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    Transparent resin material
    1.
    发明授权
    Transparent resin material 失效
    透明树脂材料

    公开(公告)号：US5164469A

    公开(公告)日：1992-11-17

    申请号：US648237

    申请日：1991-01-31

    申请人： Kohei Goto ,  Zen Komiya ,  Noboru Yamahara ,  Akira Iio ,  Masao Hisatomi ,  Hiroshi Oka

    发明人： Kohei Goto ,  Zen Komiya ,  Noboru Yamahara ,  Akira Iio ,  Masao Hisatomi ,  Hiroshi Oka

    IPC分类号： C08G61/08 ,  C08L65/00

    CPC分类号： C08L65/00 ,  C08G61/08

    摘要： A transparent resin material consisting of a hydrogenation product of a (co)polymer obtained by subjecting at least one compound represented by general formula (I) or a combination of at least 5% by weight of said compound and 95% by weight or less of other copolymerizable cyclic olefin monomer to metathesis polymerization: ##STR1## wherein A and B are independently hydrogen atoms or C.sub.1-10 hydrocarbon groups; and X and Y are independently hydrogen atoms, C.sub.1-10 hydrocarbon groups, --C(CH.sub.2).sub.n COOR.sup.1 groups or --(CH.sub.2).sub.n OCOR.sup.1 groups [R.sup.1 is a C.sub.1-20 hydrocarbon group and n is 0 or an integer of 1-10] with the proviso that at least one of X and Y is selected from the above --(CH.sub.2).sub.n COOR.sup.1 and --(CH.sub.2).sub.n OCOR.sup.1 groups. Said transparent resin material is moldable and has sufficient optical properties, low hygroscopicity, good heat resistance and excellent adhesion to recording layer.

    摘要翻译： 将由通式（I）表示的至少一种化合物或至少5重量％的所述化合物的组合和95重量％以下的化合物所得的（共）聚合物的氢化产物组成的透明树脂材料 其它可共聚的环烯烃单体进行复分解聚合反应：其中A和B独立地为氢原子或C 1-10烃基; 并且X和Y独立地是氢原子，C 1-10烃基，-C（CH 2）n COOR 1基团或 - （CH 2）nOCOR 1基团[R 1是C 1-20烃基，n是0或1-10的整数] 条件是X和Y中的至少一个选自上述 - （CH 2）n COOR 1和 - （CH 2）nOCOR 1基团。 所述透明树脂材料是可模塑的并且具有足够的光学性能，低吸湿性，良好的耐热性和对记录层的优异粘合性。

    Transparent resin material
    2.
    发明授权
    Transparent resin material 失效
    透明树脂材料

    公开(公告)号：US5053471A

    公开(公告)日：1991-10-01

    申请号：US613939

    申请日：1990-11-13

    申请人： Kohei Goto ,  Zen Komiya ,  Noboru Yamahara ,  Akira Iio

    发明人： Kohei Goto ,  Zen Komiya ,  Noboru Yamahara ,  Akira Iio

    IPC分类号： C08G61/08 ,  C08L65/00

    CPC分类号： C08L65/00 ,  C08G61/08 ,  G11B7/2538

    摘要： A transparent resin material consisting of a (co)polymer obtained by subjecting at least one compound represented by the general formula (I) or a combination of said compound and other copolymerizable monomer to metathesis polymerization, or a hydrogenation product of the (co)polymer: ##STR1## wherein A and B are independently hydrogen atoms or C.sub.1-10 hydrocarbon groups; X and Y are independently hydrogen atoms, C.sub.1-10 hydrocarbon groups, halogen atoms, halogen-substituted C.sub.1-10 hydrocarbon groups, --(CH.sub.2).sub.n COOR.sup.1, --(CH.sub.2).sub.n OCOR.sup.1, --(CH.sub.2).sub.n OR.sup.1, --(CH.sub.2).sub.n CN, --(CH.sub.2).sub.n CONR.sup.2 R.sup.3, --(CH.sub.2).sub.n COOZ, --(CH.sub.2).sub.n OCOZ, --(CH.sub.2).sub.n OZ or --(CH.sub.2).sub.n W [R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently C.sub.1-20 hydrocarbon groups, Z is a halogen-substituted hydrocarbon group, W is SiR.sub.p.sup.5 D.sub.3-p (R.sup.5 is a C.sub.1-10 hydrocarbon group, D is a halogen atom, --OCOR.sup.5 or --OR.sup.5, p is 0 or an integer of 1-3), n is 0 or an integer of 1-10] with the proviso that at least one of X and Y is selected from the above groups other than the hydrogen atom and the hydrocarbon groups, or X and Y may form together ##STR2## and m is 0 or 1. Said transparent resin material is moldable and has sufficient optical properties, low hygroscopicity, good heat resistance and excellent adhesion to recording layer.

    Radiation Curable Liquid Resin Composition for Optical Three-Dimensional Molding and Optical Molded Article Obtained by Photocuring Same
    3.
    发明申请
    Radiation Curable Liquid Resin Composition for Optical Three-Dimensional Molding and Optical Molded Article Obtained by Photocuring Same 审中-公开
    用于光学三维成型的辐射可固化液体树脂组合物和通过光固化获得的光学成型品

    公开(公告)号：US20070232713A1

    公开(公告)日：2007-10-04

    申请号：US11596744

    申请日：2005-05-26

    申请人： Katsuyuki Takase ,  Ryouji Tatara ,  Masanobu Sugimoto ,  Zen Komiya

    发明人： Katsuyuki Takase ,  Ryouji Tatara ,  Masanobu Sugimoto ,  Zen Komiya

    IPC分类号： C08G59/18 ,  B29C67/00 ,  C08K5/13 ,  C08K5/524 ,  C08L63/00

    CPC分类号： G03F7/027 ,  B29C64/00 ,  G03F7/0037 ,  G03F7/038

    摘要： Provided is a radiation curing liquid resin composition for optical three-dimensional modeling, which has a small step on the side face and excellent surface smoothness, and allows forming a high accuracy optically modeled article, is composed of the components (A) through (F). The content of (A) component in the total quantity of the composition is 0.1 to 10% by mass, and the content of (F) polyether polyol compound is 1 to 35% by mass. (A) A compound having phenolic hydroxyl group and/or phosphite group, (B) A cationic polymerizable compound, (C) A cationic polymerization initiator, (D) A radical polymerizable compound, (E) A radical polymerization initiator, and (F) A polyether polyol compound.

    摘要翻译： 提供一种用于光学三维建模的辐射固化液体树脂组合物，其在侧面具有小的台阶和优异的表面平滑度，并且允许形成高精度的光学建模的制品由组分（A）至（F ）。 组合物中（A）成分的含量为0.1〜10质量％，（F）聚醚多元醇化合物的含量为1〜35质量％。 （A）具有酚羟基和/或亚磷酸酯基的化合物，（B）阳离子聚合性化合物，（C）阳离子聚合引发剂，（D）自由基聚合性化合物，（E）自由基聚合引发剂，（F ）聚醚多元醇化合物。

    Curable Liquid Resin Composition
    4.
    发明申请
    Curable Liquid Resin Composition 有权
    可固化液体树脂组合物

    公开(公告)号：US20070203258A1

    公开(公告)日：2007-08-30

    申请号：US10571758

    申请日：2004-09-17

    申请人： Masanobu Sugimoto ,  Satoshi Kamo ,  Takeo Shigemoto ,  Zen Komiya ,  Paulus Steeman

    发明人： Masanobu Sugimoto ,  Satoshi Kamo ,  Takeo Shigemoto ,  Zen Komiya ,  Paulus Steeman

    IPC分类号： C09D11/00 ,  C08G18/00

    CPC分类号： C08G18/672 ,  C03C25/1061 ,  C03C25/1065 ,  C08G18/4854 ,  C08L75/16 ,  C09D175/16 ,  Y10T428/2933 ,  C08G18/48 ,  C08L2666/14

    摘要： The invention relates to a curable liquid resin composition comprising: (A) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 800 g/mol or more, but less than 6,000 g/mol, and (B) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 6,000 g/mol or more, but less than 20,000 g/mol, wherein the total amount of the component (A) and component (B) is 20-95 wt % of the curable liquid resin composition and the content of the component (B) is 0.1-30 wt % of the total of the component (A) and component (B).

    摘要翻译： 本发明涉及一种可固化液体树脂组合物，其包含：（A）具有起始于多元醇的结构和数均分子量为800g / mol以上但小于6,000g / mol的氨基甲酸酯（甲基）丙烯酸酯，以及 （B）具有来自多元醇的结构和数均分子量为6000g / mol以上但小于20,000g / mol的氨基甲酸酯（甲基）丙烯酸酯，其中组分（A）和组分 （B）为可固化液体树脂组合物的20-95重量％，组分（B）的含量为组分（A）和组分（B）的总量的0.1-30重量％。

    Multilayer coating
    5.
    发明授权
    Multilayer coating 有权
    多层涂层

    公开(公告)号：US07740944B2

    公开(公告)日：2010-06-22

    申请号：US10469132

    申请日：2002-03-01

    申请人： Zen Komiya ,  Masahito Mase ,  Junji Yoshizawa ,  Takashi Ukachi

    发明人： Zen Komiya ,  Masahito Mase ,  Junji Yoshizawa ,  Takashi Ukachi

    IPC分类号： B32B27/40 ,  C08F2/46

    CPC分类号： C03C17/3405 ,  C03C25/1065 ,  C03C25/50 ,  Y10T428/31504 ,  Y10T428/31554

    摘要： The present invention relates to a multilayer coating in which a plurality of photocurable resin cured films are layered on a substrate, wherein at least two adjacent layers comprise the same hindered phenol-type antioxidant.The multilayer coating can be applied onto a substrate, such as glass fibers, vinyl chloride sheets, polycarbonate sheets, glass plates, polyethylene films, wood, acrylic sheets, metal plates, and the like.

    摘要翻译： 本发明涉及一种多层涂层，其中多个光固化树脂固化膜层叠在基底上，其中至少两个相邻层包含相同的受阻酚型抗氧化剂。 可以将多层涂层涂布在基材上，例如玻璃纤维，氯乙烯片，聚碳酸酯片，玻璃板，聚乙烯薄膜，木材，丙烯酸片，金属板等。

    Radiation-curable resin composition for adhesives
    8.
    发明申请
    Radiation-curable resin composition for adhesives 审中-公开
    用于粘合剂的可辐射固化树脂组合物

    公开(公告)号：US20050244752A1

    公开(公告)日：2005-11-03

    申请号：US10508993

    申请日：2003-03-23

    申请人： Junji Yoshizawa ,  Atsuya Takahashi ,  Masahito Mase ,  Zen Komiya

    发明人： Junji Yoshizawa ,  Atsuya Takahashi ,  Masahito Mase ,  Zen Komiya

    IPC分类号： C09J4/02 ,  C08F289/00 ,  C08F290/06 ,  C09J4/06 ,  C09J11/00 ,  G11B7/24

    CPC分类号： C08F290/061 ,  C08F289/00 ,  C08F290/06 ,  C09J4/06

    摘要： A radiation-curable resin composition for adhesives comprising (A) a bisphenol-type epoxy (meth)acrylate having a hydroxyl group, (B) a polyfunctional (meth)acrylate having an aliphatic cyclic structure or an aromatic cyclic structure other than the component (A), and (C) a photoinitiator, wherein the content of the component (A) and the content of the component (B) in the composition are respectively 30 wt % or more. The radiation-curable resin composition for adhesives of the present invention exhibits excellent adhesion to silver, silicon compound, and aluminum, superior moisture-heat resistance, and fast curability, especially at the edge of the disk, and therefore is very useful in the manufacture of optical disks in comparison with conventional adhesives.

    摘要翻译： 一种用于粘合剂的辐射固化树脂组合物，其包含（A）具有羟基的双酚型环氧（甲基）丙烯酸酯，（B）具有脂肪族环状结构的多官能（甲基）丙烯酸酯或除该成分 A）和（C）光引发剂，其中组分（A）的含量和组分（B）中组分的含量分别为30重量％或更多。 本发明的粘合剂用辐射固化型树脂组合物对银，硅化合物和铝具有优异的粘合性，优异的耐湿热性和快速固化性，特别是在盘的边缘，因此在制造中非常有用 与常规粘合剂相比。

    Optical glass fiber coating composition
    10.
    发明授权
    Optical glass fiber coating composition 失效
    光学玻璃纤维涂料组合物

    公开(公告)号：US5913004A

    公开(公告)日：1999-06-15

    申请号：US840169

    申请日：1997-04-14

    申请人： Hideaki Takase ,  Mitsuhito Suwa ,  Zen Komiya ,  Takashi Ukachi

    发明人： Hideaki Takase ,  Mitsuhito Suwa ,  Zen Komiya ,  Takashi Ukachi

    IPC分类号： C03C25/10 ,  C08F290/06 ,  C08G18/10 ,  C08G18/67 ,  C09D175/16 ,  G02B6/02 ,  G02B6/16

    CPC分类号： C09D175/16 ,  C03C25/106 ,  C08F290/067 ,  C08G18/10 ,  C08G18/672

    摘要： Provided is an optical glass fiber coating composition which when coated on an optical glass fiber and suitably cured provides a coating having the combination of properties (i) through (iv):(i) a stable tensile modulus that is low at room temperature and over a broad range of temperatures below room temperature,(ii) an adhesion to the optical glass fiber sufficient to prevent structural defects and microbending in the optical glass fiber,(iii) the capability of being removed by stripping from the optical glass fiber substantially no residue left on the optical glass fiber, and(iv) which satisfies each of the following inequalities (I) and (II),X.ltoreq.0.2 kg/mm.sup.2 (I)X/Y.gtoreq.1/10 (II) wherein X is the tensile modulus (kg/mm.sup.2) measured at 23.degree. C. and Y is the tensile modulus (kg/mm.sup.2) measured at -40.degree. C.,This coating composition comprises:(A) a urethane (meth)acrylate formed from,(a) a diol compound containing at least one structure represented by one of the following formulas (1) and (2), ##STR1## (b) a compound containing two isocyanate groups, and (c) a compound containing a (meth)acrylate group and a hydroxy group;(B) a second (meth)acrylate-containing compound of which the homopolymer has a glass transition temperature of at most about 0.degree. C.; and(C) a polymerization initiator.

    摘要翻译： 提供了一种光学玻璃纤维涂料组合物，其在光学玻璃纤维上涂覆并适当固化时提供了具有性能（i）至（iv）的组合的涂层：（i）在室温和过高时稳定的拉伸模量 低于室温的宽范围的温度，（ii）足以防止光学玻璃纤维中的结构缺陷和微弯曲的光学玻璃纤维的粘附，（iii）通过从光学玻璃纤维剥离而基本上没有残留物的去除能力 留下在光学玻璃纤维上，和（iv）满足以下不等式（I）和（II）中的每一个，X <= 0.2kg / mm 2（I）X / Y> / = 1/10（II）其中 X为在23℃下测定的拉伸弹性模量（kg / mm2），Y为在-40℃下测定的拉伸弹性模量（kg / mm2）。该涂料组合物包含：（A）形成的氨基甲酸酯（甲基） 由（a）含有由下述式（1）表示的至少一种结构的二醇化合物a nd（2），（b）含有2个异氰酸酯基的化合物，（c）含有（甲基）丙烯酸酯基和羟基的化合物; （B）第二（甲基）丙烯酸酯化合物，其均聚物的玻璃化转变温度为至多约0℃; 和（C）聚合引发剂。