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1.发明授权公开(公告)号：US06552236B2
公开(公告)日：2003-04-22
申请号：US09841043
申请日：2001-04-25
IPC分类号： C07C2700
CPC分类号： C07C29/00 , C07C1/20 , Y02P20/127 , Y02P20/52 , C07C11/02 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12
摘要： Alkyl tert-alkyl ethers are cleaved into the corresponding isoolefins and alkanols by a process comprising acid-catalyzed reactive distilling an alkyl tert-alkyl ether fed into the reaction zone of a reactive distillation apparatus as an azeotrope of the alkyl tert-alkyl ether and the corresponding alkanol, wherein the reactive distillation apparatus is configured from bottom to top as a bottom zone, at least one distillation zone and a reaction zone. The process is suitable for the cleavage of primary, secondary and tertiary alkyl tert-alkyl ethers, in particular MTBE.
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2.发明授权Dealuminized catalyst carrier, method of production, and method for hydrating C2 or C3 olefins with water 有权脱色催化剂载体，生产方法，以及用水将C2或C3烯烃水合的方法公开(公告)号：US06881700B2
公开(公告)日：2005-04-19
申请号：US10634879
申请日：2003-08-06
摘要： A catalyst support comprising silicates is described. This catalyst support has a lower aluminum content than naturally occurring sheet silicates and can be used in the hydration of C2 and C3 olefins to produce C2 and C3 alcohols. A method for the production of the catalyst support and a process for hydrating C2 and C3 olefins are also described. One advantage of this catalyst support is the reduction in aluminum leaching that occurs when this catalyst is used in the presence of phosphoric acid.
摘要翻译： 描述了包含硅酸盐的催化剂载体。 该催化剂载体的铝含量比天然存在的片状硅酸盐低，可用于C 2 O 3和C 3 O 3烯烃的水合以产生C 2 SUB和C 3醇。 还描述了制备催化剂载体的方法和水合C 2和C 3 O 3烯烃的方法。 该催化剂载体的一个优点是当在磷酸存在下使用该催化剂时，铝浸出的减少。
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公开(公告)号：US06881699B1
公开(公告)日：2005-04-19
申请号：US09701054
申请日：1999-07-01
摘要： What is claimed is a dealuminated catalyst carrier, a process for producing a catalyst carrier with reduced aluminum content based on naturally occurring lattice-layer silicates, such as, for example, montmorillonite, as well as a process for the hydration reaction of C2- or C3-olefins in which said catalyst carrier with reduced aluminium content is used. For acid-catalysed hydration reaction the catalyst carrier is impregnated with phosphoric acid. The improvements according to the invention of the hydration reaction compared to conventional processes include the fact that no aluminium is leached out of the carrier in the presence of the phosphoric acid. As a result no more blockage of the succeeding apparatus due to aluminium phosphate is expected.
摘要翻译： 所要求的是脱铝催化剂载体，基于天然存在的格子层硅酸盐（例如蒙脱石）制备具有降低的铝含量的催化剂载体的方法，以及C
其中使用具有降低的铝含量的所述催化剂载体的2- 2 - 或C 3 - 烯烃。 对于酸催化的水合反应，催化剂载体用磷酸浸渍。 根据本发明的水合反应与常规方法相比的改进包括在磷酸存在下不将铝从载体中浸出的事实。 因此，预计不会因为磷酸铝而导致后续装置的堵塞。 -
4.发明申请Dealuminized catalyst support, method for producing said catalyst support and method for hydrating C2- or C3-olefins with water in the presence of a catalyst consisting of this catalyst support impregnated with acid 审中-公开脱铝催化剂载体，用于生产所述催化剂载体的方法和用水在含有酸的催化剂载体的催化剂存在下水与C2-或C3-烯烃的方法公开(公告)号：US20050131259A1
公开(公告)日：2005-06-16
申请号：US10973759
申请日：2004-10-26
摘要： What is claimed is a dealuminated catalyst carrier, a process for producing a catalyst carrier with reduced aluminium content based on naturally occurring lattice-layer silicates, such as, for example, montmorillonite, as well as a process for the hydration reaction of C2- or C3-olefins in which said catalyst carrier with reduced aluminium content is used. For acid-catalysed hydration reaction the catalyst carrier is impregnated with phosphoric acid. The improvements according to the invention of the hydration reaction compared to conventional processes include the fact that no aluminium is leached out of the carrier in the presence of the phosphoric acid. As a result no more blockage of the succeeding apparatus due to aluminum phosphate is expected.
摘要翻译： 所要求的是脱铝催化剂载体，基于天然存在的格子层硅酸盐（例如蒙脱石）制备具有降低的铝含量的催化剂载体的方法，以及C
其中使用具有降低的铝含量的所述催化剂载体的2- 2 - 或C 3 - 烯烃。 对于酸催化的水合反应，催化剂载体用磷酸浸渍。 根据本发明的水合反应与常规方法相比的改进包括在磷酸存在下不将铝从载体中浸出的事实。 因此，预计不会因为磷酸铝而导致后续装置的堵塞。 -
公开(公告)号：US06841704B2
公开(公告)日：2005-01-11
申请号：US10204923
申请日：2001-02-19
申请人： Michael Sakuth , Uwe Tanger , Markus Weber
发明人： Michael Sakuth , Uwe Tanger , Markus Weber
IPC分类号： C07C2/88 , C07B61/00 , C07C2/66 , C07C2/86 , C07C15/085 , C07C27/00 , C07C29/145 , C07C39/04 , C07L37/08
CPC分类号： C07C39/04 , C07C2/66 , C07C2/864 , C07C29/145 , C07C2529/70 , Y02P20/52 , Y02P20/582 , C07C15/085 , C07C31/10 , C07C31/20
摘要： Disclosed is a method for the preparation of cumene by reacting isopropanol or a mixture of isopropanol and propene with benzene in the presence of a β-zeolite catalyst having a SiO2/Al2O3 molar ratio greater than 10:1 that can be integrated in a process for preparing phenol, which comprises preparing cumene as described above, oxidizing cumene to cumene hydroperoxide, acid-catalyzed cleavage of cumene hydroperoxide to give phenol and acetone, and hydrogenating acetone to form isopropanol.
摘要翻译： 公开了一种在具有SiO 2 Al 2 O 3摩尔比大于10:1的β-沸石催化剂存在下，使异丙醇或异丙醇和丙烯的混合物与苯反应来制备异丙基苯的方法，其可以与制备苯酚的方法相结合 ，其包括如上所述制备枯烯，将异丙基苯氧化成氢过氧化枯烯，酸催化裂解氢过氧化枯烯，得到苯酚和丙酮，并加氢丙酮以形成异丙醇。
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6.发明授权
公开(公告)号：US5849971A
公开(公告)日：1998-12-15
申请号：US866013
申请日：1997-05-30
申请人： Michael Sakuth , Udo Peters
发明人： Michael Sakuth , Udo Peters
IPC分类号： B01J31/08 , B01D3/00 , B01J8/02 , C07B61/00 , C07C1/20 , C07C1/24 , C07C7/04 , C07C11/02 , C07C11/09 , B01D3/34
CPC分类号： B01J8/02 , B01D3/009 , C07C1/20 , C07C1/24 , C07C2531/08 , Y02P20/127 , Y10S203/06
摘要： The present invention is directed to a process for the acid-catalyzed cracking of tertiary butyl alcohol in a reaction distillation column. The advantage of the process of the present invention compared with conventional processes is that the two-phase, liquid-liquid region of the tertiary system TBA/water/isobutene is avoided and a high space-time yield is achieved. This is achieved by the arrangement of the catalyst pack above the liquid phase zone (bottom) and by the use of a dephlegmator thus achieving the isolation of isobutene of high purity.
摘要翻译： 本发明涉及反应蒸馏塔中叔丁醇酸催化裂化的方法。 与常规方法相比，本发明方法的优点是避免了三级体系TBA /水/异丁烯的两相液 - 液区域，并实现了高空时收率。 这通过催化剂组件在液相区（底部）上的布置和通过使用分馏器的方式实现，从而实现高纯度的异丁烯的分离来实现。
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