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公开(公告)号:US4515808A
公开(公告)日:1985-05-07
申请号:US517441
申请日:1983-07-26
IPC分类号: A01N37/34 , A01N53/00 , A01N53/06 , C07C251/32 , C07C251/40 , C07C251/48 , C07C121/78
CPC分类号: A01N53/00
摘要: Pesticidal compounds have the formula: ##STR1## wherein D represents hydrogen or a cyano group or an ethynyl group R.sub.a represents alkylA represents an alkyl group or a halogeno or trifluoromethyl groupn is 0 or an integer of 1-4, b is 0 or 1andRCOO is the residue of an acid RCOOH whose .alpha.-cyano-3-phenoxybenzyl ester has pesticidal properties. They are prepared by esterification methods.
摘要翻译: 杀虫化合物具有下式:其中D表示氢或氰基或乙炔基Ra表示烷基A表示烷基或卤代或三氟甲基n为0或1-4的整数,b为0 或1,RCOO是酸性RCOOH的残基,其α-氰基-3-苯氧基苄基酯具有农药性质。 它们通过酯化方法制备。
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公开(公告)号:US5248834A
公开(公告)日:1993-09-28
申请号:US870112
申请日:1992-04-17
IPC分类号: A01N31/14 , A01N43/30 , C07C25/18 , C07C33/50 , C07C43/215 , C07C43/23 , C07C43/285 , C07C43/29 , C07C43/295 , C07C45/29 , C07C47/457 , C07C47/47 , C07C49/84 , C07D317/50 , C07D317/52 , C07D317/54
CPC分类号: C07D317/54 , A01N31/14 , A01N43/30 , C07C25/18 , C07C33/50 , C07C43/215 , C07C43/23 , C07C43/285 , C07C43/29 , C07C43/295 , C07C45/292 , C07C47/457 , C07C47/47 , C07C49/84 , C07D317/50 , C07D317/52
摘要: Pesticidal compounds of formula II: R.sub.A CR.sub.3 .dbd.CR.sub.4 CHDR.sub.Bin which formula:R.sub.A represents a group ArCR.sub.1 R.sub.2 - in which Ar represents a phenyl or naphthyl group optionally substituted by one or more halogen, alkoxy, haloalkoxy, methylenedioxy, C.sub.1 -C.sub.6 alkyl or haloalkyl groups;R.sub.1 and R.sub.2 together with the carbon to which they are attached represent a C.sub.3 -C.sub.6 cycloalkyl group optionally substituted by one or more halogen atoms or C.sub.1 -C.sub.6 alkyl groups.R.sub.3 and R.sub.4 which may be identical or differ, represent hydrogen halogen or C.sub.1 -C.sub.6 alkyl groups andR.sub.B represents the residue of an alcohol R.sub.B CHDOH in which D is hydrogen or cyano and of which the [1R, cis] 2,2-dimethyl-3-(2,2-dibromovinyl) cyclopropane carboxylic ester is significantly insecticidal,the configuration of R.sub.A and CHDR.sub.B about the double bond being mutually trans,and processes for the production of compounds I, intermediates, pesticidal compositions comprising I, processes for the production thereof, methods for controlling pests, especially rice pests, in which such compounds are utilized and the use of compounds I for the manufacture of a pesticide.
摘要翻译: 式I I的杀虫化合物:RACR3 = CR4CHDRB,式中RA表示ArCR1R2基团,其中Ar表示任选被一个或多个卤素,烷氧基,卤代烷氧基,亚甲二氧基,C 1 -C 6烷基或卤代烷基取代的苯基或萘基; R1和R2与它们所连接的碳一起代表任选被一个或多个卤素原子或C 1 -C 6烷基取代的C 3 -C 6环烷基。 可以相同或不同的R 3和R 4表示氢卤素或C 1 -C 6烷基,并且R B表示其中D是氢或氰基的醇RB CHDOH的残基,其中[1R,顺式] 2,2-二甲基 -3-(2,2-二溴乙烯基)环丙烷羧酸酯是显着的杀虫剂,关于双键的RA和CHDRB相互反应的构型,以及生产化合物I,中间体,包含I的杀虫组合物的方法, 其生产方法,其中使用这些化合物的害虫特别是水稻害虫的防治方法以及化合物I用于制造农药的方法。
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公开(公告)号:US4594355A
公开(公告)日:1986-06-10
申请号:US517393
申请日:1983-07-26
申请人: Michael Elliott , Norman F. Janes , Richard L. Elliott , Bhupinder P. S. Khambay , David A. Pulman
发明人: Michael Elliott , Norman F. Janes , Richard L. Elliott , Bhupinder P. S. Khambay , David A. Pulman
IPC分类号: C07C17/16 , A01N53/00 , A01N53/06 , C07C17/00 , C07C22/04 , C07C27/00 , C07C29/14 , C07C33/22 , C07C33/30 , C07C45/59 , C07C45/62 , C07C47/548 , C07C67/00 , C07C67/03 , C07C67/08 , C07C67/10 , C07C67/14 , C07C69/08 , C07C69/743 , C07C69/747 , C07C253/00 , C07C255/32 , C07C255/34 , C07C255/35 , C07C255/36 , C07C255/39 , C07C255/53 , C07D317/12 , C07C121/66
CPC分类号: C07C255/00 , A01N53/00 , C07C29/14 , C07C33/30 , C07C45/59 , C07C45/62 , C07C47/548 , C07D317/12 , C07B2200/09
摘要: Pesticidal compounds have the formula: ##STR1## wherein D represents hydrogen or a cyano or ethynyl group;B represents hydrogen or an alkyl or alkenyl group;A represents an alkyl group or a halogeno group or a CF.sub.3 group;n is 0 or an integer of 1-4; andRCOO is the residue of an acid RCOOH which is a 2,2-dimethyl-cyclopropane carboxylic acid carrying at the 3-position a dihalovinyl, an alkenyl or a carboalkoxyalkenyl group, provided that (1) when the group --CH.sub.2 CH.dbd.CHB is located at the 4-position on the ring with respect to the ester linkage, then D must be hydrogen and the group carried at the 3-position on the cyclopropane ring of the acid must be a dihalovinyl group and (2) when the group --CH.sub.2 CH.dbd.CHB is located at the 3-position on the ring and D is a CN group, then n must be 0.
摘要翻译: 杀虫化合物具有下式:其中D表示氢或氰基或乙炔基; B表示氢或烷基或烯基; A表示烷基或卤代基或CF 3基; n为0或1-4的整数; 并且RCOO是酸性RCOOH的残基,其是在3-位上带有二卤代乙烯基,烯基或烷氧羰氧基的2,2-二甲基 - 环丙烷羧酸,条件是(1)当基团-CH 2 CH = CHB为 位于环上相对于酯键的4-位,则D必须是氢,并且在酸的环丙烷环上的3-位上携带的基团必须是二卤乙烯基,和(2)当基团 - CH2CH = CHB位于环上的3位,D是CN组,则n必须为0。
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公开(公告)号:US4874781A
公开(公告)日:1989-10-17
申请号:US143319
申请日:1988-01-11
IPC分类号: C07D317/60 , A01N37/10 , A01N37/34 , A01N37/38 , A01N43/08 , C07C57/58 , C07C57/60 , C07C69/612 , C07C69/618 , C07C69/635 , C07C69/65 , C07C69/734 , C07D307/42 , C07D307/54 , C07D317/48
CPC分类号: C07D307/42 , A01N37/10 , A01N37/38 , A01N43/08 , C07C255/00
摘要: A compound of formula II: ArCHR.sub.1 CO.sub.2 CHDR.sub.2in which formula:Ar represents a phenyl or naphthyl group optionally substituted by one or more halogen, alkoxy, haloalkoxy, methylenedioxy, C.sub.1 -C.sub.6 alkyl or haloalkyl groups;R.sub.1 represents the group --CH(CF.sub.3)CH.sub.3 or --C(CF.sub.3).dbd.CH.sub.2R.sub.2 represents the residue of an alcohol R.sub.2 CHDOH in which D is hydrogen or cyano and of which the [1R, cis]2,2-dimethyl-3-(2,2-dibromovinyl)cyclopropane carboxylic ester is significantly insecticidal.
摘要翻译: 式I I的化合物:ArCHR1CO2CHDR2,其中式Ar代表任选被一个或多个卤素,烷氧基,卤代烷氧基,亚甲二氧基,C 1 -C 6烷基或卤代烷基取代的苯基或萘基; R1表示基团-CH(CF3)CH3或-C(CF3)= CH2R2表示醇R2 CHDOH的残基,其中D是氢或氰基,其中[1R,顺式] 2,2-二甲基-3 - (2,2-二溴乙烯基)环丙烷羧酸酯是显着的杀虫剂。
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公开(公告)号:US4713392A
公开(公告)日:1987-12-15
申请号:US732642
申请日:1985-05-10
IPC分类号: A01N35/06 , A01N35/02 , A01N35/04 , A01N37/34 , A01N37/42 , A01N43/08 , A01N43/30 , C07C43/174 , C07C43/215 , C07C43/295 , C07C45/00 , C07C45/29 , C07C45/30 , C07C45/44 , C07C45/45 , C07C45/51 , C07C47/24 , C07C47/277 , C07C47/457 , C07C49/105 , C07C49/213 , C07C49/255 , C07C67/00 , C07C253/00 , C07C255/40 , A61K31/275 , C07C49/657
CPC分类号: C07C255/00 , A01N35/02 , A01N37/42 , C07C43/1747 , C07C43/215 , C07C43/295 , C07C45/292 , C07C45/305 , C07C45/44 , C07C45/45 , C07C45/513 , C07C47/24 , C07C47/277 , C07C47/457 , C07C49/255
摘要: A compound of formula IIR.sub.A CH.sub.2 COCHDR.sub.bin which formula:R.sub.A represents a group ArCR.sub.1 R.sub.2 -- in which Ar represents a phenyl or naphthyl group optionally substituted by one or more halogen, alkoxy, haloalkoxy, methylenedioxy or C.sub.1 -C.sub.6 alkyl or haloalkyl groups;R.sub.1 and R.sub.2 together with the carbon to which they are attached jointly represent a C.sub.3 -C.sub.6 cycloalkyl group optionally substituted by one or more halogen atoms or C.sub.1 -C.sub.6 cycloalkyl groups andR.sub.B represents the residue of an alcohol R.sub.B CHDOH in which D is hydrogen or cyano and of which the [IR, cis]2,2-dimethyl-3-(2,2-dibromovinyl)cyclopropane carboxylic ester is signficantly insecticidal.
摘要翻译: 式II RACH2COCHDRb的化合物,其中式RA代表ArCR1R2-基团,其中Ar表示任选被一个或多个卤素,烷氧基,卤代烷氧基,亚甲二氧基或C 1 -C 6烷基或卤代烷基取代的苯基或萘基; R 1和R 2与它们所连接的碳一起表示任选被一个或多个卤素原子或C 1 -C 6环烷基取代的C 3 -C 6环烷基,并且R B表示其中D是氢或氰基的醇RBCHDOH的残基 其中[IR,顺式] 2,2-二甲基-3-(2,2-二溴乙烯基)环丙烷羧酸酯具有显着的杀虫作用。
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公开(公告)号:US4696944A
公开(公告)日:1987-09-29
申请号:US711812
申请日:1985-03-14
IPC分类号: A01N37/02 , A01N53/00 , A01N53/02 , A01N53/10 , C07C45/00 , C07C45/63 , C07C45/64 , C07C45/67 , C07C49/687 , C07C49/743 , C07C49/747 , C07C67/00 , C07C239/00 , C07C251/44 , C07C69/743 , C07C131/08
CPC分类号: C07C49/747 , A01N53/00 , C07C45/63 , C07C45/64 , C07C45/673 , C07C49/687 , C07C49/743
摘要: A compound of formula I ##STR1## in which formula: R.sub.a represents hydrogen or a C.sub.1 -C.sub.6 alkyl group, and R.sub.c represents a C.sub.1 -C.sub.6 alkyl group;R.sub.b represents a phenyl group, optionally substituted by a C.sub.1 -C.sub.6 alkyl group or halogen, a group of formula --CH.dbd.CR.sub.d R.sub.e in which R.sub.d and R.sub.e, which may be identical or different represent hydrogen or C.sub.1 -C.sub.6 alkyl groups or a group of formula --CH.dbd.NOR.sub.f in which R.sub.f represents hydrogen or a C.sub.1 -C.sub.6 alkyl group andRCOO represents a residue of an acid RCO.sub.2 H, which acid, or an ester-forming derivative of which acid, on reaction with .alpha.-cyano-3-phenoxybenzyl alcohol or an ester forming derivative thereof, gives rise to an .alpha.-cyano-3-phenoxybenzyl ester having pesticidal properties.
摘要翻译: 式I的化合物,其中式为R a表示氢或C 1 -C 6烷基,R c表示C 1 -C 6烷基; R b表示任选被C 1 -C 6烷基或卤素取代的苯基,式-CH = CR d Re的基团,其中可以相同或不同的R d和R e表示氢或C 1 -C 6烷基或基团 式-CH = NORf,其中R f表示氢或C 1 -C 6烷基,RCOO表示酸RCO 2 H的残基,该酸或其酸形成衍生物与α-氰基-3-苯氧基苄基 醇或其形成酯的衍生物,产生具有杀虫性的α-氰基-3-苯氧基苄基酯。
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公开(公告)号:US5283371A
公开(公告)日:1994-02-01
申请号:US721149
申请日:1991-06-26
IPC分类号: C07C39/27 , C07F3/02 , C07F5/02 , C07C43/225
摘要: A process for the production of a boronic acid of formula III, ##STR1## in which an organometallic of formula IV, ##STR2## in which formula IV, M represents a metallic moiety such as --MgX, X being a halogen or an alkali metal is treated with a trialkoxy borane of formula B(OR).sub.3, R representing an alkyl group and the product is hydrolysed.
摘要翻译: 制备式III的硼酸的方法,其中式IV的有机金属化合物,其中式IV,M表示金属部分,例如-MgX,X是卤素或 碱金属用式B(OR)3的三烷氧基硼烷处理,R代表烷基,产物被水解。
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公开(公告)号:US5068403A
公开(公告)日:1991-11-26
申请号:US428193
申请日:1989-10-27
IPC分类号: C07B49/00 , C07C27/00 , C07C39/27 , C07C39/44 , C07C41/00 , C07C41/01 , C07C43/29 , C07C67/00 , C07F1/00 , C07F1/02 , C07F3/02 , C07F5/02
摘要: A process for the production of a boronic acid of formula III, ##STR1## in which an organometallic of formula IV, ##STR2## in which formula IV, M represents a metallic moiety such as --MgX, X being a halogen or an alkali metal is treated with a trialkoxy borane of formula B(OR).sub.3, R representing an alkyl group and the product is hydrolyzed.
摘要翻译: 制备式III的硼酸的方法,其中式IV的有机金属化合物,其中式IV,M表示金属部分,例如-MgX,X是卤素或 碱金属用式B(OR)3的三烷氧基硼烷处理,R代表烷基,产物水解。
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公开(公告)号:US4789754A
公开(公告)日:1988-12-06
申请号:US849070
申请日:1986-04-07
申请人: Michael Elliott , Norman F. Janes , Richard L. Elliott , Bhupinder P. S. Khambay , David A. Pulman
发明人: Michael Elliott , Norman F. Janes , Richard L. Elliott , Bhupinder P. S. Khambay , David A. Pulman
IPC分类号: C07C17/16 , A01N53/00 , A01N53/06 , C07C17/00 , C07C22/04 , C07C27/00 , C07C29/14 , C07C33/22 , C07C33/30 , C07C45/59 , C07C45/62 , C07C47/548 , C07C67/00 , C07C67/03 , C07C67/08 , C07C67/10 , C07C67/14 , C07C69/08 , C07C69/743 , C07C69/747 , C07C253/00 , C07C255/32 , C07C255/34 , C07C255/35 , C07C255/36 , C07C255/39 , C07C255/53 , C07D317/12 , C07C121/52
CPC分类号: C07C255/00 , A01N53/00 , C07C29/14 , C07C33/30 , C07C45/59 , C07C45/62 , C07C47/548 , C07D317/12 , C07B2200/09
摘要: A compound of the formula: ##STR1## wherein Y represents OH or a halogeno group;D represents hydrogen or a cyano group;B represents hydrogen or a methyl, ethyl or vinyl group;A represents methyl;n is 0, 1 or 2;with the proviso that(1) when the CH.sub.2 CH.dbd.CHB group is in the 4-position with respect to the CHDY group, then D must be hydrogen and B must be methyl, ethyl or vinyl and the configuration about the double bond in the CH.dbd.CHB group must be Z and(2) when the group CH.dbd.CHB is in the 3-position with respect to the CHDY group and D is CN then n must be 0 and(3) when the group CH.sub.2 CH.dbd.CHB is in the 2 or 3-position with respect to the CHDY group, then D is CN, are useful in the production of pesticidal esters of chrysanthemic and related acids.
摘要翻译: 下式的化合物:其中Y表示OH或卤代基; D表示氢或氰基; B表示氢或甲基,乙基或乙烯基; A代表甲基; n为0,1或2; 条件是(1)当CH 2 CH = CHB基团相对于CHDY基团处于4-位时,则D必须是氢,B必须是甲基,乙基或乙烯基,并且在CH中的双键构型 = CHB组必须为Z,(2)当组CH = CHB相对于CHDY组为3位时,D为CN,则n必须为0,(3)当CH 2 CH = CHB基为 相对于CHDY组为2或3位,则D为CN,可用于生产菊花和相关酸的杀虫剂。
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公开(公告)号:US6162799A
公开(公告)日:2000-12-19
申请号:US71887
申请日:1998-05-05
摘要: This invention relates to certain naphthoquinone derivatives of the general formula ##STR1## or a salt thereof, in which m, n, R, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8 are as defined in the description; processes for their preparation; compositions containing such compounds and their use as a pesticide, such as a fungicide and, especially, an insecticide or an acaricide.
摘要翻译: 本发明涉及某些通式的萘醌衍生物或其盐,其中m,n,R,R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8如说明书中所定义; 其准备过程; 含有这些化合物的组合物及其作为农药的用途,例如杀真菌剂,特别是杀虫剂或杀螨剂。
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