Polymerization of fluoropolymers using non-fluorinated surfactants
    1.
    发明授权
    Polymerization of fluoropolymers using non-fluorinated surfactants 有权
    使用非氟化表面活性剂聚合含氟聚合物

    公开(公告)号:US08697822B2

    公开(公告)日:2014-04-15

    申请号:US11995593

    申请日:2006-06-26

    IPC分类号: C08L27/16

    CPC分类号: C08F214/22 C08F14/18 C08F2/22

    摘要: The present invention relates to a method for the polymerization in an aqueous medium of monomers, and especially of fluoromonomers, using non-fluorinated surfactants; and the fluoropolymers formed therefrom. Specifically, the method of the polymerization uses one or more non-fluorinated surfactants selected from the group consisting of polyvinylphosphonic acid, polyacrylic acids, polyvinyl sulfonic acid, and salts thereof. Additionally, the use of polyvinylphosphonic acid, polyacrylic acids, polyvinyl sulfonic acid as surfactants in aqueous free radical polymerization is also novel.

    摘要翻译: 本发明涉及使用非氟化表面活性剂在单体,特别是含氟单体的水性介质中聚合的方法; 和由其形成的含氟聚合物。 具体地,聚合方法使用一种或多种选自聚乙烯基膦酸,聚丙烯酸,聚乙烯基磺酸及其盐的非氟化表面活性剂。 此外,在水性自由基聚合中使用聚乙烯基膦酸,聚丙烯酸,聚乙烯基磺酸作为表面活性剂也是新颖的。

    Method of producing thermoplastic fluoropolymers using alkyl sulfonate surfactants
    2.
    发明授权
    Method of producing thermoplastic fluoropolymers using alkyl sulfonate surfactants 有权
    使用烷基磺酸盐表面活性剂生产热塑性含氟聚合物的方法

    公开(公告)号:US07122610B2

    公开(公告)日:2006-10-17

    申请号:US10832535

    申请日:2004-04-27

    IPC分类号: C08F214/22

    CPC分类号: C08F14/18 C08F2/10

    摘要: Nonfluorinated surfactants selected from C7–C20 linear 1-alkanesulfonates, 2-alkanesulfones, and 1,2-alkanedisulfones are particularly effective for stabilizing emulsions in preparing non-elastomeric fluoropolymers containing at least 71 wt % vinylidene fluoride and having at least a 2% crystalline polyvinylidene fluoride content. Processes for making such fluoropolymers using these surfactants, particularly in combination with one or both of a nonionic polymerization initiator and the use of mechanical coagulation to isolate the product, are also provided, as are fluoropolymers made thereby.

    摘要翻译: 选自C 7 -C 20直链1-链烷磺酸盐,2-烷烃砜和1,2-链烷二砜的非氟化表面活性剂在制备含有至少71重量%偏二氟乙烯并且具有至少2%结晶的非弹性含氟聚合物时稳定乳液是特别有效的 聚偏二氟乙烯含量。 还提供了使用这些表面活性剂,特别是与非离子聚合引发剂中的一种或两种以及使用机械凝结来分离产物的这些含氟聚合物的制备方法,由此制备的含氟聚合物也是如此。

    Method of producing thermoplastic fluoropolymers using alkyl sulfonate surfactants
    3.
    发明申请
    Method of producing thermoplastic fluoropolymers using alkyl sulfonate surfactants 有权
    使用烷基磺酸盐表面活性剂生产热塑性含氟聚合物的方法

    公开(公告)号:US20050239983A1

    公开(公告)日:2005-10-27

    申请号:US10832535

    申请日:2004-04-27

    CPC分类号: C08F14/18 C08F2/10

    摘要: Nonfluorinated surfactants selected from C7-C20 linear 1-alkanesulfonates,-2-sulfonates, and-1,2-disulfonates are particularly effective for stabilizing emulsions in preparing non-elastomeric fluoropolymers containing at least 71 wt % vinylidene fluoride and having at least a 2% crystalline polyvinylidene fluoride content. Processes for making such fluoropolymers using these surfactants, particularly in combination with one or both of a nonionic polymerization initiator and the use of mechanical coagulation to isolate the product, are also provided, as are fluoropolymers made thereby.

    摘要翻译: 选自C7-C20线性1-烷基磺酸盐,-2-磺酸盐和1,2-二磺酸盐的非氟化表面活性剂在制备含有至少71重量%偏二氟乙烯并且具有至少2个 %结晶聚偏二氟乙烯含量。 还提供了使用这些表面活性剂,特别是与非离子聚合引发剂中的一种或两种以及使用机械凝结来分离产物的这些含氟聚合物的制备方法,由此制备的含氟聚合物也是如此。

    Cross-linkable aqueous fluoropolymer based dispersions containing silanes
    7.
    发明授权
    Cross-linkable aqueous fluoropolymer based dispersions containing silanes 失效
    含有硅烷的可交联含氟聚合物含水基分散体

    公开(公告)号:US06833414B2

    公开(公告)日:2004-12-21

    申请号:US10074333

    申请日:2002-02-12

    IPC分类号: C08L8314

    摘要: A cross-linkable fluoropolymer dispersion is described and involves a polymer product of at least one polymerizable acrylic and/or vinyl containing monomer and at least one hydrolytically stable silane containing monomer which are in the presence of an aqueous dispersion of at least one fluoropolymer. The present invention further relates to cross-linkable fluoropolymer blends wherein at least one polymer contains acrylic units, vinyl units, or both and at least one hydrolytically stable silane or silane containing group in the presence of at least one thermoplastic fluoropolymer. The silane or silane containing group can alternatively be present in the thermoplastic fluoropolymer. Methods of making the cross-linkable fluoropolymers are also described as well as products containing the cross-linkable fluoropolymer dispersions such as paints and coatings.

    摘要翻译: 描述了可交联的含氟聚合物分散体,并且涉及至少一种可聚合的丙烯酸和/或乙烯基单体和至少一种水解稳定的含硅烷的单体的聚合物产物,其在至少一种含氟聚合物的水分散体存在下。 本发明还涉及可交联的氟聚合物共混物,其中至少一种聚合物在至少一种热塑性含氟聚合物的存在下包含丙烯酸单元,乙烯基单元或两者以及至少一种水解稳定的硅烷或含硅烷基团。 含硅烷或硅烷的基团也可以存在于热塑性氟聚合物中。 还描述了制备可交联含氟聚合物的方法以及含有可交联的含氟聚合物分散体如油漆和涂料的产品。

    POLYMERIZATION OF FLUOROPOLYMERS USING NON-FLUORINATED SURFACTANTS
    8.
    发明申请
    POLYMERIZATION OF FLUOROPOLYMERS USING NON-FLUORINATED SURFACTANTS 有权
    使用非氟化表面活性剂的氟聚合物的聚合

    公开(公告)号:US20090221776A1

    公开(公告)日:2009-09-03

    申请号:US11995593

    申请日:2006-06-26

    CPC分类号: C08F214/22 C08F14/18 C08F2/22

    摘要: The present invention relates to a method for the polymerization in an aqueous medium of monomers, and especially of fluoromonomers, using non-fluorinated surfactants; and the fluoropolymers formed therefrom. Specifically, the method of the polymerization uses one or more non-fluorinated surfactants selected from the group consisting of polyvinylphosphonic acid, polyacrylic acids, polyvinyl sulfonic acid, and salts thereof. Additionally, the use of polyvinylphosphonic acid, polyacrylic acids, polyvinyl sulfonic acid as surfactants in aqueous free radical polymerization is also novel.

    摘要翻译: 本发明涉及使用非氟化表面活性剂在单体,特别是含氟单体的水性介质中聚合的方法; 和由其形成的含氟聚合物。 具体地,聚合方法使用一种或多种选自聚乙烯基膦酸,聚丙烯酸,聚乙烯基磺酸及其盐的非氟化表面活性剂。 此外,在水性自由基聚合中使用聚乙烯基膦酸,聚丙烯酸,聚乙烯基磺酸作为表面活性剂也是新颖的。