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    Solvent-free laminating adhesive composition from epoxidized block polymer
    1.
    发明授权
    Solvent-free laminating adhesive composition from epoxidized block polymer 失效
    无环氧化嵌段聚合物的无溶剂层压粘合剂组合物

    公开(公告)号：US5393818A

    公开(公告)日：1995-02-28

    申请号：US43428

    申请日：1993-04-06

    申请人： Michael A. Masse ,  Paul A. Mancinelli ,  James R. Erickson ,  Steven H. Dillman ,  Robert C. Bening ,  David R. Hansen

    发明人： Michael A. Masse ,  Paul A. Mancinelli ,  James R. Erickson ,  Steven H. Dillman ,  Robert C. Bening ,  David R. Hansen

    IPC分类号： B32B27/08 ,  C08G59/34 ,  C09J153/00 ,  C09J153/02 ,  C09J163/08 ,  C08K5/10 ,  C08L63/08

    CPC分类号： C08G59/027 ,  B32B27/08 ,  C09J153/005 ,  C09J153/025 ,  C09J163/08 ,  Y10T428/31515

    摘要： A laminating adhesive comprising an adhesive composition which comprises(a) An epoxidized block copolymer of the formula(A--B--A.sub.p).sub.n --Y.sub.r --(A.sub.q --B).sub.mwherein Y is a coupling agent or coupling monomers, and wherein A and B are polymer blocks which may be homopolymer blocks of conjugated diolefin monomers, copolymer blocks of conjugated diolefin monomers or copolymer blocks of conjugated diolefin monomers and monoalkenyl aromatic hydrocarbon monomers, and wherein the A blocks have a higher number of aliphatic double bonds between a tertiary carbon atom and either a primary, secondary, or tertiary carbon atom per unit of block mass than do the B blocks, and wherein the A blocks have a molecular weight from about 100 to about 3000 and the B blocks have a molecular weight from about 1000 to about 15,000, and wherein p and q are 0 or 1 and n>0, r is 0 or 1, m.gtoreq.0 and n+m ranges from 1 to 100; and(b) at least a significant amount of a tackifying resin compatible with the polymer of (a) up to 400 phr.The invention also relates to a laminate containing the adhesive.

    摘要翻译： 一种层压粘合剂，其包含粘合剂组合物，其包含（a）式（AB-Ap）n-Yr-（Aq-B）m的环氧化嵌段共聚物，其中Y为偶联剂或偶联单体，并且其中A和B为 聚合物嵌段，其可以是共轭二烯烃单体的均聚物嵌段，共轭二烯单体的共聚物嵌段或共轭二烯烃单体的共聚物嵌段和单链烯基芳烃单体，并且其中所述A嵌段在叔碳原子和叔碳原子之间具有更高数量的脂族双键 与B嵌段相比，每单位嵌段质量的伯，仲或叔碳原子，其中A嵌段的分子量为约100至约3000，B嵌段的分子量为约1000至约15,000 并且其中p和q为0或1且n> 0，r为0或1，m≥0和n + m的范围为1至100; 和（b）至少大量的与（a）多至400phr的聚合物相容的增粘树脂。 本发明还涉及含有粘合剂的层压体。

    Radiation cured adhesive composition
    2.
    发明授权
    Radiation cured adhesive composition 失效
    辐射固化胶粘剂组成

    公开(公告)号：US5322895A

    公开(公告)日：1994-06-21

    申请号：US84684

    申请日：1993-06-29

    申请人： Michael A. Masse ,  James R. Erickson

    发明人： Michael A. Masse ,  James R. Erickson

    IPC分类号： C09J153/02 ,  C08L53/02 ,  C08F297/04

    CPC分类号： C09J153/02

    摘要： The present invention is a cured adhesive composition with enhanced properties prepared by the high energy ionizing radiation initiated curing of a polymer composition. The polymer composition comprises from 1/3 to 2/3% by weight of the polymer composition of a block copolymer having the structure(D--A--B).sub.x --Y--C.sub.zwhere A is a polymer block of a vinyl aromatic hydrocarbon, B, C and D are polymer blocks of a conjugated diene, Y is a coupling agent or coupling monomers or initiator, x ranges from 3 to 30, z ranges from 0 to 10, the molecular weight of the A blocks ranges from 5,000 to 25,000, the molecular weights of the B and C blocks range from 15,000 to 100,000 and the molecular weight of the D blocks ranges from 500 to 5,000 in one embodiment and above 5000 to 50,000 in the other; and a tackifying resin.

    摘要翻译： 本发明是通过聚合物组合物的高能电离辐射引发固化制备的具有增强性能的固化的粘合剂组合物。 聚合物组合物占聚合物组合物的1/3〜2/3重量％，具有结构（DAB）xY-Cz的嵌段共聚物，其中A为乙烯基芳烃的聚合物嵌段，B，C和D为 共轭二烯的聚合物嵌段，Y是偶联剂或偶联单体或引发剂，x为3至30，z为0至10，A嵌段的分子量为5,000至25,000，分子量为 B和C嵌段的范围为15,000至100,000，D嵌段的分子量在一个实施方案中为500至5,000，另一个为5000至50,000; 和增粘树脂。

    Solvent-free laminating adhesive composition
    3.
    发明授权
    Solvent-free laminating adhesive composition 失效
    无溶剂层压粘合剂组合物

    公开(公告)号：US5516824A

    公开(公告)日：1996-05-14

    申请号：US337714

    申请日：1995-01-23

    申请人： Michael A. Masse ,  Paul A. Mancinelli ,  James R. Erickson ,  Steven H. Dillman ,  Robert C. Bening ,  David R. Hansen

    发明人： Michael A. Masse ,  Paul A. Mancinelli ,  James R. Erickson ,  Steven H. Dillman ,  Robert C. Bening ,  David R. Hansen

    IPC分类号： B32B27/08 ,  C08G59/34 ,  C09J153/00 ,  C09J153/02 ,  C09J163/08 ,  C08K5/10 ,  C08L63/08

    CPC分类号： C08G59/027 ,  B32B27/08 ,  C09J153/005 ,  C09J153/025 ,  C09J163/08 ,  Y10T428/31515

    摘要： A laminating adhesive comprising an adhesive composition which comprises(a) An epoxidized block copolymer of the formula(A-B-A.sub.p).sub.n -Y.sub.r -(A.sub.q -B).sub.mwherein Y is a coupling agent or coupling monomers, andwherein A and B are polymer blocks which may be homopolymer blocks of conjugated diolefin monomers, copolymer blocks of conjugated diolefin monomers or copolymer blocks of conjugated diolefin monomers and monoalkenyl aromatic hydrocarbon monomers, andwherein the A blocks have a higher number of aliphatic double bonds between a tertiary carbon atom and either a primary, secondary, or tertiary carbon atom per unit of block mass than do the B blocks, andwherein the A blocks have a molecular weight from about 100 to about 3000 and the B blocks have a molecular weight from about 1000 to about 15,000, and wherein p and q are 0 or 1 and n>0, r is 0 or 1, m.gtoreq.0 and n+m ranges from 1 to 100; and(b) at least a significant amount of a tackifying resin compatible with the polymer of (a) up to 400 phr.The invention also relates to a laminate containing the adhesive.

    摘要翻译： 一种层压粘合剂，其包含粘合剂组合物，其包含（a）式（AB-Ap）n-Yr-（Aq-B）m的环氧化嵌段共聚物，其中Y为偶联剂或偶联单体，并且其中A和B为 聚合物嵌段，其可以是共轭二烯烃单体的均聚物嵌段，共轭二烯单体的共聚物嵌段或共轭二烯烃单体的共聚物嵌段和单链烯基芳烃单体，并且其中所述A嵌段在叔碳原子和叔碳原子之间具有更高数量的脂族双键 与B嵌段相比，每单位嵌段质量的伯，仲或叔碳原子，其中A嵌段的分子量为约100至约3000，B嵌段的分子量为约1000至约15,000 并且其中p和q为0或1且n> 0，r为0或1，m≥0和n + m的范围为1至100; 和（b）至少大量的与（a）多至400phr的聚合物相容的增粘树脂。 本发明还涉及含有粘合剂的层压体。

    Radiation curable printing ink composition
    4.
    依法登记的发明
    Radiation curable printing ink composition 失效
    可辐射固化印刷油墨组合物

    公开(公告)号：USH1517H

    公开(公告)日：1996-02-06

    申请号：US91481

    申请日：1993-07-12

    申请人： James R. Erickson ,  Michael A. Masse ,  Steven H. Dillman ,  Esther M. Zimmermann

    发明人： James R. Erickson ,  Michael A. Masse ,  Steven H. Dillman ,  Esther M. Zimmermann

    IPC分类号： C09D11/10 ,  C08L61/02

    CPC分类号： C09D11/101

    摘要： The invention is a radiation curable printing ink composition comprising a liquid viscous epoxidized diene polymer and a pigment. Preferred diene polymers are block copolymers comprising at least interior and exterior diene blocks wherein the exterior diene blocks contain a greater concentration of di-, tri-, and tetrasubstituted olefinic epoxides than the interior blocks and wherein the copolymer contains from 0.1 to 3.0 Meq of olefinic epoxides per gram of copolymer and the peak molecular weights as determined by gel permeation chromatography of the exterior blocks of from 300 to 2000 and the peak molecular weights as determined by gel permeation chromatography of the interior blocks are from 2,000 to 10,000. In another preferred embodiment, the polymer is a star polymer having a random distribution of from 0.5 to 5 Meq of di-, tri-, and tetrasubstituted olefinic epoxides per gram of polymer and greater than four arms wherein the peak molecular weights as determined by gel permeation chromatography of the arms are from 1500 to 15,000.

    摘要翻译： 本发明是一种包含液体粘性环氧化二烯聚合物和颜料的可辐射固化印刷油墨组合物。 优选的二烯聚合物是包含至少内部和外部二烯嵌段的嵌段共聚物，其中外部二烯嵌段含有比内部嵌段更大浓度的二，三和四取代烯属环氧化物，并且其中共聚物含有0.1至3.0Meq的烯属 环氧化物/克共聚物和通过外部块的凝胶渗透色谱法测定的峰分子量为300至2000，并且通过内部块的凝胶渗透色谱测定的峰分子量为2,000至10,000。 在另一个优选的实施方案中，聚合物是每克聚合物和大于四个臂的随机分布为0.5-5Meq的二，三和四取代的烯烃环氧化物的星形聚合物，其中由凝胶测定的峰分子量 臂的渗透色谱法为1500至15,000。

    Bitumen and halogenated vinyl aromatic-conjugated diolefin block copolymer compositions
    8.
    发明授权
    Bitumen and halogenated vinyl aromatic-conjugated diolefin block copolymer compositions 失效
    沥青和卤代乙烯基芳族共轭二烯嵌段共聚物组合物

    公开(公告)号：US5246987A

    公开(公告)日：1993-09-21

    申请号：US882725

    申请日：1992-05-14

    申请人： Michael A. Masse ,  James H. Collins ,  Daniel B. England

    发明人： Michael A. Masse ,  James H. Collins ,  Daniel B. England

    IPC分类号： C08L95/00

    CPC分类号： C08L95/00

    摘要： A bitumen composition is provided which contains a block copolymer of one or more halogenated vinyl aromatic blocks and one or more conjugated diolefin blocks. The composition does not phase separate upon storage for five days at 160.degree. C. and has excellent ductility and elasticity. The utilization of halogenated block copolymers also results in improved high service temperature viscosity and moduli with excellent resistance to thermal cracking at low service temperatures. The block copolymer is preferably a hydrogenated block copolymer. The bitumen is preferably halogenated.

    摘要翻译： 提供了一种含有一种或多种卤代乙烯基芳族嵌段与一种或多种共轭二烯烃嵌段的嵌段共聚物的沥青组合物。 该组合物在160℃储存5天并不相分离，具有优良的延展性和弹性。 卤化嵌段共聚物的利用也导致改进的高使用温度粘度和模量，在低使用温度下具有优异的耐热裂纹性。 嵌段共聚物优选为氢化嵌段共聚物。 沥青优选为卤化。

    Method for producing statistically coupled asymmetric radial polymers
    9.
    发明授权
    Method for producing statistically coupled asymmetric radial polymers 失效
    统计耦合的不对称径向聚合物的制备方法

    公开(公告)号：US5446093A

    公开(公告)日：1995-08-29

    申请号：US150929

    申请日：1993-11-10

    申请人： Ronald J. Hoxmeier ,  Bridget A. Spence ,  Steven S. Chin ,  Michael A. Masse

    发明人： Ronald J. Hoxmeier ,  Bridget A. Spence ,  Steven S. Chin ,  Michael A. Masse

    IPC分类号： C08G81/02 ,  C08L53/02 ,  C08F297/04

    CPC分类号： C08G81/022

    摘要： A process is disclosed for producing six-armed and eight-armed asymmetric radial block copolymers. The process comprises anionically polymerizing a diene and/or a vinyl aromatic hydrocarbon to create living polydiene and/or vinyl aromatic hydrocarbon arms, sequentially anionically polymerizing a vinyl aromatic hydrocarbon and a diene to create living block copolymer arms and coupling the two sets of arms together in one step with a coupling agent that will couple six or eight arms, wherein the molar ratio of the vinyl aromatic hydrocarbon-diene arms to the polydiene arms is sufficient to produce a statistical blend with less than 5 weight percent homopolydiene.

    摘要翻译： 公开了一种用于生产六臂和八臂不对称径向嵌段共聚物的方法。 该方法包括阴离子聚合二烯和/或乙烯基芳烃以产生活性聚二烯和/或乙烯基芳族烃臂，依次阴离子聚合乙烯基芳族烃和二烯以产生活性嵌段共聚物臂并将两组臂结合在一起 在一步中与偶联剂可以连接6或8个臂，其中乙烯基芳族烃 - 二烯臂与聚二烯臂的摩尔比足以产生具有小于5重量％均聚二烯的统计学共混物。

    Method for producing coupled asymmetric polymers
    10.
    发明授权
    Method for producing coupled asymmetric polymers 失效
    偶联不对称聚合物的制备方法

    公开(公告)号：US5360875A

    公开(公告)日：1994-11-01

    申请号：US120116

    申请日：1993-09-10

    申请人： Michael A. Masse ,  Steven S. Chin ,  Craig A. Stevens

    发明人： Michael A. Masse ,  Steven S. Chin ,  Craig A. Stevens

    IPC分类号： C08F8/42 ,  C08F297/02 ,  C08F297/04

    CPC分类号： C08F297/044 ,  C08F297/046

    摘要： A process for preparing a coupled asymmetric block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene which comprises:(a) adding sufficient anionic polymerization initiator to the vinyl aromatic hydrocarbon monomer to start polymerization of the vinyl aromatic hydrocarbon,(b) polymerizing the vinyl aromatic hydrocarbon for a time sufficient to form a first set of vinyl aromatic hydrocarbon blocks having a desired molecular weight,(c) adding sufficient anionic polymerization initiator to start polymerization of a second set of vinyl aromatic hydrocarbon blocks,(d) completing the polymerization of the vinyl aromatic hydrocarbon for a time such that the first set of vinyl aromatic hydrocarbon blocks continues to grow to the desired molecular weight and the second set of vinyl aromatic hydrocarbon blocks grows to a desired smaller molecular weight,(e) adding a conjugated diene and polymerizing it on the ends of the vinyl aromatic hydrocarbon blocks for a time sufficient to form vinyl aromatic hydrocarbon-conjugated diene arms of the desired molecular weight, and(f) adding a coupling agent and coupling the arms to form the asymmetric block copolymer.

    摘要翻译： 一种制备乙烯基芳族烃和共轭二烯的偶联不对称嵌段共聚物的方法，其包括：（a）向乙烯基芳族烃单体加入足够的阴离子聚合引发剂以开始乙烯基芳烃的聚合，（b） 芳烃在足以形成具有所需分子量的第一组乙烯基芳族烃嵌段的时间内，（c）加入足够的阴离子聚合引发剂以开始聚合第二组乙烯基芳族烃嵌段，（d）完成聚合反应 乙烯基芳族烃一段时间，使得第一组乙烯基芳族烃嵌段继续生长至所需分子量，第二组乙烯基芳族烃嵌段生长至所需的较小分子量，（e）加入共轭二烯和 在乙烯基芳族烃嵌段的末端聚合足够长的时间 以形成所需分子量的乙烯基芳族烃 - 共轭二烯臂，和（f）加入偶联剂并偶联臂以形成不对称嵌段共聚物。