催化剂的混合物; 并通过在氧化条件下将氧化剂与氧化剂接触来氧化对二甲苯以产生包含对苯二甲酸，对甲苯甲酸，4-羧基苯甲醛的固体氧化产物。 溶剂包括具有1至7个碳原子的羧酸和二烷基咪唑鎓离子液体; 催化剂包括钴，钛，锰，铬，铜，镍，钒，铁，钼，锡，铈和锆中的至少一种。 固体对苯二甲酸组合物包含小于约4,000ppm重量的4-羧基苯甲醛含量和大于约2,000ppm重量的对甲苯甲酸。
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公开(公告)号：US08222465B2
公开(公告)日：2012-07-17
申请号：US13193227
申请日：2011-07-28
申请人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
发明人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
CPC分类号： C07C29/132 , C10G3/44 , C10G3/46 , C10G3/48 , C10G3/52 , C10G3/56 , C10G2300/1014 , Y02P20/52 , Y02P30/20 , C07C31/202 , C07C31/205
摘要： A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
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公开(公告)号：US20120004449A1
公开(公告)日：2012-01-05
申请号：US13155519
申请日：2011-06-08
申请人： Alakananda Bhattacharyya , Joseph A. Kocal , Joel T. Walenga , Nikolay Y. Adonin , Nina L. Kuznetsova , Bair S. Bal'zhinimaev
发明人： Alakananda Bhattacharyya , Joseph A. Kocal , Joel T. Walenga , Nikolay Y. Adonin , Nina L. Kuznetsova , Bair S. Bal'zhinimaev
IPC分类号： C07C51/265 , C07C51/42 , C07C51/16
CPC分类号： C07C51/265 , C07C63/16 , C07C63/24 , C07C63/26 , C07C63/06
摘要： A process and a mixture for oxidizing an alkyl-aromatic compound comprises forming a mixture comprising the alkyl-aromatic compound, a solvent, a bromine source, and a catalyst; and contacting the mixture with an oxidizing agent at oxidizing conditions to produce an oxidation product comprising at least one of an aromatic aldehyde, an aromatic alcohol, an aromatic ketone, and an aromatic carboxylic acid. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an ionic liquid selected from the group consisting of an imidazolium ionic liquid, a pyridinium ionic liquid, a phosphonium ionic liquid, a tetra alkyl ammonium ionic liquid, and combinations thereof. The catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium.
摘要翻译： 用于氧化烷基 - 芳族化合物的方法和混合物包括形成包含烷基 - 芳族化合物，溶剂，溴源和催化剂的混合物; 以及在氧化条件下使所述混合物与氧化剂接触以产生包含芳族醛，芳族醇，芳族酮和芳族羧酸中的至少一种的氧化产物。 溶剂包括具有1至7个碳原子的羧酸和选自咪唑鎓离子液体，吡啶鎓离子液体，鏻离子液体，四烷基铵离子液体及其组合的离子液体。 催化剂包括钴，钛，锰，铬，铜，镍，钒，铁，钼，锡，铈和锆中的至少一种。
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公开(公告)号：US20110313210A1
公开(公告)日：2011-12-22
申请号：US13193227
申请日：2011-07-28
申请人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
发明人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
IPC分类号： C07C31/20
CPC分类号： C07C29/132 , C10G3/44 , C10G3/46 , C10G3/48 , C10G3/52 , C10G3/56 , C10G2300/1014 , Y02P20/52 , Y02P30/20 , C07C31/202 , C07C31/205
摘要： A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
摘要翻译： 以包含纤维素的原料生成至少一种多元醇的催化方法是以连续方式进行的。 该方法包括使含有纤维素的氢，水和原料与催化剂连续地接触，以产生包含至少一种多元醇，水，氢和至少一种共同产物的流出物流。 将水，氢和至少一种副产物与流出物流分离并再循环至反应区。 从流出物流中回收多元醇。
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公开(公告)号：US20110313209A1
公开(公告)日：2011-12-22
申请号：US13193200
申请日：2011-07-28
申请人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
发明人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
IPC分类号： C07C29/74
CPC分类号： C07C29/132 , C07C31/20
摘要： A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
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公开(公告)号：US08039682B2
公开(公告)日：2011-10-18
申请号：US12402078
申请日：2009-03-11
申请人： Michael J. McCall , Joseph A. Kocal , Alakananda Bhattacharyya , Tom N. Kalnes , Timothy A. Brandvold
发明人： Michael J. McCall , Joseph A. Kocal , Alakananda Bhattacharyya , Tom N. Kalnes , Timothy A. Brandvold
IPC分类号： C10G1/00
CPC分类号： C10G3/47 , C10G3/46 , C10G3/49 , C10G3/52 , C10G45/02 , C10G45/58 , C10G47/00 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/08 , Y02P30/20
摘要： A hydrocarbon product stream having hydrocarbons with boiling points in the aviation fuel range is produced from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating, deoxygenating, isomerization, and selectively hydrocracking the feedstock to produce paraffinic hydrocarbons having from about 9 to about 16 carbon atoms and a high iso/normal ratio in a single reaction zone containing a multifunctional catalyst, or set of catalysts, having hydrogenation, deoxygenation, isomerization and selective hydrocracking functions.
摘要翻译： 在航空燃料范围内具有沸点的烃的烃产物流由可再生原料如植物油和动物油生产。 该方法包括通过氢化，脱氧，异构化和选择性加氢裂解原料来处理可再生原料，以在含有多官能催化剂的单个反应区中产生具有约9至约16个碳原子的链烷烃和高异/正常比例，或 具有氢化，脱氧，异构化和选择性加氢裂化功能的催化剂组。
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8.发明申请公开(公告)号：US20110201855A1
公开(公告)日：2011-08-18
申请号：US12707433
申请日：2010-02-17
IPC分类号： C10G1/00
摘要： Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.
摘要翻译： 提供了低氧生物质衍生的热解油及其从碳质生物质原料生产它们的方法。 在含有贱金属基催化剂，贵金属基催化剂，经处理的沸石催化剂或其组合的催化剂存在下，碳质生物质原料热解产生裂解气。 在热解期间，催化剂催化脱氧反应，由此将热解气体中的至少一部分氧化烃转化成烃。 作为碳氧化物和水除去氧气。 热解气体的可冷凝部分（蒸汽）被冷凝成低氧生物质衍生的裂解油。
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公开(公告)号：US20090253947A1
公开(公告)日：2009-10-08
申请号：US12418986
申请日：2009-04-06
CPC分类号： C10L1/04 , C10B53/02 , C10G3/46 , C10G3/47 , C10G3/49 , C10G3/50 , C10G50/00 , C10G65/00 , C10G65/02 , C10G65/14 , C10G69/00 , C10G69/02 , C10G69/08 , C10G69/126 , C10G69/14 , C10G2300/1014 , C10G2300/1022 , C10G2300/1037 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10J3/00 , C10J2300/0916 , C10J2300/1659 , C10L1/08 , Y02E50/13 , Y02P30/42 , Y02T50/678
摘要： A process for producing a blended fuel from a paraffin rich component and a cyclic rich component, where each of the components are generated from a renewable feedstock, is presented. The paraffin rich component is generated from a first renewable feedstock comprising at least one component selected from the group consisting of glycerides, free fatty acids, biomass, lignocellulose, free sugars, and combinations thereof. The cyclic rich component is generated from a second renewable feedstock comprising at least one component selected from the group consisting of glycerides, free fatty acids, free fatty alkyl esters, biomass, lignocellulose, free sugars, and combinations thereof. The blended fuel may a gasoline boiling point range blended fuel, a diesel boiling point range blended fuel, an aviation boiling point range blended fuel, any combination thereof, or any mixture thereof.
摘要翻译： 本发明提供了一种从富含链烷烃的组分和富含循环的组分制备混合燃料的方法，其中每种组分均由可再生原料生成。 富含链烷烃的组分由包含至少一种选自甘油酯，游离脂肪酸，生物质，木质纤维素，游离糖及其组合的组分的第一可再生原料产生。 循环富含组分由第二可再生原料生成，其包含至少一种选自甘油酯，游离脂肪酸，游离脂肪烷基酯，生物质，木质纤维素，游离糖及其组合的组分。 混合燃料可以是汽油沸点范围混合燃料，柴油沸点范围混合燃料，航空沸点范围混合燃料，其任何组合，或其任何混合物。
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10.发明申请Oxidation of Methane to Methanol using a Catalyst Containing a Transition Metal 审中-公开使用含有过渡金属的催化剂将甲烷氧化成甲醇公开(公告)号：US20080249337A1
公开(公告)日：2008-10-09
申请号：US11697776
申请日：2007-04-09
IPC分类号： C07B41/02
CPC分类号： C07C29/095 , C07C67/035 , C12C11/02 , C07C31/04 , C07C69/63
摘要： A process for the oxidation of methane to methanol has been developed. The process involves contacting a gas stream, comprising methane, a solvent and an oxidizing agent with a catalyst at oxidation conditions to produce a methyl ester. Finally, the methyl ester is hydrolyzed to yield a methanol product stream. The catalyst comprises a transition metal component such as manganese oxide and an inorganic oxide such as silica. The transition metal component can be dispersed onto the inorganic oxide.
摘要翻译： 已经开发了将甲烷氧化成甲醇的方法。 该方法包括在氧化条件下使包含甲烷，溶剂和氧化剂的气流与催化剂接触以产生甲酯。 最后，将甲酯水解，得到甲醇产物流。 催化剂包括过渡金属组分如氧化锰和无机氧化物如二氧化硅。 过渡金属组分可以分散在无机氧化物上。
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