公开(公告)号：US11491459B2

公开(公告)日：2022-11-08

申请号：US17008419

申请日：2020-08-31

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Youssef Belmabkhout ,  Mohamed Infas Haja Mohideen ,  Karim Adil ,  Prashant M. Bhatt ,  Osama Shekhah ,  Valeriya Chernikova

IPC: B01J20/22 ,  B01J20/02 ,  B01J20/28 ,  C07C7/13 ,  C10G25/00 ,  C10L1/06 ,  C10L1/08 ,  F02B1/14 ,  F02B5/02 ,  F02B47/04 ,  F02M25/12 ,  C01B3/40 ,  B01D53/02

Abstract: Embodiments of the present disclosure provide a metal-organic framework composition including a metal-organic framework having an ana topology, the metal-organic framework including one or more metals connected to one or more organic linkers. Embodiments of the present disclosure further provide a method of separating chemical species including contacting a metal-organic framework having an ana topology with a flow of paraffins and separating the paraffins.

公开(公告)号：US10377786B2

公开(公告)日：2019-08-13

申请号：US15319505

申请日：2015-06-17

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Osama Shekhah ,  Youssef Belmabkhout

IPC: C07F15/04 ,  B01J20/22 ,  B01J20/30 ,  B01J37/00 ,  C07F7/02 ,  B01J31/16 ,  B01J37/04

Abstract: A green route for preparing a metal organic framework include mixing metal precursor with a ligand precursor to form a solvent-free mixture; adding droplets of water to the mixture; heating the mixture at a first temperature after adding the water; and isolating the metal organic framework material including the metal and the ligand.

公开(公告)号：US11077423B2

公开(公告)日：2021-08-03

申请号：US16943998

申请日：2020-07-30

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC: B01J20/22 ,  B01J20/28 ,  B01J20/30 ,  C07D241/10 ,  C07F19/00 ,  B01D53/02

Abstract: Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US10563554B2

公开(公告)日：2020-02-18

申请号：US16507730

申请日：2019-07-10

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Youssef Belmabkhout ,  Osama Shekhah

IPC: B01D53/02 ,  F01N3/08 ,  B01J20/22 ,  F01N3/022

Abstract: In general, this disclosure describes method of capturing and storing CO2 on a vehicle. The method includes contacting an vehicle exhaust gas with one or more of a first metal organic framework (MOF) composition sufficient to separate CO2 from the exhaust gas, contacting the separated CO2 with one or more of a second MOF composition sufficient to store the CO2 and wherein the one or more first MOF composition comprises one or more SIFSIX-n-M MOF and wherein M is a metal and n is 2 or 3. Embodiments also describe an apparatus or system for capturing and storing CO2 onboard a vehicle.

公开(公告)号：US10328414B2

公开(公告)日：2019-06-25

申请号：US15564909

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC: B01J20/22 ,  B01J31/16 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

Abstract: Provided herein are metal organic frameworks having high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Metal organic frameworks can comprise metal nodes and N-donor organic ligands. Further provided are methods of making metal organic frameworks.

公开(公告)号：US10130908B2

公开(公告)日：2018-11-20

申请号：US15100513

申请日：2014-11-26

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Bassem A. Almaythalony ,  Osama Shekhah ,  Youssef Belmabkhout

IPC: B01D53/22 ,  B01D71/02 ,  B01D67/00 ,  B01D69/02 ,  B01D69/10 ,  B01D53/28

Abstract: Metal organic framework membranes can be used in gas separation applications.

公开(公告)号：US11623203B2

公开(公告)日：2023-04-11

申请号：US16861283

申请日：2020-04-29

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Osama Shekhah

IPC: B01D53/02 ,  B01J20/22 ,  B01J20/32 ,  C07F1/00 ,  C07F3/00 ,  B01J20/30 ,  B05D1/00

Abstract: Embodiments describe a method of depositing an MOF, including depositing a metal solution onto a substrate, spinning the substrate sufficient to spread the metal solution, depositing an organic ligand solution onto the substrate and spinning the substrate sufficient to spread the organic ligand solution and form a MOF layer.

公开(公告)号：US11439944B2

公开(公告)日：2022-09-13

申请号：US16584130

申请日：2019-09-26

Applicant: University of South Florida ,  King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Michael J. Zaworotko ,  Patrick Nugent ,  Stephen Burd ,  Ryan Luebke ,  Youssef Belmabkhout ,  Osama Shekhah

IPC: B01D53/02 ,  B01D53/04 ,  B01J20/22 ,  B01J20/28

Abstract: Embodiments of the present disclosure provide for metal-organic materials (MOMs), systems that exhibit permanent porosity and using hydrophobic MOMs to separate components in a gas, methods of separating CO2 from a gas, and the like.

公开(公告)号：US10903019B2

公开(公告)日：2021-01-26

申请号：US16471812

申请日：2017-12-29

Applicant: King Abdullah University of Science and Technology

Inventor： Arijit Mallick ,  Bilal Ahmed ,  Osama Shekhah ,  Husam N. Alshareef ,  Mohamed Eddaoudi

IPC: H01G11/30 ,  C07D471/06 ,  C07F7/00 ,  H01G11/86

Abstract: Embodiments of the present disclosure describe an electrode material comprising a metal ion cluster and an organic linker with a redox-active center associated with the metal ion cluster sufficient to form a metal-organic framework. Embodiments of the present disclosure further describe a method of forming an electrode material comprising contacting a metal ion cluster with an organic linker including a redox-active center sufficient to form a metal-organic framework. Embodiments of the present disclosure also describe a metal-organic framework composition comprising a metal ion cluster and an organic linker with a redox-active center associated with the metal ion cluster.

公开(公告)号：US10759724B2

公开(公告)日：2020-09-01

申请号：US15952511

申请日：2018-04-13

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Youssef Belmabkhout ,  Mohamed Infas Haja Mohideen ,  Karim Adil ,  Prashant M. Bhatt ,  Osama Shekhah ,  Valeriya Chernikova

IPC: C07C7/13 ,  B01J20/02 ,  B01J20/04 ,  B01J20/22 ,  B01J20/28 ,  B01J31/16

Abstract: Embodiments of the present disclosure describe a zeolite-like metal-organic framework composition comprising a metal-organic framework composition with ana topology characterized by the formula [MIII(4, 5-imidazole dicarboxylic acid)2X(solvent)a]n wherein MIII comprises a trivalent cation of a rare earth element, X comprises an alkali metal element or alkaline earth metal element, and solvent comprises a guest molecule occupying pores. Embodiments of the present disclosure describe a method of separating paraffins comprising contacting a zeolite-like metal-organic framework with ana topology with a flow of paraffins, and separating the paraffins by size.