公开(公告)号：US20110207901A1

公开(公告)日：2011-08-25

申请号：US12711353

申请日：2010-02-24

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/602 ,  C08F4/60 ,  C08F4/32

CPC classification number: C08F110/06 ,  C08F2500/12 ,  C08F4/6494 ,  C08F4/651

Abstract: The present invention relates to catalyst systems containing solid catalyst components comprising titanium, magnesium, halogen and an internal electron donor compound having at least one ether group and at least one ketone group; organoaluminum compounds and alkyl benzoate derivatives as external electron donors. The present invention also relates to methods of making the catalyst systems, and methods of polymerizing or copolymerizing alpha-olefins using the catalyst systems.

Abstract translation: 本发明涉及包含钛，镁，卤素和具有至少一个醚基和至少一个酮基的内电子给体化合物的固体催化剂组分的催化剂体系; 有机铝化合物和苯甲酸烷基酯衍生物作为外部电子给体。 本发明还涉及制备催化剂体系的方法，以及使用催化剂体系聚合或共聚α-烯烃的方法。

公开(公告)号：US07153803B2

公开(公告)日：2006-12-26

申请号：US10879572

申请日：2004-06-28

Applicant: Zhidong Zhu ,  Main Chang ,  Christopher J. Aarons

Inventor： Zhidong Zhu ,  Main Chang ,  Christopher J. Aarons

IPC: C08F4/02 ,  C08F4/64 ,  C08F5/58

CPC classification number: C08F10/00 ,  C08F110/02 ,  Y02P20/52 ,  C08F4/6567 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/24

Abstract: Disclosed are catalyst systems and methods of making the catalyst systems/supports for the polymerization of polyethylene containing a solid titanium catalyst component containing a titanium compound and a support made from a magnesium compound, an alkyl silicate, and a monoester. The catalyst system may further contain an organoaluminum compound. Also disclosed are methods of making various types of polyethylene involving polymerizing ethylene in the presence of hydrogen and a catalyst system containing a support made from a magnesium compound, an alkyl silicate and a monoester.

Abstract translation: 公开了制备用于聚合聚乙烯的催化剂体系和载体的方法，所述聚乙烯含有含钛化合物的固体钛催化剂组分和由镁化合物，硅酸烷基酯和单酯制成的载体。 催化剂体系还可以含有有机铝化合物。 还公开了制备各种类型的聚乙烯的方法，包括在氢存在下聚合乙烯和含有由镁化合物，硅酸烷基酯和单酯制成的载体的催化剂体系。

公开(公告)号：US06184170B2

公开(公告)日：2001-02-06

申请号：US09565854

申请日：2000-05-05

Applicant: Main Chang

Inventor： Main Chang

IPC: B01J3114

CPC classification number: C08F10/00 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/943 ,  C08F4/65912

Abstract: This invention relates generally to metallocene catalyst systems and to methods for their production and use. Specifically, this invention relates to a method for preparing metallocene catalyst systems using olefin additives which promote catalyst activity.

Abstract translation: 本发明一般涉及茂金属催化剂体系及其生产和使用方法。 具体地说，本发明涉及使用促进催化剂活性的烯烃添加剂制备茂金属催化剂体系的方法。

公开(公告)号：US5032652A

公开(公告)日：1991-07-16

申请号：US430991

申请日：1989-11-02

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/02 ,  C08F4/60 ,  C08F4/639 ,  C08F4/68 ,  C08F10/00

CPC classification number: C08F10/00 ,  Y10S526/943

Abstract: This invention relates to a supported vanadium-alumoxane catalyst for use in gas and liquid polymerization of olefins. The invention particularly relates to the use of silica gel containing from about 6 to about 20 percent by weight adsorbed water as the catalyst support material. The particle size of the silica gel is generally between about 0.1 and 200.0.mu.. Such silica gel may be safely added to a trialkylaluminum solution to form by direct reaction with the adsorbed water content of the silica gel catalyst support material the alumoxane cocatalyst component of the catalyst system. An alumoxane coated silica gel is formed to which a vanadium compound is added and the resulting material dried to a free flowing powder. The dry free flowing powder may then be used as a supported vanadium alumoxane catalyst complex for the polymerization of olefins. Resins produced from such processes have a broad molecular weight distribution suitable in blow molding for the fabrication of household and industrial containers.

公开(公告)号：US5017665A

公开(公告)日：1991-05-21

申请号：US385339

申请日：1989-07-25

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/643 ,  C08F4/60 ,  C08F4/659 ,  C08F4/6592 ,  C08F210/00 ,  C08F210/02 ,  C08F210/16 ,  C08F210/18

CPC classification number: C08F210/18 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  Y10S526/943

Abstract: A process using a high activity supported metallocene-alumoxane catalyst, comprising methylalumoxane and bisindenyl zirconium dichloride on a silica support, for the copolymerization of ethylene and 1,4-hexadiene to produce a copolymer having a high concentration of pendant functionalizeable groups which may also be used to cross-link the copolymer.

Abstract translation: 一种使用高活性负载型茂金属 - 铝氧烷催化剂的方法，其包括在二氧化硅载体上的甲基铝氧烷和二茚基二氯化锆，用于乙烯和1,4-己二烯的共聚合以制备具有高浓度侧链可官能化基团的共聚物，其也可以是 用于交联共聚物。

公开(公告)号：US5008228A

公开(公告)日：1991-04-16

申请号：US174668

申请日：1988-03-29

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/02 ,  C08F4/60 ,  C08F4/602 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/648 ,  C08F4/6592 ,  C08F10/00

CPC classification number: C08F10/00 ,  C08F4/63912 ,  C08F4/63916 ,  C08F4/6392 ,  Y10S526/943

Abstract: This invention relates to a process for preparing a supported metallocene alumoxane catalyst for use in the slurry or liquid phase polymerization of olefins. The invention particularly relates to the use of silica gel containing from about 10 to about 50 percent by weight adsorbed water as the catalyst support material. It has been found that such silica gel may be safely added to an aluminum trialkyl solution to form by direct reaction with the adsorbed water content of the silica gel catalyst support material the alumoxane component of the catalyst system. An alumoxane coated silica gel is formed to which a metallocene may be added. The resulting material can either be used in this slurry state for slurry polymerization or can be used for liquid phase polymerization of olefins.

公开(公告)号：US4937301A

公开(公告)日：1990-06-26

申请号：US277167

申请日：1988-11-29

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/639 ,  C08F4/6392 ,  C08F10/00

CPC classification number: C08F10/00 ,  C08F4/63912 ,  C08F4/63916 ,  C08F4/6392 ,  C08F4/63922 ,  Y10S526/943

Abstract: This invention relates to a process for preparing a supported metallocene alumoxane catalyst for use in the gas phase polymerization of olefins. The invention particularly relates to the use of silica gel containing from about 6 to about 10 percent by weight adsorbed water as the catalyst support material. It has been found that such silica gel may be safely added to an aluminum trialkyl solution to form by direct reaction with the adsorbed water content of the silica gel catalyst support material the alumoxane component of the catalyst system. An alumoxane coated silica gel is formed to which a metallocene may be added and the resulting material dried to free flowing powder. The dry free flowing powder may then be used as a supported metallocene alumoxane catalyst complex for gas phase polymerization of olefins.

Abstract translation: 本发明涉及一种制备用于烯烃气相聚合的负载金属茂铝氧烷催化剂的方法。 本发明特别涉及含有约6至约10重量％吸附水的硅胶作为催化剂载体材料的用途。 已经发现，通过与催化剂体系的硅氧烷组分的硅胶催化剂载体材料的吸附水含量的直接反应，可以将这种硅胶安全地加入到三烷基铝溶液中形成。 形成铝氧烷涂覆的硅胶，向其中加入茂金属，所得材料干燥以自由流动的粉末。 然后可将干燥自由流动的粉末用作烯烃气相聚合的负载金属茂铝氧烷催化剂络合物。

公开(公告)号：US08211819B2

公开(公告)日：2012-07-03

申请号：US12655007

申请日：2009-12-21

Applicant: Main Chang

Inventor： Main Chang

IPC: B01J31/00 ,  B01J37/00 ,  C08F4/44 ,  C08F210/00 ,  C08F10/14 ,  C08F10/04 ,  C08F110/06 ,  C08F110/02

CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F2500/12 ,  C08F4/651 ,  C08F4/6494

Abstract: The present invention relates to catalyst systems containing solid catalyst components comprising titanium, magnesium, halogen and a 1,8-naphthyl diaryloate internal electron donor compound; organoaluminum compounds and alkyl benzoate derivatives as external electron donors. The present invention also relates to methods of making the catalyst systems, and methods of polymerizing or copolymerizing alpha-olefins using the catalyst systems.

Abstract translation: 本发明涉及含有固体催化剂组分的催化剂体系，其中包括钛，镁，卤素和1,8-萘基二异辛烯内电子给体化合物; 有机铝化合物和苯甲酸烷基酯衍生物作为外部电子给体。 本发明还涉及制备催化剂体系的方法，以及使用催化剂体系聚合或共聚α-烯烃的方法。

公开(公告)号：US20100029870A1

公开(公告)日：2010-02-04

申请号：US12181907

申请日：2008-07-29

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/42 ,  C07C63/00 ,  B01J31/02 ,  B01J31/04 ,  B01J37/00 ,  C08F4/32

CPC classification number: C07C67/14 ,  C07C69/76 ,  C07C69/78 ,  C08F10/00 ,  C08F110/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/12

Abstract: Disclosed are 1,8-naphthyl diaryloates, methods of making 1,8-naphthyl diaryloates, methods of using 1,8-naphthyl diaryloates, solid titanium catalyst components, catalyst systems containing solid titanium catalyst components, methods of making solid titanium catalyst components, and polymerization methods. The solid titanium catalyst components contain a 1,8-naphthyl diaryloate internal electron donor compound. The catalyst system can contain a solid titanium catalyst component, an organoaluminum compound, and an organosilicon compound.

Abstract translation: 公开了1,8-萘基二芳基酯，制备1,8-萘基二异辛酸的方法，使用1,8-萘基二异辛酸酯的方法，固体钛催化剂组分，含有固体钛催化剂组分的催化剂体系，制备固体钛催化剂组分的方法， 和聚合方法。 固体钛催化剂组分含有1,8-萘基二异丙内酯电子给体化合物。 催化剂体系可以含有固体钛催化剂组分，有机铝化合物和有机硅化合物。

公开(公告)号：US20090286672A1

公开(公告)日：2009-11-19

申请号：US12119824

申请日：2008-05-13

Applicant: Main Chang

Inventor： Main Chang

IPC: B01J31/14 ,  B01J31/02 ,  C08F4/76

CPC classification number: C08F10/02 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/12

Abstract: Disclosed are solid titanium catalyst components, catalyst systems containing solid titanium catalyst components, and methods of making solid titanium catalyst components. The solid titanium catalyst components contain an internal electron donor compound containing at least one ether group and at least one ketone group. The catalyst system can contain a solid titanium catalyst component, an organoaluminum compound, and an organosilicon compound. Also disclosed are methods of polymerizing or copolymerizing an alpha-olefin. The methods involve contacting an olefin with a catalyst system containing the solid titanium catalyst component.

Abstract translation: 公开了固体钛催化剂组分，含有固体钛催化剂组分的催化剂体系，以及制备固体钛催化剂组分的方法。 固体钛催化剂组分含有含有至少一个醚基团和至少一个酮基团的内电子给体化合物。 催化剂体系可以含有固体钛催化剂组分，有机铝化合物和有机硅化合物。 还公开了聚合或共聚α-烯烃的方法。 所述方法包括使烯烃与含有固体钛催化剂组分的催化剂体系接触。